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High Responsivity and High Rejection Ratio Self-Powered Solar-Blind Ultraviolet Photodetector Based on PEDOT:PSS/β-Ga2O3 Organic/Inorganic p-n Junction
摘要： A high responsivity self-powered solar-blind deep UV (DUV) photodetector with high rejection ratio was proposed based on inorganic/organic hybrid p-n junction. Owing to the high crystalized β-Ga2O3 and excellent transparent conductive polymer PEDOT:PSS, the device exhibited ultrahigh responsivity of 2.6 A/W at 245 nm with a sharp cut off wavelength at 255 nm without any power supply. The responsivity is much larger than that of previous solar-blind DUV photodetectors. Moreover, the device exhibited an ultrahigh solar-blind/UV rejection ratio (R245 nm /R280 nm) of 103, which is two orders of magnitude larger than the average value ever reported in Ga2O3-based solar-blind photodetectors. In addition, the photodetector shows a narrow band-pass response of only 17 nm in width. This work might be of great value in developing high wavelength selective DUV photodetector with respect to low cost for future energy-efficient photoelectric devices.
关键词： Self-Powered,PEDOT:PSS/β-Ga2O3,Plasmonics and Optoelectronics,Organic/Inorganic p-n Junction,Energy Conversion and Storage,High Rejection Ratio,High Responsivity,Solar-Blind Ultraviolet Photodetector
更新于2025-09-19 17:13:59
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A solid-state integrated photo-supercapacitor based on ZnO nanorod arrays decorated with Ag <sub/>2</sub> S quantum dots as the photoanode and a PEDOT charge storage counter-electrode
摘要： A planar solid-state photocapacitor with two electrodes has been prepared for the first time using a passivated film of ZnS with Ag2S quantum dots deposited on ZnO nanorods, which were electrochemically grown on ZnO seed layers, as the photoanode. The supercapacitor part is composed of a electrodeposited poly(3,4-ethylene-dioxythiophene) PEDOT film as the counter-electrode and an ionic liquid-based electrolyte between them deposited by the dip coating method. The different nanostructures and electrodes were morphologically and structurally characterized, and the device was electrochemically characterized and could reach a potential of 0.33 V during photocharge and a storage efficiency of 6.83%.
关键词： solid-state,ZnO nanorod arrays,electrochemical characterization,PEDOT,photo-supercapacitor,Ag2S quantum dots
更新于2025-09-19 17:13:59
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Modifying the nanostructures of PEDOT:PSS/Ti3C2TX composite hole transport layers for highly efficient polymer solar cells
摘要： Two-dimensional (2D) transition metal carbides MXene, typically represented by Ti3C2TX, have shown great promise in optoelectronic devices due to their metallic electrical conductivity, large surface area, superior hydrophilicity and excellent transparency. Herein, to improve the conductivity of polymer poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) film, we incorporate solution-processable 2D Ti3C2Tx nanosheets into PEDOT:PSS to fabricate PEDOT:PSS/Ti3C2TX composite layers, and polymer solar cells (PSCs) with PEDOT:PSS/Ti3C2TX composite films as hole transport layers (HTLs) are fabricated for the first time. The nanostructures and the corresponding hole injection properties of PEDOT:PSS/Ti3C2TX composite layers are systematically evaluated. Based on the non-fullerene PBDB-T:ITIC system, a power conversion efficiency (PCE) of 11.02% is obtained for the device with PEDOT:PSS/Ti3C2TX as HTL, which is improved by 13.5% than that of the control device with pure PEDOT:PSS as HTL (9.72%). When using the PM6:Y6 system as the active layer, the PCE of the device based on PEDOT:PSS/Ti3C2TX is improved to 14.55% from 13.10% for the PEDOT:PSS reference device. 2D Ti3C2TX nanoflakes with higher conductivity constructing additional charge transfer pathways between the PEDOT nanocrystals and inducing conformational transition of PEDOT from a coil to a liner/expanded-coil structure, leading to the conductivity and device performance improvement. Interestingly, PEDOT:PSS/Ti3C2TX based devices also exhibit enhanced long-term stability than PEDOT:PSS based device. These results show that PEDOT:PSS/Ti3C2TX composite film has a promising prospect in high efficiency organic optoelectronics.
