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The combination of Raman imaging and LIBS for quantification of original and degradation materials in Cultural Heritage
摘要： Quantification with nondestructive techniques is not very well developed in the field of Cultural Heritage despite its interest. In the last decades, several works have been published using Raman spectroscopy for quantifying. However, depending on the methodology used, the information provided by this technique is not complete, and the results could lead to misunderstanding when dealing with unknown samples. In this work, a novel double quantification using Raman imaging (its representativeness would be higher than point-by-point analysis) and Laser Induce Breakdown Spectroscopy (LIBS) analyses is presented for analysis of Cultural Heritage samples. Several dolomitic marble samples, with some calcite impurities, covered or not by a calcium oxalate (whewellite, CaC2O4·H2O) layer were analysed in order to optimize the novel methodology. The agreement between the quantitative results from the independent analyses of the Raman Image data and the LIBS data is consistent within the uncertainty arising from both techniques. Further, the same methodology was applied on the same samples but using point-by-point Raman analysis with portable instruments, and portable LIBS information, showing again a great agreement between them and with the results obtained using the laboratory instruments.
关键词： hydrated salts,quantification,Cultural Heritage,LIBS,Raman imaging
更新于2025-09-23 15:23:52
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A multipurpose X-ray fluorescence scanner developed for in situ analysis
摘要： Over the time, instrument transportability has become more and more important, especially in Cultural Heritage, as often artworks cannot be moved from their site, either because of the size or due to problems with permission issues, or simply because moving them to a laboratory is physically impossible, as e.g. in the case of mural paintings. For this reason, the INFN-CHNet, the network for Cultural Heritage studies of the Italian National Institute of Nuclear Physics (INFN), has developed an XRF scanner for in situ analyses. The instrument is the result of a wide collaboration, where different units of the network have been developing the diverse parts, then merged in a single system. The XRF scanner has been designed to be a four-season and green instrument. The control/acquisition/analysis software has been fully developed by our group, using only open-source software. Other strong points of the system are easiness of use, high portability, good performances and ultra-low radiation dispersion, which allows us to use even when the public can be present. It can run both with mains or on batteries, in the latter case with a maximum runtime longer than 10 h. It has a very low cost, when compared to commercial systems with equivalent performances, and easily replaceable components, which makes it accessible for a much wider portion of the interested community. The system has been thought and designed as an open system, suitable for further development/improvements, that can result interesting for non-conventional XRF analysis. The CHNet XRF scanner has proved to be really very well suited for applications in the Cultural Heritage field, as testified by the many recent applications. This paper describes the present version of our instrument and reports on the tests performed to characterise its main features.
关键词： Transportable instrument,XRF imaging,Acquisition,In situ analysis,Cultural heritage,XRF scanner
更新于2025-09-23 15:22:29
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[IEEE 2018 25th IEEE International Conference on Image Processing (ICIP) - Athens, Greece (2018.10.7-2018.10.10)] 2018 25th IEEE International Conference on Image Processing (ICIP) - Realistic Texture Reconstruction Incorporating Spectrophotometric Color Correction
摘要： With the proliferation of high resolution 3D scanners, the quality of recorded 3D models has greatly improved. Nonetheless, while geometric fidelity is important, color information is still required to achieve photo-realistic 3D models. In this regard, texture reconstruction techniques combine color images from several views in order to optimally color the mesh of a 3D model. Nonetheless, a major challenge that is often overlooked by existing approaches is the technical limitations of color acquisition devices that lead to erroneously colored 3D models. In this paper, a novel technique is presented that formulates texture reconstruction as an optimization problem incorporating a color correction term in its objective function. The underlying rationale is to exploit external to the 3D scanner color measurements that can be available from more reliable sensors such as a UV-VIS spectrometer. Such measurements are often available for objects of high aesthetic value such as artworks of cultural heritage objects. Through experimental evaluation of our method on a real painting we demonstrate the superiority of the proposed technique, compared to state-of-the-art texture reconstruction, providing a reliable representation of the artworks appearance both in terms of numerical accuracy and visual observation.
关键词： cultural heritage,3D reconstruction,UV-VIS spectrometer,color correction,Texture reconstruction
更新于2025-09-23 15:22:29
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Er:YAG laser cleaning of a marble Roman urn
摘要： There are very few documented instances of the use of an Er:YAG laser in the cleaning of stone artefacts; however, the cases reported in the literature have shown its effectiveness in the removal of surface organic patinas and lichens. A Roman marble funerary urn (67–100 AD) of archaeological importance was covered with an intractable surface layer that obscured its delicate decorative carving. Chromatographic mass spectrometric and Raman spectroscopic techniques allowed the characterisation of those inorganic and organic materials that had undergone photo-oxidation and biological changes, resulting in the thick encrustation. An Er:YAG laser at 2940nm, with a pulse length of 300μsec, was used for cleaning the urn. Preliminary tests were performed with fluences ranging from 0.7 to 6.4J/cm2 and in the presence of a variety of wetting agents. The laser cleaning resulted in a sufficiently clean marble surface with the thick deposit of unwanted material removed. Finally, the sensitivity of the method allowed for a compact layer of calcium oxalate to be retained on the marble’s surface to help protect it.
