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Power-law decay in the nonadiabatic photodissociation dynamics of alkali halides due to quantum wavepacket interference
摘要： The nonadiabatic photodissociation dynamics of alkali halide molecules excited by a femtosecond laser pulse in the gas phase are investigated theoretically, and it is shown that the population of the photoexcited molecules exhibits power-law decay with exponent ?1/2, in contrast to exponential decay, which is often assumed in femtosecond spectroscopy and unimolecular reaction theory. To elucidate the mechanism of the power-law decay, a diagrammatic method that visualizes the structure of the nonadiabatic reaction dynamics as a pattern of occurrence of dynamical events, such as wavepacket bifurcation, turning, and dissociation, is developed. Using this diagrammatic method, an analytical formula for the power-law decay is derived, and the theoretical decay curve is compared with the corresponding numerical decay curve computed by a wavepacket dynamics simulation in the case of lithium ?uoride. This study reveals that the cause of the power-law decay is the quantum interference arising from the wavepacket bifurcation and merging due to nonadiabatic transitions.
关键词： quantum wavepacket interference,nonadiabatic photodissociation,alkali halides,power-law decay,femtosecond laser pulse
更新于2025-09-10 09:29:36
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Simultaneous measurements of temperature and pressure with a dual-cavity Fabry-Perot sensor
摘要： A fiber-optic dual-cavity Fabry-Perot interferometric sensor for the simultaneous measurement of temperature and pressure is proposed and experimentally demonstrated. The sensor cascades a fiber-optic intrinsic Fabry–Perot interferometer (IFPI) and an extrinsic Fabry–Perot interferometer (EFPI). The IFPI is used as the temperature sensor and the EFPI is used as the pressure sensor. The pressure sensor is based on a diaphragm-free structure, and can work stably at high temperature. Two optical path differences are interrogated simultaneously by using the fast Fourier transform-based white-light interferometry and the peak-to-peak method. Experimental results show that the proposed sensor exhibits a temperature sensitivity of 29.63 nm/°C within the temperature range of 40-1100 °C, and a pressure sensitivity of 1465.8 nm/MPa within the pressure range of 0-10 MPa at the room temperature.
关键词： pressure measurement,femtosecond laser micromachining,fiber optics sensors,Fabry-Perot interferometers,temperature measurement
更新于2025-09-04 15:30:14
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Temporally Resolving Synchronous Degenerate and Nondegenerate Two-Photon Absorption in 2D Semiconducting Monolayers
摘要： Degenerate and nondegenerate two-photon absorption (TPA) in WS2 and MoSe2 monolayers are synchronously induced and temporally resolved by femtosecond laser pump-probe. Di?erential transmission signals in the ?rst 500 fs consist of negative and positive components, that originate from direct probe depletion via nondegenerate TPA and carrier accumulation via degenerate TPA, respectively. Temporal cross-correlation of pump and probe pulses allows us to fully decouple the ultrafast nondegenerate and degenerate TPA signals. Subsequently, degenerate and nondegenerate TPA coe?cients are calculated as a function of pump irradiance. Under nonresonant pumping, 100 ± 10 and 250 ± 25 cm GW?1 are obtained for degenerate and nondegenerate TPA coe?cients of monolayer WS2, respectively, which both present linearly decreasing trends as increasing pump irradiances. However, under resonant pumping of 2 p excitonic states in monolayer MoSe2, degenerate TPA coe?cients exponentially decrease from 800 to 80 cm GW?1 as increasing pump irradiances, due to the interplay between band-renormalization and band-?lling e?ects, while nondegenerate TPA coe?cient is about 650 ± 50 cm GW?1. For comparison, a trilayer MoSe2 is also investigated. These results set a foundation for precisely measuring TPA coe?cients and actively controlling nonlinear excitonic dynamics via TPA in 2D semiconducting monolayers.
关键词： 2D monolayer,transition metal dichalcogenide,femtosecond laser pump-probe,nondegenerate two-photon absorption,degenerate two-photon absorption
更新于2025-09-04 15:30:14