关键词： PEDOT:PSS/Ti3C2Tx composite film,hole injection property,improved conductivity,polymer solar cells,hole transport layer
更新于2025-09-19 17:13:59
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Highly conductive PEDOT:PSS electrode obtained via post-treatment with alcoholic solvent for ITO-free organic solar cells
摘要： We demonstrated a simple and effective processing protocol to improve the electrical conductivity of poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) films via post-treatment with an alcohol-based solvent, 2-chloroethanol (2-CE), and to enhance their performance as a transparent anode in organic photovoltaic cells (OPVs). Owing to its moderate boiling point, in contrast to previously reported chemicals, 2-CE is advantageous both for handling as a liquid-phase chemical and for drying from the films via evaporation. We compared the optical and electrical properties of the 2-CE-treated PEDOT:PSS with those of standard PEDOT:PSS-based electrodes with the addition of 5 vol% dimethyl sulfoxide (DMSO). With a similar thickness and transmittance in the visible region, the 2-CE-treated polymer electrodes outperformed the DMSO-added films with regard to the electrical conductivity (762 S cm-1 vs. 439 S cm-1). The work functions were almost identical: ~5 eV. We fabricated and characterized organic photovoltaic devices using the anodes and polymer:fullerene blends and found that the 2-CE treatment resulted in higher device performance. Additionally, the 2-CE treatment was applicable to OPVs on a flexible plastic substrate, indicating the effectiveness of the proposed protocol.
关键词： solvent treatment,PEDOT:PSS,organic photovoltaics,transparent electrode,conductive polymer
更新于2025-09-19 17:13:59
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Inverted Perovskite Solar Cells Based on Small Molecular Hole Transport Material C <sub/>8</sub> ‐BTBT
摘要： The small organic molecular Dioctylbenzothienobenzothiophene (C8-BTBT) has been explored as hole transport material (HTM) to replace PEDOT:PSS in inverted perovskite solar cells (PVSCs). MAPbI3 perovskite films depositd onto C8-BTBT are smooth and uniform, with negligible residual of PbI2 and large grain size even larger than 1 μm. Our champion C8-BTBT based devices reached a high power conversion efficiency (PCE) of 15.46% with marginal hysteresis, much higher than that of 11.50% achieved using PEDOT:PSS. Besides, device adopting C8-BTBT as substrate show superior stability compared with the PEDOT:PSS based devices when stored under ambient conditions with a relative humidity of 25±5%.
关键词： perovskite solar cells,stability,PEDOT:PSS,hole transport material,C8-BTBT
更新于2025-09-19 17:13:59
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Charge transfer in Nanowire-Embedded PEDOT:PSS and Planar Heterojunction Solar Cells
摘要： Hybrid metallic nanowires-embedded, highly conductive poly(3,4-ethylenedioxy thiophene):polystyrenesulfonate (PEDOT:PSS) with synergetic properties is indispensable for enhancing the performances of conductive polymer-based electronic devices. Here we report embedment of silver nanowires (AgNWs), with diameter ~100 nm and a high concentration (500 mg/ml) of nanowires dispersed in either ethanol or isopropanol, in PEDOT:PSS and compare the effects of the nanowire-dispersing solvents as well as its thicker diameter and high concentration on the overall properties, and particularly its charge transfer characteristics and planar heterojunction solar cell (HSC) properties. Furthermore, electrostatic force microscopy is applied to elucidate the direct charge transfer from AgNWs to the PEDOT:PSS matrix. The AgNW-embedded PEDOT:PSS-based planar HSCs show a very high open-circuit voltage of over 638 mV and a high power conversion efficiency greater than 15.3%, and without any significant influence from the AgNWs dispersing solvents. While charge transfer in PEDOT:PSS without AgNWs occurs through the conducting PEDOT grains, enhanced charge transfer is realized in AgNW-embedded PEDOT:PSS with charge transport from PEDOT grains to AgNWs and then to PEDOT grains before reaching the top electrode in the HSC. The AgNW-embedded PEDOT:PSS hybrid materials pave a simple way to enhance the charge transfer performance in not only HSCs but also other hybrid or heterojunction electronics.
关键词： heterojunction solar cell,poly(3,4-ethylenedioxy thiophene):polystyrenesulfonate or PEDOT:PSS,silver nanowire,Conducting polymer,electrostatic force microscopy,charge transfer
更新于2025-09-19 17:13:59
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All-solution Processed High Performance Inverted Quantum Dot Light Emitting Diodes
摘要： All-solution processed colloidal quantum dot light emitting diodes (QLEDs) with record performance have been successfully realized by introducing dually-doped poly(ethylenedioxythiophene)/polystyrenesulfonate (PEDOT:PSS) hole-injection layer and polyethylenimine (PEI) interfacial layer. Doping PEDOT:PSS with both Zonyl and isopropanol (IPA) significantly improves the wettability of PEDOT:PSS, making coating hydrophilic PEDOT:PSS onto hydrophobic hole-transporting layer poly(9-vinlycarbazole) (PVK) possible. The PEI interlayer between PVK/QD layer not only lowers down the vacuum level, thereby reducing the hole-injection barrier to balance the charge carriers, but also passivates QD surface defects via its amine group to suppress fluorescence quenching. As a result, the peak current efficiency of 28.1 cd/A, 43.1 cd/A, and 1.26 cd/A, the maximum external quantum efficiency (EQE) of 20.6%, 10.4%, and 2.95%, and the maximum luminance of 5.06 × 104 cd/m2, 1.21 × 105 cd/m2, and 2.96 × 103 cd/m2, have been achieved for red, green, and blue QLEDs, respectively. To the best of our knowledge, the red device’s EQE is one of the highest among all inverted red QLEDs. In addition, the extrapolated lifetime of the red QLEDs sets a new record by reaching 8253 h at an initial brightness of 100 cd/m2.