关键词： Er:YAG,cultural heritage,wetting auxiliary agent,laser cleaning,calcium oxalate,marble
更新于2025-09-23 15:19:57
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Chemical Analysis in Cultural Heritage || 4. Laser-induced breakdown spectroscopy in heritage science
摘要： Laser-induced breakdown spectroscopy (LIBS) is a versatile analytical technique that can be used to probe the elemental composition of materials in diverse types of heritage samples, objects or monuments. The main physical principles underlying LIBS are presented along with analytical figures of merit and technical details concerning instrumentation. In practice, LIBS analysis does not require any sample preparation and the technique is nearly non-invasive, offering close to microscopic spatial resolution and the possibility for depth profile analysis. These features are, at present, available in a number of compact or transportable instruments that offer versatility and enable the use of LIBS for the analysis of a broad variety of objects/samples at diverse locations and this can be highly valuable at investigations and conservation campaigns. Representative examples are presented indicating how LIBS has been used to obtain compositional information for materials in the context of archaeological science, art history and conservation.
关键词： elemental analysis,cultural heritage,LIBS,laser
更新于2025-09-23 15:19:57
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Influence of the Laser Wavelength on Harmful Effects on Granite due to Biofilm Removal
摘要： The colonization of stone-built monuments by different organisms (algae, fungi, lichens, bacteria, and cyanobacteria) can lead to biodeterioration of the stone, negatively affecting the artistic value of the heritage. To address this issue, laser cleaning has been widely investigated in recent years, due to the advantages it offers over traditional mechanical and chemical methods: it is gradual, selective, contactless, and environmentally friendly. That said, the laser parameters should be optimized in order to avoid any by-effects on the surface as a result of overcleaning. However, as the adjustment of each parameter to clean polymineralic stones is a difficult task, it would be useful to know the effect of overcleaning on the different forming minerals depending on the wavelength used. In this paper, three different wavelengths (355 nm, 532 nm, and 1064 nm) of a Q-Switch neodymium-doped yttrium aluminum garnet (Nd:Y3Al5O12) laser, commonly known as QS Nd:YAG laser were applied to extract a naturally developed sub-aerial biofilm from Vilachán granite, commonly used in monuments in the Northwest (NW)Iberian Peninsula. In addition to the removal rate of the biofilm, the by-effects induced for fluences higher than the damage threshold of the stone were evaluated using stereomicroscopy, color spectrophotometry, and scanning electron microscopy with energy-dispersive x-ray spectroscopy. The results showed that different removal rates were obtained depending on the wavelength used and 532 nm obtained the highest removal level. In terms of by-effects, biotite melting was registered on all surfaces regardless of the wavelength. In addition, 532 nm seemed to be the most aggressive laser system, inducing the greatest change in appearance as a result of extracting the kaolinite crackled coating and the segregations rich in Fe, which are a result of natural weathering. These changes were translated into colorimetric changes visible to the human eye. The surfaces treated with 355 nm and 1064 nm showed lower surface changes.
关键词： laser,granite,stone cleaning,cultural heritage,Nd:YAG,cleaning effectiveness
更新于2025-09-16 10:30:52
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Design and optimization of a laser-PIXE beamline for material science applications
摘要： Multi-MeV proton beams can be generated by irradiating thin solid foils with ultra-intense (>1018 W/cm2) short laser pulses. Several of their characteristics, such as high bunch charge and short pulse duration, make them a complementary alternative to conventional radio frequency-based accelerators. A potential material science application is the chemical analysis of cultural heritage (CH) artifacts. The complete chemistry of the bulk material (ceramics, metals) can be retrieved through sophisticated nuclear techniques such as particle-induced X-ray emission (PIXE). Recently, the use of laser-generated proton beams was introduced as diagnostics in material science (laser-PIXE or laser-driven PIXE): Coupling laser-generated proton sources to conventional beam steering devices successfully enhances the capture and transport of the laser-accelerated beam. This leads to a reduction of the high divergence and broad energy spread at the source. The design of our hybrid beamline is composed of an energy selector, followed by permanent quadrupole magnets aiming for better control and manipulation of the final proton beam parameters. This allows tailoring both, mean proton energy and spot sizes, yet keeping the system compact. We performed a theoretical study optimizing a beamline for laser-PIXE applications. Our design enables monochromatizing the beam and shaping its final spot size. We obtain spot sizes ranging between a fraction of mm up to cm scale at a fraction of nC proton charge per shot. These results pave the way for a versatile and tunable laser-PIXE at a multi-Hz repetition rate using modern commercially available laser systems.
