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Laser-Writing of Janus Graphene/Kevlar Textile for Intelligent Protective Clothing
摘要： Protective clothing plays a vital role in safety and security. Traditional protective clothing can protect human body from physical injure. It is highly desired if modern wearable electronics can be integrated into traditional protection suit to endow it with versatile smart functions. However, it is still challenging to integrate electronics into clothing through a practical approach while keeping the intrinsic flexibility and breathability of textiles. In this work, we realized the direct writing of laser-induced graphene (LIG) on Kevlar textile in air and demonstrated the applications the as-prepared Janus graphene/Kevlar textile in intelligent protective clothing. The C=O and N?C bonds in Kevlar were broken and the remaining carbon atoms were reorganized into graphene, which can be ascribed to photothermal effect induced by the laser irradiation. Proof-of-concept devices based on the prepared graphene/Kevlar textile, including flexible Zn-air batteries, electrocardiogram electrodes, and NO2 sensors, were demonstrated. Furtherly, we fabricated a self-powered and intelligent protective clothing based on the graphene/Kevlar textile. The laser induced direct writing of graphene from commercial textiles in air conditions provides a versatile and rapid route for the fabrication of textile electronics.
关键词： laser-induced graphene,Kevlar textile,NO2 sensor,textile electronics,photothermal effect
更新于2025-09-23 15:19:57
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Morphological Evolution Induced through Heterojunction of W-decorated NiO Nanoigloos: Synergistic Effect on High-performance Gas Sensors
摘要： Morphological evolution accompanying a surface roughening and the preferred orientation is an effective way to realize a high-performance gas sensor because of its significant potential as a chemical catalyst by chemical potentials and atomic energy states. In this work, we investigated the heterojunction of both-sided W-decorated NiO nanoigloos fabricated through RF sputtering and a soft-template method. Interestingly, the morphological evolution characterized by a pyramidal rough surface and the preferred orientation of the (111) plane was observed upon decorating the bare NiO nanoigloos with W. The underlying mechanism of the morphological evolution was precisely demonstrated based on a van der Drift competitive growth model originating from the oxygen transport and chemical strain in a lattice. The gas sensing properties of W-decorated NiO show an excellent NO2 response and selectivity when compared to other gases. In addition, high response stability was evaluated under interference gas and humidity condition. The synergistic effects on the sensing performance were interpreted based on the morphological evolution of W-decorated NiO nanoigloos.
关键词： Gas sensor,Nanostructure,Morphological evolution,Heterojunction,NO2
更新于2025-09-19 17:15:36
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Characterization and NO2 gas sensing performance of CdO:In2O3 polycrystalline thin films prepared by spray pyrolysis technique
摘要： Polycrystalline CdO:In2O3 thin films for gas sensor applications were prepared on glass and silicon substrates by using one-step spray pyrolysis technique from the aqueous solution of CdCl2 and InCl3 at a substrate temperature of 300 °C. The structure, surface morphology, and the optoelectronic properties of prepared films were characterized respectively by means of X-ray diffraction (XRD), atomic force microscope and UV–visible spectroscopy. Based on the XRD results, the polycrystalline nature of CdO films has been confirmed, and In2O3 films were found to exhibit a preferred orientation along (222) diffracted plane. The grain size varies between 9.0 and 28.4 nm. The results of Hall effect measurement of CdO:In2O3 thin films confirms that all films were an n-type semiconductor. The electrical properties of prepared thin films and their sensitivity to nitrogen dioxide (NO2) gas are also studied. The influence of the operating temperature and In2O3 concentration on the NO2 response were investigated. It is found that all films are sensitive to NO2 gas, and the ideal operating temperature for the film contented 20 vol% of In2O3 was found to be 200 °C at a gas concentration of 25 ppm. The sensing mechanism of the CdO:In2O3 thin film is discussed and attributed to electron transfer between the sensing element and NO2 molecules.
