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Optimization of Transparent Passivating Contact for Crystalline Silicon Solar Cells
摘要： A highly transparent front contact layer system for crystalline silicon (c-Si) solar cells is investigated and optimized. This contact system consists of a wet-chemically grown silicon tunnel oxide, a hydrogenated microcrystalline silicon carbide [SiO2/μc-SiC:H(n)] prepared by hot-wire chemical vapor deposition (HWCVD), and a sputter-deposited indium doped tin oxide. Because of the exclusive use of very high bandgap materials, this system is more transparent for the solar light than state of the art amorphous (a-Si:H) or polycrystalline silicon contacts. By investigating the electrical conductivity of the μc-SiC:H(n) and the influence of the hot-wire filament temperature on the contact properties, we find that the electrical conductivity of μc-SiC:H(n) can be increased by 12 orders of magnitude to a maximum of 0.9 S/cm due to an increased doping density and crystallite size. This optimization of the electrical conductivity leads to a strong decrease in contact resistivity. Applying this SiO2/μc-SiC:H(n) transparent passivating front side contact to crystalline solar cells with an a-Si:H/c-Si heterojunction back contact we achieve a maximum power conversion efficiency of 21.6% and a short-circuit current density of 39.6 mA/cm2. All devices show superior quantum efficiency in the short wavelength region compared to the reference cells with a-Si:H/c-Si heterojunction front contacts. Furthermore, these transparent passivating contacts operate without any post processing treatments, e.g., forming gas annealing or high-temperature recrystallization.
关键词： solar cell,tunneling,silicon,silicon carbide,transparent passivating contact (TPC),selective contact,photovoltaic cells,Passivating contact
更新于2025-09-11 14:15:04
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Novel photo-voltaic device based on Bi1?xLaxFeO3 perovskite films with higher efficiency
摘要： Photovoltaic cells using polycrystalline La substituted bismuth iron oxide, Bi1?xLaxFeO3, (0.1 ≤ x ≤ 0.4), films as the light harvesting component were investigated in this work. A novel cell set-up utilizing a double layered TiO2 film as top contact and a thin layer of quasi-solid polymer electrolyte as back contact was used and a significant enhancement in cell efficiency was observed for assemblies based on x ≥ 0.2 samples, coincident with a structural transition of Bi1?xLaxFeO3 from ferroelectric to non-ferroelectric. The power conversion efficiency of the PV device was 0.13% for the cell with x = 0.2 at 1 sun irradiation. The short circuit current density for this La composition was 0.35 mA cm?2. A hysteretic behaviour was observed for higher La compositions when the scanning is from open-circuit (OP) to short-circuit (SC) which may be attributed to polarization effects. The results at x ≥ 0.2 show an improved performance with respect to BiFeO3 based systems, suggesting the stabilization of the non-ferroelectric crystal structure leads either to a more efficient separation of photo-generated electron–hole pairs and/or enhanced charge transport. The findings represent a step towards the realisation of facile to fabricate, inorganic solid state photovoltaic devices.
关键词： ferroelectric,Photovoltaic cells,power conversion efficiency,quasi-solid polymer electrolyte,Bi1?xLaxFeO3,non-ferroelectric,TiO2
更新于2025-09-10 09:29:36
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[ASME ASME 2015 Conference on Smart Materials, Adaptive Structures and Intelligent Systems - Colorado Springs, Colorado, USA (Monday 21 September 2015)] Volume 2: Integrated System Design and Implementation; Structural Health Monitoring; Bioinspired Smart Materials and Systems; Energy Harvesting - A Sub-Surface Model of Solar Power for Distributed Marine Sensor Systems
摘要： The capabilities of distributed sensor systems, such as wildlife telemetry tags, could be significantly enhanced through the application of energy harvesting. For animal telemetry systems, supplemental energy would allow for longer tag deployments, wherein more data could be collected, enhancing our temporal and spatial comprehension of the hosts activities and/or environments. There are various transduction methods that could be employed for energy harvesting in aquatic environments. Photovoltaic elements have not been widely deployed in the sub-surface marine environments despite a significant potential. In addition to wildlife telemetry systems, photovoltaic energy harvesting systems could also serve as a means of energy supply for Autonomous Underwater Vehicles (AUVs), as well as submersible buoys for oceanographic data collection. Until now, the use of photovoltaic cells for underwater energy harvesting has generally been disregarded as a viable energy source in this arena, with only one company currently offering solar modules integrated with marine telemetry tags. In this article, we develop a model of power available from photovoltaic cells deployed in a sub-surface marine environment. We cover the methods and tools used to estimate solar energy at depth, including the effects of: latitude and longitude, reflected solar energy off of the oceans surface, solar irradiance lost due to the absorption and turbidity of the sea water, cloud cover, etc. We present the availability of this solar energy source in the context of the energy requirements of some of these sensor systems, such as marine bio-loggers. Additionally, we apply our model to simulate the energy harvested on specific marine species in which high fidelity depth information is known. We also apply our model to simulate solar cells at certain depths under the ocean to gain a general understanding of the solar energy available at these depths.
关键词： sub-surface marine environment,photovoltaic cells,marine telemetry,solar energy,energy harvesting
更新于2025-09-09 09:28:46