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Tunable thermo-piezo-plasmonic effect on core/shell nanoparticles under laser irradiation and external electric field
摘要： This work is focused on the characterization of the opto-heating generation in thermo-piezo-plasmonic solutions of gold-PbZrTiO3 (PZT) core/shell nanoparticles. Core/shell nanoparticles have been prepared by the laser ablation in liquid method. Linear and nonlinear optical properties of proposed nanoparticles were studied by optical spectroscopy and the Z-scan technique under external voltage to investigate the piezo-photonic effect. Furthermore, the linear optical properties of these nanostructures were calculated vie dipole approximation method with different core size and different shell thickness of samples immersed in water and poly-vinyl-pyrrolidone. In addition, thermo-plasmonic effects of samples are investigated theoretically and experimentally by the finite element method of COMSOL multiphysics V5.4 and infrared camera under laser irradiation and external electric field. The results revealed a clear tunable and adjustable linear and nonlinear behavior and thermo-piezo-plasmonic properties under external effects. The temperature elevation is ranging of ?T = 3.7–14.1 °C under different external effects. Accordingly, these results encourage to uses proposed samples for the cancer treatment and the different biomedical applications.
关键词： Nonlinear refractive index,External electric field,Core/shell NPs,Laser irradiation,Thermoplasmonic,Piezoelectric,Z-scan technique,Schottky barrier
更新于2025-09-23 15:21:01
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Modulation of the electronic properties of two-dimensional MoTe2/WSe2 heterostructure by electrical field
摘要： The structure and electronic properties of two-dimensional MoTe2/WSe2 van der Waals heterostructure under external electric field have been investigated by first-principles calculation. The interlayer distance between MoTe2 and WSe2 is 3.613? and the binding energy per unit is ?0.183eV, which indicated that MoTe2 is bound to WSe2 via van der Waals interaction. The interlayer distance can be modified by external electric field and the band gap of MoTe2/WSe2 heterostructure continuously decreases with increasing external electric field, eventually a transition from semiconductor to metal is observed, particularly, the band alignment of the MoTe2/WSe2 heterostructure can be effectively tuned from intrinsic type-II to type-I. Applying external electric field along +z direction and ?z direction has different effects on the band gap due to the intrinsic spontaneous polarization in MoTe2/WSe2 heterostructure. Our study indicates that the external electric field can significantly tune the band offsets and modify the band alignment between MoTe2 and WSe2. The present study would be helpful for application of such transition-metal dichalcogenides heterostructures in nano- and optoelectronics.
关键词： band gap,MoTe2/WSe2 heterostructure,external electric field,Density of States
更新于2025-09-09 09:28:46