关键词： hybrid beamline and beam manipulation,laser-PIXE,Cultural heritage,particle induced X-ray emission (PIXE),laser-driven proton acceleration,ion beam analysis
更新于2025-09-12 10:27:22
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Study of dry‐ and wet‐process amorphous arsenic sulfides: Synthesis, Raman reference spectra, and identification in historical art materials
摘要： This paper reports the dry and wet synthetic procedures and characterization by Raman spectroscopy of amorphous arsenic sulfide reference pigments. Reference spectra of two amorphous materials obtained by wet process methods and four dry process references of amorphous arsenic sulfide pigments of known composition are presented and discussed. While all materials present a main band characteristic for the amorphous pigment centered on 341 cm?1, additional small contributions indicate the presence of sulfur, arsenic oxide, and crystalline nano phases embedded in the amorphous matrix. Although only the broad 341‐cm?1 peak is necessary to identify the arsenic sulfide as an amorphous material, the smaller additional features allow for the characterization of the various manufacturing processes and initial materials used. In ideal conditions, these small features also enable to assess the As/S ratio of the studied amorphous arsenic sulfide pigments based on their relative intensity. In this context, the latter reference spectra were used to characterize the amorphous arsenic sulfide pigments and their arsenic to sulfur elemental composition in four 18th‐ to 20th‐century historical samples and compared with scanning electron microscopy with energy dispersive X‐ray semiquantitative analyses. The identification of the amorphous arsenic sulfide used in these historical samples was compared with the description of the manufacturing processes reported in historical sources of the time, allowing for a better understanding of the evolution of the amorphous arsenic sulfide pigments manufacturing methods.
关键词： reference spectra,cultural heritage,pigment characterization,synthesis,amorphous arsenic sulfide
更新于2025-09-09 09:28:46
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Hypercolorimetric multispectral imaging system for cultural heritage diagnostics: an innovative study for copper painting examination
摘要： The aim of this work is to test the application of a new multispectral imaging system, named Hypercolorimetric Multispectral Imaging, on two little 17th century oil paintings on copper in order to support the restoration activities. Hypercolorimetric Multispectral Imaging is a non-invasive, rapid and diagnostic technique that allows in situ accurate and reproducible spectral reflectance measurements between 300 nm and 1000 nm to obtain seven monochromatic very high spatial resolution images (36 megapixels starting from RAW format). The acquired images are transformed into radiometric and colorimetric measurements, consisting of 7 monochromatic images of spectral reflectance and one colorimetric image. All these calibrated images constitute the base for further processing performed through a dedicated software that implements a number of functions. In the present paper, a subset of those functions has been used. Specifically: Principal Component Analysis, spectral clustering, spectral mapping, multiband contrast enhancement and edge detection. Combining calibrated images of different spectral regions acquisitions, it was possible to extract relevant information about the state of conservation of the two copper paintings and further significant details were readable compared with the data coming from each single acquisition. The Hypercolorimetric Multispectral Imaging acquisition process revealed to be fast allowing to be performed during the cleaning stage of the paintings. The imaging nature of the analysis allowed to compare and map different areas of the surfaces producing degradation maps of the painting layers, which represents a precious decision-making tool for conservators.
关键词： copper painting examination,non-invasive technique,cultural heritage diagnostics,restoration support,Hypercolorimetric Multispectral Imaging
更新于2025-09-04 15:30:14
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Exploring RGB-D Cameras for 3D Reconstruction of Cultural Heritage
摘要： RGB-D cameras have a great potential to solve several problems arising during the digitization of objects, such as cultural heritage. Three-dimensional (3D) digital preservation is usually performed with the use of high-end 3D scanners, as the 3D points generated by this type of equipment are in average millimeter up to sub-millimeter accurate. The downside of 3D scanners, in addition to the high cost, is the infrastructure requirements. It requires its own source of energy, a large workspace with tripods, special training to calibrate and operate the equipment, and high acquisition time, potentially taking several minutes for capturing a single image. An alternative is the use of low-cost depth cameras that are easy to operate and only require connection to a laptop and a source of energy. There are several recent studies showing the potential of RGB-D sensors. However, they often exhibit errors when applied to a full 360 degrees 3D reconstruction setup, known as the loop closure problem. This kind of error accumulation is intensified by the lower accuracy and large volume of data generated by RGB-D cameras. This article proposes a complete methodology for 3D reconstruction based on RGB-D sensors. To mitigate the loop closure effect, a pairwise alignment method was developed. The proposed approach expands the connectivity graph connections in a pairwise alignment system, by automatically discovering new pairs of meshes with overlapping regions. Then the alignment is more evenly distributed over the aligned pairs, avoiding the loop closure problem of full 3D reconstructions. The experiments were performed on a collection of 30 artworks made by the Baroque artist Antonio Francisco Lisboa, known as Aleijadinho, as part of the Aleijadinho Digital project conducted in partnership with IPHAN (Brazilian National Institute for Cultural and Artistic Heritage) and United Nations Educational, Scientific and Cultural Organization (UNESCO). Experimental results show 3D models that are favorably compared to state-of-the-art methods available in the literature using RGD-D sensors. The main contributions of this work are: a new method for 3D alignment dedicated to attenuate the RGB-D camera loop closure problem; the development and disclosure of a complete, practical solution for 3D reconstruction of artworks; and the construction of 3D digital models of an important and challenging collection of Brazilian cultural heritage, made accessible by a virtual museum.
关键词： global registration,cultural heritage,3D reconstruction
更新于2025-09-04 15:30:14