关键词： NO2 gas sensor,Sensitivity,Optoelectronic properties,Structural,Morphology,Metal-oxide semiconductors
更新于2025-09-19 17:15:36
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Facile and <i>in-situ</i> spray deposition of SnO <sub/>2</sub> – reduced graphene oxide heterostructure sensor devices
摘要： A facile and economic solution based technique is developed for the deposition of SnO2 – Reduced Graphene Oxide (RGO) heterostructure thin films. The single step deposition process leads to uniformly coated films of SnO2 nanocrystallites on well exfoliated RGO sheets as confirmed by xray diffraction, Raman spectroscopy and transmission electron microscopy investigations. The response to NO2 gas at room temperature (25 oC) is studied. The interface between n-type SnO2 and p-type RGO flakes forms a hetrostrcuture barrier, which enhances the native sensitivity of pristine RGO towards toxic gases like NO2. The technique allows controlling the density of SnO2 nanoparticles (~3 nm in size) attached to the RGO flakes and thereby enhancing the response of the heterostructure sensor device. The highest SnO2 loading shows a 14 fold increase in response to 200 ppm of NO2 and a response time as low as 5 sec compared to that of ~200 sec for bare RGO films.
关键词： tin oxide,thin films,Reduced graphene Oxide,heterostructure,NO2 sensing
更新于2025-09-19 17:15:36
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NO<sub>2</sub> gas sensing performance enhancement based on reduced graphene oxide decorated V<sub>2</sub>O<sub>5</sub> thin film
摘要： Here, we demonstrate the improved NO2 gas sensing properties based on reduced graphene oxide (rGO) decorated V2O5 thin film. Excluding the DC sputtered grown V2O5 thin film, rGO was spread over V2O5 thin film by drop cast method. The formation of several p-n heterojunctions is greatly affected by the current-voltage relation of rGO decorated V2O5 thin film due to p-type and n-type nature of rGO and V2O5, respectively. Initially with rGO decoration on V2O5 thin film, current decreases in comparison to V2O5 thin film, whereas depositing rGO film on glass substrate, current increases drastically. Among all sensors, only rGO decorated V2O5 sensor revealed maximum NO2 gas sensing response for 100 ppm at 150°C, and helped achieve approximately 61% times more response than the V2O5 sensor. An elaborated mechanism for an extremely high sensing response is attributed to the formation and modulation of p-n heterojunction at the interface of rGO and V2O5. In addition, the presence of active sites like oxygenous functional groups on rGO surface also enhances the sensing response. On that account, the sensor based on rGO decorated V2O5 thin film is highly suitable for the purpose of NO2 gas sensing. This enables timely detection of the gas, further prevent the ecosystem from its harmful effects.
关键词： NO2 gas,relative response,DC sputtering,p-n heterojunction,rGO decorated V2O5 thin film
更新于2025-09-19 17:15:36
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Thin film chemiresistive gas sensor on single-walled carbon nanotubes-functionalized with polyethylenimine (PEI) for $${\hbox {NO}}_{2}$$NO2 gas sensing
摘要： Chemical detection of toxic gases, such as greenhouse gases is still very important as a research topic. To design gas sensor detectors based on single-walled carbon nanotubes (SWCNTs) with high sensitivity and selectivity for the toxic environment is a continuous process. The aim is to detect NO2 gas with better sensitivity. In the present work, the thin-film sensor is fabricated on SiO2 substrate and it is functionalized with polyethylenimine (PEI). It has been established that PEI functionalized SWCNTs (F-SWCNTs) show high sensitivity towards strong electron-withdrawing particles. It was found that at room temperature, SWCNTs-PEI functionalized gas sensor exhibited a higher sensitivity of 37.00% as compared with bare SWCNTs gas sensor. The gas sensor has shown the repeatable response for the entire concentration range studied. The sensing properties and the PEI functionalization duration effects on the behaviour of SWCNTs-based gas sensors were demonstrated.
关键词： NO2,Carbon nanotubes,sensor,polyethylenimine (PEI)
更新于2025-09-19 17:13:59
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Multifunctional inorganic nanomaterial aerogel assembled into fSWNT hydrogel platform for ultraselective NO2 sensing
摘要： Facile fabrication of multifunctional porous inorganic aerogels remains an outstanding challenge despite the considerable demand for extensive applications. Here, we present the production of a multifunctional porous inorganic nanomaterial aerogel by controllable surface chemistry of a functionalized SWNT (fSWNT) hydrogel platform for the first time. The versatile functional inorganic nanoparticles can be incorporated uniformly on the porous 3D fSWNT hydrogel platform through a facile dip coating method at ambient conditions. The morphology of the multifunctional inorganic aerogel is manipulated by designing the fSWNT hydrogel platform for different requirements of applications. In particular, Pt-SnO2@fSWNT aerogels exhibit high porosity and uniformly distributed ultrafine Pt and SnO2 on the fSWNT platform with controllable particle size (1.5–3.5 nm), which result in significantly high surface area (393 m2 g-1). The ultrafine Pt-SnO2@fSWNT aerogels exhibit highly sensitive (14.77% at 5 ppm) and selective NO2 sensing performance even at room temperature due to the increased active surface area and controllable porous structure of the ultrafine aerogel, which can provide fast transport and penetration of a target gas into the sensing layers. The newly designed multifunctional inorganic aerogel with ultrahigh surface area and high open porosity is a prospective materials platform of high performance gas sensors, which could be also broadly expanded to widespread applications including catalysis and energy storages.
