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Functionalizing Window Coatings with Luminescence Centers by Combinatorial Sputtering of Scatter-Free Amorphous SiAlON:Eu2+ Thin Film Composition Libraries
摘要： SiAlON window coatings are applied on an industrial scale to achieve e.g. scratch-resistance and anti-reflection. Doping these SiAlONs with rare-earths adds luminescent functionality, which could be applied in photovoltaics. By using a combinatorial reactive sputtering approach, an amorphous thin film composition library with a Si:Al ratio from 0:062 : 1 to 3:375 : 1 and a Eu doping from 4:8 at:% to 26 at:% is created. This library uniquely combines high absorption, strong emission and absence of light scattering. By combining position-dependent EDX measurements with transmission and emission spectra, properties like the index of refraction, absorption strength, emission wavelength and decay times of the library can directly be related to the composition. Throughout the library, an index of refraction of 1:63 ± 0:03 is observed, typical for a film with low nitrogen content. The library also shows a large absorption coefficient of 1294 ± 8 cm?1 at:%?1. Laser-excited emission spectra show that the library has a strong redshift from 500 nm to 550 nm with increasing Al concentration. An increase in Eu concentration also causes a shift of the emission to red. Decay spectra show that a high degree of Si greatly improves the luminescence intensity. These functionalized SiAlON coatings can be of great interest for transparent and scatter-free luminescent solar concentrators applied as windows.
关键词： Combinatorial Science,SiAlON,Sputter Deposition,Solar-Conversion
更新于2025-11-14 15:30:11
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Effect of NaN<sub>3</sub> Addition Content on NaCl-NaF Medium Nitridation Synthesis β-Sialon Powders
摘要： β-Sialon powders were synthesized via salt-assisted nitridation synthesis from Al, Si, SiO2 powders and molten salt medium (NaCl and NaF) with the addition of different content of NaN3 at different temperature for 3 h. NaN3 were employed as auxiliary nitrogen source which effectively provide sufficient nitrogen. The results indicated that the growth of β-Sialon powders had better effect when the NaN3 was added. And the β-Sialon powders grew more completely and the morphology of β-Sialon powders showed the rod-like crystal with hexagonal smooth tips instead of conical tips. In addition, the products displayed different sizes when the content of NaN3 was changed. These results of this work suggested that β-Sialon could be synthesized with specific morphology by adding different content of NaN3.
关键词： β-Sialon,synthesis,Morphology,nitridation,salt-assisted
更新于2025-09-23 15:22:29
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Laser Micro-Texturing of Sintered Tool Materials Surface
摘要： The purpose of this paper is to show the effect of tool materials surface treatment while using laser texturing on the structure and properties of cemented carbides and sialon ceramics. The tests were made on multi-point inserts subjected laser texturization and honeycomb-like texture was obtained. Comprehensive investigations in the scanning electron microscope (SEM) were made. Morphology was examined by the use of atomic forces microscope (AFM) and confocal microscope. The chemical composition of the tested materials using energy-dispersive X-ray spectrometer (EDS) was investigated. Moreover, exploitative properties, including wear resistance using the "pin on disc" method and roughness, were also tested. It was found that the laser texturing provides a suitable modification of the structure improving tribological properties. Tests suggest that laser texturing can contribute to the durability of cutting tool’s edge, which qualifies this type of surface treatment for wide industrial applications.
关键词： Laser Induced Periodic Surface Structures (LIPSS),cemented carbides,laser texturing,sialon tool ceramics
更新于2025-09-19 17:13:59