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Optical Band Gap, Local Work Function and Field Emission Properties of MBE Grown β-MoO3 Nanoribbons
摘要： Monoclinic molybdenum trioxide (β-MoO3) nanostructures (shaped like nanoribbons: NRs) were grown on Si(100), Si(5512) and fluorine-doped tin oxide (FTO) by molecular beam epitaxy (MBE) technique under ultra-high vacuum (UHV) conditions. The dependence of substrate conditions and the effective thickness of MoO3 films on the morphology of nanostructures and their structural aspects were reported. The electron microscopy measurements show that the length and the aspect ratio of nanostructures increased by, 260% without any significant change in the width for a change in effective thickness from 5 nm to 30 nm. NRs are grown along <011> for all the effective thickness of MoO3 films. Similarly, when we increased the film thickness from 5 nm to 30 nm, the optical band gap decreased from 3.38± 0.01eV to 3.17± 0.01eV and the local work function increased from 5.397 ± 0.025 eV to 5.757 ± 0.030 eV. Field emission turn-on field decreased from 3.58 V/μm for 10-μA/cm2 to 2.5 V/μm and field enhancement factor increased from 1.1×104 to 5.9×104 for effective thickness variation of 5 nm to 30 nm β-MoO3 structures. The β-MoO3 nanostructures found to be much better than the α-MoO3 nanostructures due to low work function, low turn on field and high field enhancement factor, and are expected to be useful applications.
关键词： β-MoO3 nanostructures,Field emission and Kelvin probe force microscopy (KPFM),Optical band gap,Molecular beam epitaxy (MBE),Electron microscopy
更新于2025-09-23 15:22:29
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Implementation of data-cube pumpa??probe KPFM on organic solar cells
摘要： An implementation of pump–probe Kelvin probe force microscopy (pp-KPFM) is reported that enables recording the time-resolved surface potential in single-point mode or over a 2D grid. The spectroscopic data are acquired in open z-loop configuration, which simplifies the pp-KPFM operation. The validity of the implementation is probed by measurements using electrical pumping. The dynamical photoresponse of a bulk heterojunction solar cell based on PTB7 and PC71BM is subsequently investigated by recording point-spectroscopy curves as a function of the optical power at the cathode and by mapping 2D time-resolved images of the surface photovoltage of the bare organic active layer.
关键词： Kelvin probe force microscopy (KPFM),time-resolved measurements,bulk heterojunctions,organic photovoltaics,pump–probe configuration,photocarrier dynamics
更新于2025-09-16 10:30:52