A facile in situ growth of CdS quantum dots on covalent triazine-based frameworks for photocatalytic H2 production

摘要： CdS quantum dots (QDs) are excellent visible-light-driven photocatalysts due to their unique small size (<10 nm), suitable band energy structure, and short charge transportation length. Unfortunately, the easy aggregation of CdS QDs to form larger particles results in a higher recombination rate for photoinduced electron-hole pairs, which deteriorates the photocatalytic activity. Here, we report in situ growth of CdS QDs with high dispersion and stability on covalent triazine-based frameworks (CTFs) via a facile photoreduction method. The photocatalytic H2 evolution activity of CdS QD-loaded CTFs is effectively enhanced to approximately 55 and 4 times than that of pristine CTFs and bulk CdS, respectively. This enhanced photocatalytic performance is mainly ascribed to the higher separation rate of photogenerated carriers resulting from synergistic QD-on-sheet interactions between CdS QDs and CTFs. This work develops an efficient one-pot strategy to prepare metal-sulfide QDs with high dispersion and underlines the potential of utilizing CTFs as a suitable platform to develop efficient photocatalytic systems.