- 标题
- 摘要
- 关键词
- 实验方案
- 产品
-
Toward the laser control of electronic decoherence
摘要： Controlling electronic decoherence in molecules is an outstanding challenge in chemistry. Recent advances in the theory of electronic decoherence [B. Gu and I. Franco, J. Phys. Chem. Lett. 9, 773 (2018)] have demonstrated that it is possible to manipulate the rate of electronic coherence loss via control of the relative phase in the initial electronic superposition state. This control emerges when there are both relaxation and pure-dephasing channels for decoherence and applies to initially separable electron–nuclear states. In this paper, we demonstrate that (1) such an initial superposition state and the subsequent quantum control of electronic decoherence can be created via weak-field one-photon photoexcitation with few-cycle laser pulses of definite carrier envelope phase (CEP), provided the system is initially prepared in a separable electron–nuclear state. However, we also demonstrate that (2) when stationary molecular states (which are generally not separable) are considered, such one-photon laser control disappears. Remarkably, this happens even in situations in which the initially factorizable state is an excellent approximation to the stationary state with fidelity above 98.5%. The laser control that emerges for initially separable states is shown to arise because these states are superpositions of molecular eigenstates that open up CEP-controllable interference routes at the one-photon limit. Using these insights, we demonstrate that (3) the laser control of electronic decoherence from stationary states can be recovered by using a two-pulse control scheme, with the first pulse creating a vibronic superposition state and the second one inducing interference. This contribution advances a viable scheme for the laser control of electronic decoherence and exposes a surprising artifact that is introduced by widely used initially factorizable system-bath states in the field of open quantum systems.
关键词： electronic decoherence,few-cycle laser pulses,laser control,carrier envelope phase,vibronic superposition state,quantum control
更新于2025-09-23 15:21:01
-
Laser control of molecular rotation: Expanding the utility of an optical centrifuge
摘要： Since its invention in 1999, the optical centrifuge has become a powerful tool for controlling molecular rotation and studying molecular dynamics and molecular properties at extreme levels of rotational excitation. This technique has been applied to a variety of molecular species, from simple linear molecules to symmetric and asymmetric tops, to molecular ions and chiral enantiomers. Properties of isolated ultrafast rotating molecules, the so-called molecular superrotors, have been investigated, as well as their collisions with one another and the interaction with external fields. The ability of an optical centrifuge to spin a particular molecule of interest depends on both the molecular structure and the parameters of the centrifuge laser pulse. An interplay between these two factors dictates the utility of an optical centrifuge in any specific application. Here, we discuss the strategy of assessing and adjusting the properties of the centrifuge to those of the molecular rotors and describe two practical examples of optical centrifuges with very different characteristics, implemented experimentally in our laboratory.
关键词： laser control,molecular rotation,molecular dynamics,molecular superrotors,optical centrifuge
更新于2025-09-23 15:21:01
-
Design of a laser control system with continuously variable power and its application in additive manufacturing
摘要： system adjusts the laser position. This paper will also discuss the development and advanced laser control techniques enable a higher level of control over the processing process relies heavily on understanding and controlling the thermodynamics of the polymer melt temperatures and lead to more uniform components. Currently, there are no commercial options for a laser power controller that allows continuously variable power to be used as a galvanometer process. One of the biggest challenges SLS faces is lack of adequate process control, which leads to comparatively high component variations. It has been shown that implementing more manufacturing processes with applications in aerospace, biomedical, tooling, prototyping, and beyond. SLS is capable of creating unique, functional parts with little waste and no tooling by using a high-powered laser to selectively melt powdered polymer into desired shapes. This Selective laser sintering (SLS) is one of the most popular industrial polymer additive implementation of a galvanometer controller solution that works in conjunction with an off-the-shelf unit to enable this crucial functionality and will present results showing that, when applied laser sintering (SLS) additive manufacturing. The work contained in this paper is a continuation of previous work that developed a method of controlling laser power is SLS in order to improve the consistency of components built [1]. This previous effort was capable of improving temperature uniformity of SLS components by up to 57% and strength uniformity by up to 45%. Powder Bed Fusion
关键词： Laser Control,Additive Manufacturing,Surrogate Modeling,Powder Bed Fusion,Process Control
更新于2025-09-23 15:19:57
-
Laser-Based Phase Contrast for Transmission Electron Microscopy
摘要： Laser control of free electrons has been used to advance the exploration of matter on the atomic scale. For example, temporal modulation of electron waves with light has enabled the study of transient processes with attosecond resolution. By contrast, laser-based spatial shaping of the electron wave function has not yet been realized, even though it could be harnessed to probe radiation-sensitive systems, such as biological macromolecules, at the standard quantum limit and beyond. We demonstrate increased image contrast by laser control of the spatial phase profile of the electron wave function in transmission electron microscopy (TEM). We first realize an electron interferometer, using continuous-wave laser-induced retardation to coherently split the electron beam, and capture TEM images of the light wave. We then demonstrate Zernike phase contrast by using the laser beam to shift the phase of the electron wave scattered by a specimen relative to the unscattered wave. Electrons interact with light via the repulsive ponderomotive potential arising from stimulated Compton scattering. Due to the short electron-light interaction time in a micron-scale laser focus, retardation of the relativistic electrons used in TEM requires an intensity of tens of GW/cm2. Such intensities have so far only been attained with pulsed lasers, but a cw laser is needed in order to work state-of-the-art, continuously operating TEM. The requisite laser intensity is generated by 4000-fold resonant power enhancement in a near-concentric Fabry-Perot optical cavity with a mode waist of w0 = 13 μm. A laser system consisting of a fiber amplifier seeded by a low-power master laser supplies an input laser beam at a wavelength of λ = 1064 nm. The experiments are carried out with 80 keV electrons, in a custom-modified TEM (FEI Titan) equipped with additional electron optics that magnify the diffraction pattern to an effective focal length of f = 20 mm. The cavity is suspended in the TEM column, with its axis orthogonal to the electron beam propagation direction and with the mode waist positioned close to the center of the magnified electron diffraction plane, as shown in Fig. 1. Zernike phase contrast is evident in a typical close-to-focus image (Fig. 1), showing the structure of the carbon film. A high-intensity CW laser field generates Zernike phase contrast in a TEM and significantly increases the image contrast at low spatial frequencies. Such a phase plate will enable dose-efficient data collection in single-particle analysis of biological macromolecules, electron tomography of vitrified cells, and imaging of sensitive materials science specimens. The controllable phase shift in this device can also be used for holographic reconstruction of the post-specimen wave function. Work in the immediate future will include working with 300-keV electrons, which requires constructing a new cavity with lower-loss optical coatings to reach higher laser intensity. We will also study and optimize the imaging properties of the phase-contrast TEM, and apply it to structural biology.
关键词： Zernike phase contrast,Laser control,Fabry-Perot optical cavity,Transmission Electron Microscopy,electron wave function
更新于2025-09-19 17:13:59