- 标题
- 摘要
- 关键词
- 实验方案
- 产品
过滤筛选
- 2018
- Carbon nanotubes
- Magnetic focused
- Field emission cathodes
- Travelling wave tubes
- Heat Trap
- outgassing
- lifetime
- current stability
- cathode
- thermionic emission
- Electronic Science and Technology
- Nanomaterials and Technology
- University of British Columbia
- Beijing Vacuum Electronics Research Institute
- Sun Yat-sen University
-
Design and Mechanism of Embedding Specific Carbon Nanotubes in Sputtered Sandwiched InGaZnO Thin Film Transistors
摘要： Amorphous indium gallium zinc oxide (a-IGZO) thin film transistors (TFTs) with high mobility are highly desirable to achieve high-speed operation in active-matrix displays and large-area sensors. Only a few works provided potential solutions. In this work, we have embedded carbon nanotubes (CNTs) into sputtered a-IGZO film to form a-IGZO/CNT/a-IGZO (ACA) sandwiched channel. In the ACA channel, the CNT percolation networks connected by the a-IGZO film work as high-speed carrier paths to enable faster transport of carriers during the on state while it does not degrade the leakage performance during the off state. The type and the embedding location of the CNT percolation network are critical to determine the ACA device performance, which is analyzed and verified by experiment and simulation. The optimum ACA design has approximately doubled the mobility and the on current density of the TFT. The design owns relatively better uniformity and provides a high-speed TFT solution for the advanced electronics.
关键词： mobility,amorphous indium gallium zinc oxide,carbon nanotube,thin film transistor,sandwiched structure
更新于2025-09-23 15:22:29
-
[IEEE 2018 International Semiconductor Conference (CAS) - Sinaia, Romania (2018.10.10-2018.10.12)] 2018 International Semiconductor Conference (CAS) - Carbon Nanotube/Polyaniline Composite Films Prepared by Hydrothermal- Electrochemical Method for Biosensor Applications
摘要： In this study, CNT-PANI composites were prepared in soft chemical synthesis conditions using hydrothermal method. Our aim is to obtain CNT-PANI films with potential applications in VOC’s detection, using an environmental friendly, low energy consumption technique: hydrothermal-electrochemical deposition of composite films. Thin films were characterized by AFM and FT-IR analyses.
关键词： carbon nanotubes,poly(aniline),composites,biosensor,electrochemical
更新于2025-09-23 15:22:29
-
Preconditioning with carbon monoxide inhalation promotes retinal ganglion cell survival against optic nerve crush via inhibition of the apoptotic pathway
摘要： Optic neurodegeneration, in addition to central nervous trauma, initiates impairments to neurons resulting in retinal ganglion cell (RGC) damage. Carbon monoxide (CO) has been observed to elicit neuroprotection in various experimental models. The present study investigated the potential retinal neuroprotection of preconditioning with CO inhalation in a rat model of optic nerve crush (ONC). Adult male Sprague-Dawley rats were preconditioned with inhaled CO (250 ppm) or air for 1 h prior to ONC. Animals were euthanized at 1 or 2 weeks following surgery. RGC densities were quantified by hematoxylin and eosin (H&E) staining and FluoroGold labeling. Visual function was measured via flash visual evoked potentials (FVEP). Terminal deoxynucleotidyl transferase dUTP nick end labeling (TUNEL) staining, and caspase-9 and caspase-3 activity in the retinas, were assessed at 2 weeks post-ONC. The RGC density of CO + crush rats was significantly increased compared with that of the corresponding crush-only rats at 2 weeks (survival rate, 66.2 vs. 48.2% as demonstrated by H&E staining, P<0.01; and 67.6 vs. 37.6% as demonstrated by FluoroGold labeling, P<0.05). FVEP measures indicated a significantly better-preserved latency and amplitude of the P1 wave in the CO + crush rats compared with the crush-only rats. The TUNEL assays demonstrated fewer apoptotic cells in the CO + crush group compared with the crush-only group, accompanied by the suppression of caspase-9 and caspase-3 activity. The results of the present study suggested that inhaled CO preconditioning may be neuroprotective against ONC insult via inhibition of neuronal apoptosis.
关键词： neuroprotection,optic nerve crush,carbon monoxide,preconditioning,retinal ganglion cell
更新于2025-09-23 15:22:29
-
Tailoring Grain Boundary Chemistry of Polymeric Carbon Nitride for Enhanced Solar H2 Production and CO2 Reduction
摘要： Photocatalytic water splitting is a promising and clean way to mimic the plant photosynthesis in a sustainable manner. Improvements of the quantum efficiency and optical absorption in the relevant range are certainly the further steps to approach practicality. Here, we reported that these issues can be readily addressed when 5-aminotetrazole, a monomer with still higher nitrogen content, is used for the synthesis of carbon nitride. The molten salt mixture NaCl/KCl is used as a high temperature solvent to tailor the grain boundary structure and chemistry. Visible light quantum efficiency for H2 production of 0.65 could be obtained in the presence of K2HPO4 as double layer modifier. This value is very high, considering that this number is a convolute of light to charge couple conversion, charge localization, as well as a successful oxidation and reduction reaction.
