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- 2018
- Carbon nanotubes
- Magnetic focused
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- University of British Columbia
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Effect of Zn Content on the physicochemical Characteristics and Photoactivity of ZnO supported Activated Carbon
摘要： In the present work, synthesis of ZnO dispersed onto activated carbon (ZnO/AC) is reported. Synthesis was conducted by using impregnation method by zinc acetate as precursor at varied Zn content. A systematic characterization of ZnO/C materials was performed using XRD, SEM, gas sorption analyzer and diffuse reflectance UV-Visible spectrophotometer. Photoactivity of the materials was studied in phenol removal via photooxidation mechanism. From the study it is confirmed that ZnO dispersion give acceleration of phenol removal refer to surface area contribution. It is no linear correlation of each physical character to the photocatalytic activity.
关键词： ZnO,Activated Carbon,Photocatalyst,Photooxidation
更新于2025-09-04 15:30:14
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Dual?Wavelength Ratiometric Electrochemiluminescence Immunosensor for Cardiac Troponin I Detection
摘要： Ratiometric electrochemiluminescence (ECL) has attracted special focus in biological analysis field because it could eliminate the environmental interference to gain precise measurement. Herein, a dual?wavelength ratiometric ECL biosensor was designed for detection of cardiac troponin I (cTnI), where (4,4’?dicarboxylicacid?2,2’?bipyridyl) ruthenium(II) (Ru(dcbpy)3 2+) and Au nanoparticles loaded graphene oxide/polyethyleneimine (GPRu?Au) nanomaterial acts as an acceptor, and Au nanoparticles modified graphitic phase carbon nitride nanosheets composite (Au?CNN) acts as donor. Au?CNN shows high and steady ECL signal centered at 455 nm, which is well matched with the adsorption of GPRu?Au, thereby a high efficient electrochemiluminescent resonance energy transfer (ECL?RET) sensing platform is designed. AuNPs facilitate the immobilization of antibody on the nanomaterials through Au?N bond. The high surface area of graphene oxide/polyethyleneimine allows a large number of Ru(dcbpy)3 2+ to be loaded, which immensely amplify the ECL signal. This sensing platform exhibits outstanding analytical performance toward cTnI with a detection limit of 3.94 fg/mL (S/N=3). The high reliability, selectivity and sensitivity of this ratiometric ECL biosensor provides a versatile sensing platform for the bioanalysis.
关键词： carbon nitride nanosheets,ECL biosensor,graphene oxide,Ratiometric electrochemiluminescence,cardiac troponin I,Au nanoparticles
更新于2025-09-04 15:30:14
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Estimation of Voxel-Based Above-Ground Biomass Using Airborne LiDAR Data in an Intact Tropical Rain Forest, Brunei
摘要： The advancement of LiDAR technology has enabled more detailed evaluations of forest structures. The so-called “Volumetric pixel (voxel)” has emerged as a new comprehensive approach. The purpose of this study was to estimate plot-level above-ground biomass (AGB) in different plot sizes of 20 m × 20 m and 30 m × 30 m, and to develop a regression model for AGB prediction. Both point cloud-based (PCB) and voxel-based (VB) metrics were used to maximize the efficiency of low-density LiDAR data within a dense forest. Multiple regression model AGB prediction performance was found to be greatest in the 30 m × 30 m plots, with R2, adjusted R2, and standard deviation values of 0.92, 0.87, and 35.13 Mg·ha?1, respectively. Five out of the eight selected independent variables were derived from VB metrics and the other three were derived from PCB metrics. Validation of accuracy yielded RMSE and NRMSE values of 27.8 Mg·ha?1 and 9.2%, respectively, which is a reasonable estimate for this structurally complex intact forest that has shown high NRMSE values in previous studies. This voxel-based approach enables a greater understanding of complex forest structure and is expected to contribute to the advancement of forest carbon quantification techniques.
关键词： LiDAR,voxel,REDD+,volumetric pixel,forest biomass,forest carbon stock,climate change
更新于2025-09-04 15:30:14