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Highly Stretchable, High‐Mobility, Free‐Standing All‐Organic Transistors Modulated by Solid‐State Elastomer Electrolytes

DOI:10.1002/adfm.201808909 期刊:Advanced Functional Materials 出版年份:2019 更新时间:2025-11-14 17:28:48
摘要: Highly stretchable, high-mobility, and free-standing coplanar-type all-organic transistors based on deformable solid-state elastomer electrolytes are demonstrated using ionic thermoplastic polyurethane (i-TPU), thereby showing high reliability under mechanical stimuli as well as low-voltage operation. Unlike conventional ionic dielectrics, the i-TPU electrolyte prepared herein has remarkable characteristics, i.e., a large specific capacitance of 5.5 μF cm?2, despite the low weight ratio (20 wt%) of the ionic liquid, high transparency, and even stretchability. These i-TPU-based organic transistors exhibit a mobility as high as 7.9 cm2 V?1 s?1, high bendability (Rc, radius of curvature: 7.2 mm), and good stretchability (60% tensile strain). Moreover, they are suitable for low-voltage operation (VDS = ?1.0 V, VGS = ?2.5 V). In addition, the electrical characteristics such as mobility, on-current, and threshold voltage are maintained even in the concave and convex bending state (bending tensile strain of ≈3.4%), respectively. Finally, free-standing, fully stretchable, and semi-transparent coplanar-type all-organic transistors can be fabricated by introducing a poly(3,4-ethylenedioxythiophene):polystyrene sulfonic acid layer as source/drain and gate electrodes, thus achieving low-voltage operation (VDS = ?1.5 V, VGS = ?2.5 V) and an even higher mobility of up to 17.8 cm2 V?1 s?1. Moreover, these devices withstand stretching up to 80% tensile strain.
作者: Do Hyung Park,Han Wool Park,Jong Won Chung,Kyungah Nam,Shinyoung Choi,Yoon Sun Chung,Haejung Hwang,BongSoo Kim,Do Hwan Kim
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To develop highly stretchable, high-mobility, free-standing all-organic transistors using deformable solid-state elastomer electrolytes for applications in stretchable and conformal electronics.

The research successfully demonstrated highly stretchable, high-mobility, free-standing all-organic transistors using i-TPU elastomer electrolytes, achieving low-voltage operation and excellent mechanical reliability. This approach addresses interfacial problems in organic devices and provides a foundation for future flexible and stretchable electronics.

The study may have limitations in scalability for large-scale production, potential issues with long-term stability under cyclic mechanical stress, and the use of specific materials that might not be universally applicable. Optimization could be needed for higher strain tolerance and improved electrode conductivity.

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