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Phosphorus incorporation into graphitic material via hot pressing of graphite oxide and triphenylphosphine
摘要： It was shown, that the treatment of graphite oxide (GO) at a temperature of 1000 °C and a static pressure of 500 bar recovers the graphene layers. Addition of triphenylphosphine to GO helps in removal of oxygen during the treatment and allows introducing ca. 0.7 at% of phosphorus in the product. Most phosphorus atoms are bonded with oxygen as the 31P nuclear magnetic resonance spectrum showed. An analysis of the X-ray photoelectron P 2p spectrum additionally found the components corresponding to CeP and PeP bonding. Assembling of phosphorus atoms into nanometer clusters was con?rmed by transmission electron microscopy. Raman spectroscopy and electrical conductivity measurements revealed the n-type doping of graphitic material through the incorporation of phosphorus.
关键词： Triphenylphosphine,XPS,Phosphorus doping,NMR,Hot pressing,Graphite oxide
更新于2025-09-23 15:23:52
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All-Fiber Erbium-doped Q-Switched Laser with Recycled Graphite Oxide
摘要： This work demonstrates a passively Q-Switched fiber laser employing graphite oxide as a saturable absorber, generating tunable microsecond pulses with kHz repetition rates, pulse energies of up to 15.54 nJ and the pulse-to-pulse timing jitter of 46.14 fs. The graphite oxide samples were obtained by recycling the graphite present in Li-ion batteries utilized in cell phone devices through a chemical separation and subsequent oxidation process. Sample characterization employing X-ray diffraction, solid-state nuclear magnetic resonance and Raman spectroscopy showed that the produced graphite oxide exhibited a homogeneously oxidized structure. These results indicate that applications in the physics of pulsed lasers can benefit from the recycling of lithium batteries, directing the process of discarding spent batteries.
关键词： Recycled Graphite Oxide,Lithium Batteries,Erbium-Doped Fiber Laser,Saturable Absorber,Q-Switched
更新于2025-09-12 10:27:22
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WN/nitrogen-doped reduced graphite oxide hybrids for triiodide reduction in dye-sensitized solar cells
摘要： The development of low-cost, environmental friendliness, outstanding catalytic activity, superior conductivity and good stability counter electrode (CE) catalyst in dye-sensitized solar cells (DSSCs) is important to promote the commercial application of DSSCs. Here, WN/nitrogen-doped reduced graphite oxide hybrids (WN/NrGO) had been synthesized by hydrothermal method followed by nitridation treatment, which used as CE catalysts for catalyzing I3? to I?. The combined WN and nitrogen-doped reduced graphite oxide (NrGO) into WN/NrGO could effectively regulate the catalytic activity for the reduction of I3?, accelerate the charge transfer at the interface, and then the synergistic effect between of them can be fully achieved. When the WN/NrGO served as the CE catalyst in DSSCs, the photoelectric conversion efficiency (PCE) of 7.42% has been obtained, compared to the conventional Pt-based DSSCs (7.71%). Meanwhile, as-prepared WN/NrGO exhibited higher PCE than that of the solo WN (6.19%) and NrGO (5.81%) in parallel. A series of electrochemical measures revealed that the WN/NrGO displayed the higher catalytic activity and charge transfer ability than that of the solo WN and NrGO, so the synthesized low-cost WN/NrGO have an potential to be used as the effectively CE catalysts for the replacement of the noble Pt.
关键词： Dye-sensitized solar cells,Triiodide reduction,Counter electrode,WN/nitrogen-doped reduced graphite oxide
更新于2025-09-12 10:27:22