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Organic solar cells based on chlorine functionalized benzo[1,2-b:4,5-ba?2]difuran-benzo[1,2-c:4,5-ca?2]dithiophene-4,8-dione copolymer with efficiency exceeding 13%
摘要： Benzo[1,2-b:4,5-b′]dithiophene (BDT) has been widely used to construct donor-acceptor (D-A) copolymers in organic solar cells (OSCs). However, benzo[1,2-b:4,5-b′]difuran (BDF), an analogue of BDT, has received less attention than BDT. The photovoltaic performance of BDF copolymers has lagged behind that of BDT copolymers. Here, we designed and synthesized two BDF copolymers, PBF1-C and PBF1-C-2Cl. PBF1-C-2Cl, which is composed of BDF and benzo[1,2-c:4,5-c′]dithiophene-4,8-dione connected by a chlorinated thiophene π-bridge, displays a low-lying highest occupied molecular orbital energy level, which helps in yielding a high open-circuit voltage (Voc) in OSCs. As a result, when blended with Y6, PBF1-C-2Cl-based devices showed a high Voc of 0.83 V and a power conversion efficiency (PCE) of 13.10%. To the best of our knowledge, the PCE of 13.10% is among the highest efficiency values for OSCs based on BDF copolymers.
关键词： chlorinated thiophene,π-bridge,benzo[1,2-c:4,5-c′]dithiophene-4,8-dione,benzo[1,2-b:4,5-b′]difuran,organic solar cells
更新于2025-09-19 17:13:59
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Non‐Fullerene Organic Solar Cells Based on Benzo[1,2‐b:4,5‐b′]difuran‐Conjugated Polymer with 14% Efficiency
摘要： The development of high-performance donor polymers is important for obtaining high power conversion efficiencies (PCEs) of non-fullerene polymer solar cells (PSCs). Currently, most high-efficiency PSCs are fabricated with benzo[1,2-b:4,5-b′]dithiophene (BDT)-based conjugated polymers. The photovoltaic performance of benzo[1,2-b:4,5-b′]difuran (BDF)-based copolymers has lagged far behind that of BDT-based counterparts. In this study, a novel BDF-based copolymer L2 is designed and synthesized, in which BDF and benzotriazole (BTz) building blocks have been used as the electron-sufficient and deficient units, respectively. When blending with a non-fullerene small molecule acceptor (SMA), TTPT-T-4F, the L2-based device exhibits a remarkably high PCE of 14.0%, which is higher than that of the device fabricated by its analogue BDT copolymer (12.72%). Moreover, PSCs based on the L2:TTPT-T-4F blend demonstrate excellent ambient stability with 92% of its original PCE remaining after storage in air for 1800 h. Thus, BDF is a promising electron-donating unit, and the BDF-based copolymers can be competitive or even surpass the performance of BDT-based counterparts.
关键词： ambient stability,copolymer,organic solar cells,power conversion efficiency,benzo[1,2-b:4,5-b′]difuran
更新于2025-09-16 10:30:52