关键词： PEDOT:PSS,inverted structure,QLEDs,all-solution processed,quantum dot light emitting diodes,PEI
更新于2025-09-19 17:13:59
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Light-trapping strategy for PEDOT:PSS/c-Si nanopyramid based hybrid solar cells embedded with metallic nanoparticles
摘要： In this article, we have investigated the combined role of nanopyramid (NP) array and metal nanoparticles (MNPs) in enhancing the light trapping ability and improving the photo-absorption of PEDOT:PSS/c-Si Hybrid Solar Cells (HSCs) using a 3D ?nite-di?erence time-domain (FDTD) method. A parametric optimization of the essential geometrical parameters of NPs and MNP is performed based on short circuit current density (Jsc). The optimization result reveals that maximum Jsc of 35.91 mA/cm2 is achievable with top textured NP (without MNPs) which is 24.38% higher than the planar counterpart. However, the absorption spectrum is broadened with the insertion of Al MNP at rear side of the HSC. This is also accompanied by almost two fold increase in Jsc to 41.71 mA/cm2 which is 44.47% higher the planar HSCs. The photovoltaic parameters such as Jsc, Voc, PCE and Fill Factor (FF) are calculated using the DEVICE software for NP and NP embedded with Al MNPs based c-Si Solar Cells. The physics at the interface of inorganic nanostructure and organic material layer is thoroughly described. In addition to this, we have tried to decode the underlying physics for the enhancement of photon absorption in nanopyramidal structures and MNPs structures through an extensive analysis of the photo- generation rate, electric ?eld intensity, power absorption pro?les, PCE and FF of nanopyramidal, nanopyramidal with MNP and planar HSCs.
关键词： Absorption,Metal nanoparticles,Short circuit current density,Nanopyramid,PEDOT:PSS,FDTD,Hybrid solar cells
更新于2025-09-19 17:13:59
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[IEEE 2019 1st International Conference on Advances in Science, Engineering and Robotics Technology (ICASERT) - Dhaka, Bangladesh (2019.5.3-2019.5.5)] 2019 1st International Conference on Advances in Science, Engineering and Robotics Technology (ICASERT) - Layer thickness effect on power conversion efficiency of a P <sub/>3</sub> HT:PCBM based organicsolar cell
摘要： In recent years Organic Solar Cells have become a prominent topic of research to achieve an optimum efficiency at low cost. By using the GPVDM software on this paper, we have analyzed the power conversion efficiency, changing simultaneously both the polymers and blending layer thickness of P3HT:PCBM based solar cell. Our main goal is to find which layer change keeps the power conversion efficiency output better. After comparing them, the result shows that setting the active layer (P3HT:PCBM) in an optimum layer thickness and varying the polymer (PEDOT:PSS) gives a better output of PCE. In our paper, from the data in both cases, The highest efficiency is 4.50 percent where P3HT:PCBM thickness is 2.2×10-7 m and PEDOT:PSS layer thickness is 1×10-7 m.
关键词： PEDOT:PSS,Organic solar cell,polymer layer,blending layer,active layer,PCE,P3HT:PCBM
更新于2025-09-16 10:30:52
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The Role of Mineral Acid Doping of PEDOT:PSS and Its Application in Organic Photovoltaics
摘要： Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) is one of the most successful conducting polymers in terms of commercialization. A method to readily obtain highly conductive and transparent PEDOT:PSS films is urgently needed. A simple method is introduced to enhance the conductivity of such films dramatically. By adding a series of mineral acids into the PEDOT:PSS aqueous solution directly, the conductivity is enhanced by 3–4 orders of magnitude. Mechanistic study reveals that the conductivity enhancement is dependent on boiling point, pKa value, softness parameter, and oxidability of the dopant acid. Specifically, acids with high boiling point, low pKa, and low softness parameter are able to induce phase separation between PEDOT and PSS, leading to secondary doping. If the dopant acid exhibits strong oxidability, the conductivity can also be enhanced via primary doping. H2SO4-doped PEDOT:PSS films exhibit the highest conductivity of 2244 S cm?1. These films are employed as the transparent electrodes of poly(3-hexylthiophene-2,5-diyl) (P3HT)-based organic photovoltaic cells, and the power conversation efficiency reaches 3.13%. These results suggest direct acid doping of PEDOT:PSS solution is a facile approach to obtain highly flexible transparent electrodes.
关键词： transparent flexible electrodes,PEDOT:PSS doping,organic photovoltaic cells
更新于2025-09-16 10:30:52