关键词： H2 production,Grain boundary,Polymeric carbon nitride,Photocatalysis,Salt melt
更新于2025-09-23 15:22:29
-
Tuning Carbon Dots’ Optoelectronic Properties with Polymers
摘要： Due to their unique properties of photoluminescence, biocompatibility, photostability, ease of preparing, and low cost, carbon dots have been studied extensively over the last decade. Soon after their discovery, it was realized that their main optical attributes may be protected, enhanced, and tuned upon proper surface passivation or functionalization. Therefore, up to date, numerous polymers have been used for these purposes, resulting to higher-quality carbon dots regarding their quantum yield or further emission-related aspects and compared to the primitive, bare ones. Hence, this review aims to clarify the polymers’ role and effect on carbon dots and their features focusing on the quality characteristics of their photoluminescence upon passivation or functionalization. Given in fact the numbers of relevant publications, emphasis is given on recent articles capturing the latest advances for polymers in carbon dots for expanding emission lifetimes, advancing quantum yields, tuning emission wavelengths, enhancing specific spectral range absorption, and tailoring optoelectronic properties in general.
关键词： photoluminescence,functionalization,carbon dots,polymers,optoelectronic properties,surface passivation
更新于2025-09-23 15:22:29
-
Use of Sun-Induced Chlorophyll Fluorescence Obtained by OCO-2 and GOME-2 for GPP Estimates of the Heihe River Basin, China
摘要： Sun-induced chlorophyll ?uorescence (SIF) provides a new method for monitoring vegetation photosynthesis from space and has been widely used to estimate gross primary productivity (GPP). However, the ability of SIF obtained from the Orbital Carbon Observatory 2 (OCO-2 SIF) and Global Ozone Monitoring Experiment-2 (GOME-2) to estimate GPP in the cold and arid region of Heihe River Basin remains unclear because previous comparisons were insuf?cient. Here, we choose maize and alpine meadow to evaluate the performance of SIF obtained by OCO-2 and GOME-2 in GPP estimations. The results of this study show that daily SIF757 had stronger correlations with daily tower GPP than daily SIF771, and the correlation between daily SIF757 and daily tower GPP was stronger than the correlation between 16-d averaged SIF740 and 16-d averaged tower GPP. The 16-d averaged absorbed photosynthetically active radiation (APAR) and reconstructed sun-induced ?uorescence (RSIF) had the strongest linear correlations with 16-d averaged tower GPP. GPP_VPM and GPP_RSIF exhibited the best performance in GPP estimation, closely followed by GPP_SIF757, then GPP_SIF771 and GPP_ SIF740. We also found that the robustness of the correlation coef?cients of OCO-2 SIF with GOME-2 SIF was highly dependent on the size of their spatial footprint overlaps, indicating that the spatial differences between OCO-2 and GOME-2 footprints contribute to the differences in GPP estimates between OCO-2 and GOME-2. In addition, the differences of viewing zenith angle (VZA), cloud contamination, scale effects, and environmental scalars (Tscalar × Wscalar) can result in differences between OCO-2 SIF and GOME-2 SIF.
关键词： vegetation photosynthesis model,eddy covariance,sun-induced ?uorescence,gross primary productivity,carbon cycle
更新于2025-09-23 15:22:29
-
Gas Sensing with Iridium Oxide Nanoparticle Decorated Carbon Nanotubes
摘要： The properties of multi-wall carbon nanotubes decorated with iridium oxide nanoparticles (IrOx-MWCNTs) are studied to detect harmful gases such as nitrogen dioxide and ammonia. IrOx nanoparticles were synthetized using a two-step method, based on a hydrolysis and acid condensation growth mechanism. The metal oxide nanoparticles obtained were employed for decorating the sidewalls of carbon nanotubes. Iridium-oxide nanoparticle decorated carbon nanotube material showed higher and more stable responses towards NH3 and NO2 than bare carbon nanotubes under different experimental conditions, establishing the optimal operating temperatures and estimating the limits of detection and quantification. Furthermore, the nanomaterials employed were studied using different morphological and compositional characterization techniques and a gas sensing mechanism is proposed.
关键词： carbon nanotubes,relative humidity effect,metal nanoparticles,iridium oxide,chemoresistive gas sensor
更新于2025-09-23 15:22:29
-
Multifunctional nanoplatforms for photoacoustic imaging-guided combined therapy enhanced by CO induced ferroptosis
摘要： A multifunctional CO/thermo/chemotherapy nanoplatform is here reported, which is composed of mesoporous carbon nanoparticles (MCN) as near-infrared (NIR)-responsive drug carrier, doxorubicin (DOX) as chemotherapeutic drug and triiron dodecacarbonyl (FeCO) as thermosensitive CO prodrug. The nanoplatform could absorb near-infrared (NIR) light and convert it into ample heat to trigger CO release and could also release DOX in the acidic tumor microenvironment. More importantly, the generated CO molecules successfully increase cancer cell sensitivity to chemotherapeutics by the ferroptosis pathway. Subsequently, under the guidance of photoacoustic imaging, the FeCO-DOX@MCN nanoplatform demonstrates high treatment efficacies in vitro and in vivo by combination of chemotherapy, photothermal therapy and gas therapy. This multifunctional platform with excellent antitumor efficacy has great potential in precision cancer therapy.
