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- 2018
- tumor imaging
- conductivity
- MRI
- EPT
- Electrical properties tomography
- Optoelectronic Information Science and Engineering
- Ghent University
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Effect of BaZr <sub/>0.4</sub> Ti <sub/>0.6</sub> O <sub/>3</sub> addition on electrical and magnetic properties of multiferroic (1-x)BiFeO <sub/>3</sub> -xBaTiO <sub/>3</sub> ceramics
摘要： The 0.75((1-x)BiFeO3-xBaTiO3)-0.25BaZr0.4Ti0.6O3 or 0.75(BFO-BTO)-0.25BZT ceramics (x = 0.23–0.27) have been prepared by solid state reaction method to studied the relationship between phase formation, dielectric and magnetic properties. The results found that the phase formations of calcined BFO-BTO and BZT powders are distorted rhombohedral and cubic structure, respectively. Moreover, the addition of BZT in BFO-BTO-BZT ceramics affected to the phase change dramatically according to increasing of BZT content compared to calcined BFO-BTO powders. All the samples showed cubic perovskite structure. The room temperature dielectric properties decreased with increasing of BTO content, the highest dielectric constant with low losses observed in 0.75(0.77BFO-0.23BTO)-0.25BZT ceramic. Furthermore, the ceramics displayed maximum dielectric constant temperature (Tm) above 360 °C. Interestingly, all ceramic compositions exhibited typical ferromagnetic hysteresis loop and the highest remanent magnetization observed in 0.75(0.77BFO-0.23BTO)-0.25BZT ceramic.
关键词： composite,dielectric properties,ferromagnetic hysteresis loops,BFO-BTO,BZT
更新于2025-11-14 17:28:48
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Elastic Properties and Fracture Behaviors of Biaxially Deformed, Polymorphic MoTe <sub/>2</sub>
摘要： Biaxial deformation of suspended membranes widely exists and is used in nanoindentation to probe elastic properties of structurally isotropic two-dimensional (2D) materials. However, elastic properties and particularly fracture behaviors of anisotropic 2D materials remain largely unclarified in the case of biaxial deformation. MoTe2 is a polymorphic 2D material with both isotropic (2H) and anisotropic (1T’ and Td) phases, thereby an ideal system of single-stoichiometric materials to study these critical issues. Here we report the elastic properties and fracture behaviors of biaxially-deformed, polymorphic MoTe2, by combining temperature-variant nanoindentation and first-principles calculations. It is found that due to similar atomic bonding, the effective moduli of the three phases deviate by less than 15 %. However, the breaking strengths of distorted 1T’ and Td phases are only half the value of 2H phase due to their uneven distribution of bonding strengths. Fractures of both isotropic 2H and anisotropic 1T’ phases obey the theorem of minimum energy, forming triangular and linear fracture patterns, respectively, along the orientations parallel to Mo-Mo zigzag chains. Our findings not only provide a reference database for the elastic behaviors of versatile MoTe2 phases, but also illuminate a general strategy to the mechanical investigation of any isotropic and anisotropic 2D materials.
关键词： elastic properties,phase transition,MoTe2,nanoindentation
更新于2025-11-14 17:04:02
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Laser-induced synthesis and photocatalytic properties of hybrid organic–inorganic composite layers
摘要： A laser-based method was developed for the synthesis and simultaneous deposition of multicomponent hybrid thin layers consisting of nanoentities, graphene oxide (GO) platelets, transition metal oxide nanoparticles, urea, and graphitic carbon nitride (g-C3N4) for environmental applications. The photocatalytic properties of the layers were tested through the degradation of methyl orange organic dye probing molecule. It was further demonstrated that the synthesized hybrid compounds are suitable for the photodegradation of chloramphenicol, a widely used broad-spectrum antibiotic, active against Gram-positive and Gram-negative bacteria. However, released in aquatic media represents a serious environmental hazard, especially owing to the formation of antibiotic-resistant bacteria. The obtained results revealed that organic, urea molecules can become an alternative to noble metals co-catalysts, promoting the separation and transfer of photoinduced charge carriers in catalytic composite systems. Laser radiation induces the reduction of GO platelets and the formation of graphene-like material. During the same synthesis process, g-C3N4 was produced, by laser pyrolysis of urea molecules, without any additional heat treatment. The layers exhibit high photocatalytic activity, being a promising material for photodegradation of organic pollutants in wastewater.
