A Novel Anion Doping for Stable CsPbI <sub/>2</sub> Br Perovskite Solar Cells with an Efficiency of 15.56% and an Open Circuit Voltage of 1.30 V

摘要： Currently, the efficient preparation of imines is still a great challenge under mild conditions. In this article, by incorporating 2-acetylpyridine thiosemicarbazone (HL), Co(NO3)2·6H2O and Na2MoO4·2H2O, a new compound [Co(L)2]2[Mo6O19] (1) was prepared and characterized by elemental analysis (EA), infrared (IR) spectra, ultraviolet–visible (UV–Vis) spectra, powder X-ray diffractometry (PXRD) spectra, X-ray photoelectron spectroscopy (XPS) and X-ray single-crystal diffraction. 1 could be used as a heterogeneous catalyst for oxidative coupling of amines in a comparatively mild condition. Furthermore, 1 exhibited remarkable catalytic performance for oxidation coupling of amines to imines with high yield in the presence of tert-butyl hydroperoxide (TBHP) (up to 92%). Kinetic measurements of the oxidation of benzylamine suggest that the rate law is r = k′[BnNH2][TBHP] (k′ = k[cat] = 0.2338 L mol?1 h?1). Additionally, 1 can be recycled at least three times without a distinct loss of activity.