关键词： fSWNT hydrogel platform,room temperature sensor,ultraselective NO2 gas sensing,Pt-SnO2@fSWNT aerogel,Multifunctional ultrafine inorganic aerogel
更新于2025-09-19 17:13:59
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rGO modified nanoplate-assembled ZnO/CdO junction for detection of NO2
摘要： The triadic composite of ZnO/CdO heterojunction decorated with reduced graphene oxide (rGO) was prepared using a one-step hydrothermal method. The characterizations of morphology, structure and composition to the composite were undertaken by XRD, Raman, SEM, TEM, XPS, UV-vis spectra. The sensing experimental data indicate that the highest response of the ZnO/CdO/rGO (1.0 wt%) composite to ppm-level NO2 is 8 times and 2 times higher than pure ZnO and ZnO/CdO junction, respectively. The composite not only exhibits fast response time and recovery time, high response, but also reveals outstanding stability and repeatability at an operating temperature of 125°C. The sensing mechanism also has been discussed in detail in the work. The enhancement in gas sensing properties is credited to the development of ZnO/CdO heterojunction and the decoration of rGO with high conductivity. The logarithm of sensitivity in the range of 0.4-2.4 ppm NO2 shows good linear dependence, indicating that the composite based sensor can be used to quantificationally detect low concentration of NO2.
关键词： Graphene,NO2,rGO,ZnO/CdO,Gas sensor
更新于2025-09-16 10:30:52
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WO3 processed by direct laser interference patterning for NO2 detection
摘要： In this paper two kind of sensors based on WO3 sputtered by magnetron sputtering and annealed at 600°C have been studied. The first kind was processed by two-dimensional direct laser interfering patterning (DLIP) and the second one without any additional treatment. Morphological and structural characterization have shown a hole structure in a periodic line-pattern for the DLIP-processed sensors and a flat surface for the only-annealed sensors, both with a tetragonal WO3 phase. TOF-SIMS analysis has revealed that the first WO3 layers are reduced for both samples, which could improve sensing performance. Promising response enhancement of DLIP-processed sensors has been observed for low concentrations of NO2 (from 0.5 ppm to 5 ppm) at 200°C, lowering the limit of detection (LOD) to 10 ppb, half of the LOD of the only-annealed sensors (20 ppb). Cross sensitivity to CO and HCHO have been investigated and the sensing mechanisms discussed.
关键词： Arrhenius,WO3,NO2,TOF-SIMS,tetragonal phase,DLIP
更新于2025-09-16 10:30:52
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Computation-led design of pollutant gas sensors with bare and carbon nanotube supported rhodium alloys
摘要： Quantum chemical study has been performed on finite-sized bi-metallic Rh3M alloys, M = Ag, Ir, Pd, Pt, Au, derived from magic cluster, Rh4. Bond length of C–O and N–O are noticed to be elongated in the presence of rhodium alloy clusters. CO2 and NO2 gases are found to be highly adsorbed on Rh3M clusters, which is confirmed by stretching frequency of C–O and N–O. DFT evaluated dipole moment and electronic charge redistribution suggests the sensing capability of CO2 and NO2 gases by Rh3M clusters which is further confirmed by the calculated HOMO–LUMO gap. Mixed rhodium alloy clusters supported on single-wall carbon nanotube (SWCNT) exhibits much higher ability to sense CO2 and NO2. On the other hand, SWCNT@Rh3M shows higher catalytic activity for the activation of CO2 and NO2 in comparison to bare Rh3M because of the higher electronic charge redistribution in the case of SWCNT@Rh3M. In case of SWCNT-supported gas adsorbed clusters, p electrons play a major role in bonding.
关键词： SWCNT,Rhodium,DFT,Alloy,CO2,NO2
更新于2025-09-16 10:30:52