关键词： transition metal oxide nanoparticles,urea,photocatalytic properties,hybrid organic–inorganic composite layers,graphene oxide,graphitic carbon nitride,methyl orange,laser-based synthesis,chloramphenicol
更新于2025-11-14 17:04:02
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Precipitation behavior of selective laser melted FeCoCrNiC0.05 high entropy alloy
摘要： Interstitial elements are e?ective to strengthen high entropy alloys (HEAs). In this work, FeCoCrNiC0.05 was prepared by selective laser melting (SLM) followed by annealing. The e?ects of annealing on the microstructures and mechanical properties of the SLMed FeCoCrNiC0.05 were investigated. Results show that, nano-scale Cr23C6-type carbides can precipitate under annealing conditions, leading to higher yielding strength. The SLMed FeCoCrNiC0.05 annealed at 1073 K for 0.5 h has a yielding strength of 787 MPa and an elongation of 10.3%. Precipitation kinetics in SLMed FeCoCrNiC0.05 has been established according to Avrami formula. The high strength can be attributed to solid solution hardening, precipitation hardening and cell-like structures.
关键词： Precipitation kinetics,Hardening mechanism,Selective laser melting,Mechanical properties,High entropy alloy
更新于2025-11-14 17:04:02
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Microstructure and properties of laser interference crystallized amorphous FeSiB ribbon
摘要： The influence of Q-switched pulsed Nd:YAG laser interference heating, using 120 mJ of pulse energy and a variable number of consecutive pulses, on the microstructure and magnetic properties of amorphous Fe80Si11B9 alloy was examined. Microstructural analysis, using light, scanning and transmission electron microscopy, was complemented by results of M?ssbauer spectroscopy and measurement of magnetic properties (vibrating sample magnetometer). Periodically distributed crystallized micro-areas, *10 lm in diameter, in an amorphous matrix were produced by the treatments. Magnetization measurements showed that the as-cast ribbon and laser light irradiated samples are magnetically soft materials. The results lead to the conclusion that the dots corresponding to the laser modified regions exhibit a perpendicular magnetic anisotropy.
关键词： Laser interference heating,SEM,TEM,FeSiB amorphous alloy,Magnetic properties
更新于2025-11-14 17:04:02
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Influence of multiple laser peening on vibration fatigue properties of TC6 titanium alloy
摘要： In this study, typical TC6 titanium alloy was taken to investigate the effects of multiple laser peening (LP) on the vibration fatigue properties and microstructural evolution. The vibration fatigue experiments were conducted, while the vibration fatigue life of the specimens before and after LP was compared and the fracture morphologies were observed by scanning electron microscopy (SEM). In addition, the measurements of residual stress and microhardness were carried out. The microstructures produced by different treatments were also characterized by transmission electron microscopy (TEM) and electron backscattered diffraction (EBSD). The experimental results indicated that multiple LP could indeed enhance the vibration fatigue properties of TC6 titanium alloy. Comparing with the investigated specimen without LP, the vibration fatigue life of the specimen subjected to 5 times LP increased by 105.2%. Meanwhile, after 5 times LP, the surface residual stress transformed from tensile stress (+26 MPa) to compressive stress (?485 MPa), and the surface microhardness was 428 HV, which increased by 32.9% compared with the untreated sample. Additionally, high-density of dislocation and deformation twin were also generated after multiple LP. The improvement of vibration fatigue properties was attributed to the rewarding compressive residual stress and the beneficial microstructural evolution induced by multiple LP.
关键词： TC6 titanium alloy,Laser peening,Vibration fatigue properties,Microstructure evolution,Residual stress
更新于2025-11-14 17:04:02
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High-efficiency synthesis of high-performance K0.5Na0.5NbO3 ceramics
摘要： Pure (K0.5Na0.5)NbO3 (KNN) ceramics with high density, fine and uniform-size grains were prepared by mechanochemical activation-assisted process. The time of synthesis is only 100 min, which is 72% - 93% shorter than the 6-24h of the conventional solid-state method. Compared to samples prepared by conventional solid-state method, both the microstructure evolvement and electric properties were explored in detail. Results show the electric properties was significantly improved. Moreover, the dielectric and ferroelectric properties of obtained KNN ceramics exhibit strong dependence on the crystal size of the initial powders. The optimized ceramics HKNN100 showed a quite high energy storage performance, i.e., large electric energy storage density (Wtol=1.612 J/cm3) and recoverable energy storage density (Wrec=0.431 J/cm3), which can be mainly ascribed to the large dielectric breakdown strength (DBS=110 kV/cm). Our works demonstrated that mechanochemical activation-assisted method possesses advantages for high-efficiency preparation of KNN or KNN-based ceramics.