关键词： Mesoporous materials,Ferroptosis,Controlled release,Photothermal therapy,Carbon monoxide
更新于2025-09-23 15:22:29
-
Metaheuristic <i>Ab Initio</i> Optimum Search for Doping Effects in Nanocarbons
摘要： We have developed a combined approach of metaheuristic optimization algorithms (MOA), such as the genetic algorithm, with an ab-initio materials simulation engine. Concurrent run of the ab-initio calculations with each different parameter set selected by the MOA searches the optimum condition within a given input-parameter space. Using this methodology, the optimum dopant and its position/structure at a graphene edge are found to be a multiple N-atoms doping at graphitic sites, which predicts to lead to better charging/discharging performance when it is used as an anode material of Li-ion battery.
关键词： genetic algorithm,lithium-ion battery,nano-carbon,ab-initio simulation,doping effect
更新于2025-09-23 15:22:29
-
Carbon Nanomaterials for Bioimaging, Bioanalysis, and Therapy || Functionalized Carbon Nanomaterials for Drug Delivery
摘要： Chemical functionalization of nanomaterials is important to control their physical properties. Since their applications frequently require the homogeneity in the physical properties of the components, many precise functionalization methods for nanomaterials have been developed in view of their applications from electronics and optics to biomedicine. Nanomedicine has been attracting growing interest in terms of therapy and diagnosis, or so called theranostics. In the field, nanomaterials play a key role and hence they are chemically functionalized frequently to meet the requirements for the purpose. In the nanomaterial‐based drug delivery system (DDS), for example, the following functions are required: the nanodrug has to disperse well in the blood to avoid embolism; circulate throughout the body to avoid leaking from the pores in the blood vessel and trapping in the reticuloendothelial system; accumulate in the targeting organ or tissue; and finally, release the loaded drug. Among the nanomaterials in the DDS, carbon nanomaterials have the following characteristic properties: (i) basically inert, but functionizable at the functional groups such as carboxylic and hydroxyl ones on the surface, edge, and defect through organic transformation; (ii) variety of options in terms of shapes including zero‐dimensional (0D, fullerenes), one‐dimensional (1D, carbon nanotubes, CNTs), two‐dimensional (2D, graphene, G), and three‐dimensional (3D, nanodiamond, ND); (iii) commercially available; and (iv) fluorescence emission from semiconducting SWNTs, relatively small size graphenes and color center in ND. The carbon nanomaterials discussed in this chapter are graphene (Section 10.2) and ND (Sections 10.3 and 10.4). Graphene has a flat and hydrophobic surface consisting of sp2 carbons. It exhibits high affinity to the flat molecules, including π‐electrons such as triphenylene, as we reported quite recently. Therefore, it has been utilized as carrier for anti‐cancer drugs with flat and hydrophobic properties. In addition, it can work as photosensitizer in photothermal therapy, making it more fascinating as a bifunctional material in cancer therapy. However, the graphene‐based carriers that have been used so far are graphene oxide (GO), because the carrier is required to have sufficient dispersibility in a physiological environment. The direct use of pristine graphene as a drug carrier, which will be described below, is the first example, as far as we know. On the other hand, ND has been reported to be low toxicity or even nontoxic nanomaterial. It is composed of the curved surface and core, not the flat surface and edge for graphene. As in the case of edge and defect in graphene, the ND surface is covered with various functional groups such as carboxylic and hydroxyl groups. Although ND is categorized as an inorganic nanomaterial due to its robustness and chemical stability, the surface functionalities impart the organic characteristics to ND, enabling the control of the physical property by controlling the surface functionality. Recently, surface chemical functionalization of ND has been actively investigated in view of its applications. In this chapter (Sections 10.3 and 10.4), chemical functionalization on ND for drug carrier will be described; the requisite functions of aqueous dispersibility, targeting specificity, and cytotoxicity are imparted to ND through stepwise surface chemical functionalization. This chapter covers synthesis, characterization, and evaluation of the following three nanodrugs: chlorin e6 (Ce6)‐loaded graphene for cancer phototherapy; Pt drug‐loaded nanodiamond for cancer chemotherapy; and DNA‐loaded nanodiamond for gene therapy.
关键词： nanodiamond,functionalization,drug delivery,graphene,phototherapy,chemotherapy,carbon nanomaterials,gene therapy
更新于2025-09-23 15:22:29