关键词： Dielectric properties,Ferroelectricity,(K0.5Na0.5)NbO3 Ceramics,Mechanochemical activation,Microstructure
更新于2025-11-14 17:04:02
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Silver Nanoparticles - Fabrication, Characterization and Applications || Synthesis and Optical Properties of Highly Stabilized Peptide- Coated Silver Nanoparticles
摘要： The interaction between the silver nanoparticle and peptide surfaces has been of increased interest for the applications of bionanotechnology and tissue engineering. In order to completely understand such interactions, we have examined the optical properties of peptide-coated silver nanoparticles. However, the effect of peptide binding motif upon the silver nanoparticles surface characteristics and physicochemical properties of these nanoparticles remains incompletely understood. Here, we have fabricated sodium citrate stabilized silver nanoparticles and coated with peptide IVD (ID3). The optical properties of these peptide-capped nanomaterials were characterized by UV-visible, transmission electron microscopy (TEM), and z-potential measurement. The results indicate that the interface of silver nanoparticles (AgNP)-peptide is generated using ID3 peptide and sug-gested that the reactivity of peptide is governed by the conformation of the bound pep-tide on the silver nanoparticle surface. The interactions of peptide-nanoparticle would potentially be used to fabricate specific functionality into the various peptide-capped nanomaterials and antibacterial applications.
关键词： Z-potential,silver nanoparticles,peptide,physicochemical properties
更新于2025-11-14 17:04:02
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Phosphotellurite glass and glass-ceramics with high TeO <sub/>2</sub> content: thermal, structural and optical properties
摘要： Phosphotellurite based glasses have interesting features such as low characteristic temperatures, large glass forming ability, high thermal stability against crystallization and broad transparency window from ultraviolet (UV) to near-infrared (NIR), which makes them promising materials for photonic applications. In this work, phosphotellurite binary glasses, having composition (100 – x) TeO2–x Ba(PO3)2 with x varying from 1 to 20 mol %, were synthesized by the conventional melt-quenching method in covered gold crucibles under air. Optical, physical and structural properties of the new glass samples were investigated by differential scanning calorimetry, X-rays diffraction, Raman spectroscopy, transmission electron microscopy, linear optical absorption from UV to NIR, IR transmittance, and optical limiting experiments. Transparent glass-ceramics in the visible range were obtained for phosphotellurite samples containing 2, 4 and 6 mol % of Ba(PO3)2 and the phase crystallization was investigated through Rietveld analysis and transmission electron microscopy. The incorporation of Ba(PO3)2 into the TeO2 network drastically increases the thermal stability against devitrification and helps to shift the infrared multiphonon absorption edge to longer wavelengths. Nonlinear measurements performed with a picosecond laser at 532 nm indicate large effective nonlinear absorption coefficients for all samples. In summary, the dependence of the spectroscopic properties on the samples’ compositions revealed a promising transparent glass and glass-ceramics for photonic applications.
关键词： transparent glass-ceramics,phosphotellurite glass,optical properties,nonlinear optical response
更新于2025-11-14 17:03:37
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Luminescent Composites Based on Tetrafluoroethylene Copolymer Porous Films Produced by the Diffusion Embedding of Semiconductor Nanoparticles in a Supercritical Medium
摘要： A method for creating film composites based on a new material—a fibrous copolymer of tetrafluoroethylene and vinylidene fluoride—using the diffusion embedding of ready-made nanoparticles into a porous matrix in a supercritical (SC) carbon dioxide medium is developed. The method of cold or hot pressing of impregnated porous films was used at the final stage of creation of such composites. The peculiarities of the effect of the supercritical fluid treatment of porous copolymer films on the surface structure of pressed films are discussed. Luminescent composites with semiconductor nanoparticles of cadmium selenide and nanocrystalline silicon are obtained; their radiation covers a range of 500–1000 nm. The change in the luminescence properties of the resulting nanocomposites under the action of excitation laser radiation at 405 nm is demonstrated.
关键词： cadmium selenide,film composite,fibrous matrix,luminescent properties,diffusion embedding,nanocrystalline silicon
更新于2025-11-14 15:30:11