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- 摘要
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- 实验方案
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Novel Spark Method for Deposition of Metal Oxide Thin Films: Deposition of Hexagonal Tungsten Oxide
摘要： Hexagonal tungsten trioxide (WO3) layers are grown on indium tin oxide (ITO) substrates using a novel spark deposition system. The effects of deposition time, substrate temperature, and oxygen (O2) flow rate through the chamber on the structural and morphological characteristics as well as the electrochemical response of the layers are examined. It is found that a deposition temperature of 400 °C and O2 flow rate at 60 mL min?1 through the chamber can result in hexagonal WO3 with improved crystallinity and quite effective electrochemical/electrochromic response.
关键词： tungsten trioxide,spark method deposition,electrochemical response
更新于2025-09-23 15:23:52
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Angle-dependent excitonic luminescence in semiconductor microtube cavity: The self-absorption effect
摘要： We obtain a Liouville theorem for the semilinear fractional CR covariant equation Pα/2u = up (1 ≤ α < 2) on the Heisenberg group Hn. For this purpose, we extend the fractional equation to sub-Laplace Neumann problem on Hn × R+. Then the conclusion is derived by applying the CR inversion and moving plane method to the Neumann problem. Our result is a generalization for the corresponding one to P1/2u = up.
关键词： Liouville theorem,moving plane method,fractional CR covariant equation,Heisenberg group,CR inversion
更新于2025-09-23 15:23:52
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Spectroscopic properties of Eu:Bi4Ge3O12 single crystal grown by the micro-pulling-down method
摘要： Eu3+-doped Bi4Ge3O12 (BGO) single crystal with the size of ?2 × 83 mm3 was successfully grown by the micro-pulling-down method. The absorption cross section, emission cross section and Judd–Ofelt analysis of Eu:Bi4Ge3O12 (Eu:BGO) were reported for the first time. The absorption cross-section is 1.03 × 10?20 cm2 with full-width at half-maximum of 3.1 nm at around 393 nm. The spectroscopic intensity parameter Ωt (t = 2,4,6), radiative transition probabilities, branching ratios and radiative lifetime were obtained, respectively. Furthermore, the stimulated emission cross-section centered at 611 nm was calculated to be 6.32 × 10?21 cm2. The fluorescence lifetime of 5D0 level was obtained to be 1.51 ms. The results indicate that Eu: BGO single crystal could be a potential laser host in the visible range.
关键词： Micro-pulling-down method,Optical properties,Eu:BGO
更新于2025-09-23 15:23:52
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[SpringerBriefs in Applied Sciences and Technology] Vibration Analysis of Functionally Graded Piezoelectric Actuators ||
摘要： This book has evolved from the passionate desire of the author in using the modern concepts of piezoelectric materials for the design improvement of sensors and actuators. In this connection, the author took up his doctoral studies whose findings have resulted in this book. The initial focus here is on the basic theory, application, and drawbacks of piezoelectric materials. The types of deformation produced in piezoelectric materials due to different piezoelectric effects are reported briefly. Further, the concept of functionally graded material (FGM) used in the design of piezoelectric materials with graded properties is described. The engineering applications of functionally graded piezoelectric materials (FGPMs) are summarized thereafter. In the latter sections, the modal analysis of FGPM actuators is provided. Two types of actuator geometries are taken into consideration—first is beam, and the second is annular plate. The effects of various parameters on the natural frequencies are given in detail. A detailed account of a new numerical technique called the generalized differential quadrature (GDQ), adopted in this book, is also provided. An extension of this technique for the analysis of FGPM structures becomes an important endeavor. The overall focus is on the vibration analysis of FGPM actuators excited under the shear effect using the GDQ method.
关键词： Shear effect,Piezoelectric materials,Functionally graded materials,Vibration analysis,Actuators,Generalized differential quadrature method
更新于2025-09-23 15:23:52
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Uniform-in-time bounds for approximate solutions of the drift–diffusion system
摘要： In this paper, we consider a numerical approximation of the Van Roosbroeck’s drift–diffusion system given by a backward Euler in time and finite volume in space discretization, with Scharfetter–Gummel fluxes. We first propose a proof of existence of a solution to the scheme which does not require any assumption on the time step. The result relies on the application of a topological degree argument which is based on the positivity and on uniform-in-time upper bounds of the approximate densities. Secondly, we establish uniform-in-time lower bounds satisfied by the approximate densities. These uniform-in-time upper and lower bounds ensure the exponential decay of the scheme towards the thermal equilibrium as shown in Bessemoulin-Chatard (Numer Math 25(3):147–168, 2016).
关键词： Finite volume method,Uniform-in-time bounds,Scharfetter–Gummel scheme,Drift–diffusion system,Numerical analysis
更新于2025-09-23 15:23:52
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An unstructured Monte Carlo ray-tracing method for solving radiative heat transfer in 3D gray semitransparent medium
摘要： Monte Carlo ray-tracing method (MCRTM) is widely used for solving the Radiative Transfer equation (RTE) due to its high accuracy and flexibility. In this paper, a MCRTM is developed for solving the radiative heat transfer in gray semitransparent media with complex geometries which are discretized by 3D unstructured grids. A novel algorithm associated to unstructured four-node tetrahedron element is proposed for generating random emitting positions of rays, and the ray tracing process is performed based on Beer's law. Meanwhile, radiation distribution factors are used for calculating radiative source terms which are loaded to the grid. The present method is first validated by comparing the predictive results with those from previous studies on a cubic enclosure, a 3D L-shaped enclosure, and a 3D elliptical enclosure, respectively. Furthermore, a radiation-conduction heat transfer problem is examined in a cylindrical enclosure. All the comparisons show that the present method is in good agreement with these previous cases. This method can be well adapted to various complex geometries. In addition, since the source term is calculated by the radiation distribution factor, which can be reused for different conditions as long as the volumetric radiative properties remain unchanged, this will bring great advantage when coupled with other heat transfer models such as conduction, convection, combustion, etc.
关键词： Monte Carlo ray-tracing method,Radiative heat transfer,Semitransparent medium,Radiation distribution factor,Unstructured grids
更新于2025-09-23 15:23:52
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A magnetic and carbon dot based molecularly imprinted composite for fluorometric detection of 2,4,6-trinitrophenol
摘要： A magnetic molecularly imprinted composite was prepared by reverse microemulsion using carbon dots (CDs), Fe3O4 as the co-nucleus, and a molecularly imprinted polymer (MIP; with 2,4,6-trinitrophenol as the template) acting as recognition sites. The composite of type CD/Fe3O4@MIPs was characterized by transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), Fourier transform infrared spectroscopy (FT-IR), zeta potentiometric analysis, X-ray diffraction (XRD) and vibrating sample magnetometry (VSM). The results showed that the composite MIP has a spherical shape with average diameter of 200 nm. They also showed that the composite contains core-shell structures with several Fe3O4 nanoparticles and CDs embedded in each of the microsphere. The composite can extract 2,4,6-trinitrophenol (TNP) and has an imprinting factor of 3.6. It has high selectivity and sensitivity for TNP which acts as a quencher of the fluorescence of the CDs (with excitation/emission maxima at 370/470 nm). The limit of detection of this fluorometric TNP assay is 0.5 nM. The method was successfully applied to the determination of TNP in spiked tap water and river water samples, and recoveries ranged from 89.4% to 108.5% (with an RSD of <6%).
关键词： Fluorescence quenching,Fe3O4 nanoparticles,Stern-Volmer plot,Environmental pollutants,Reverse microemulsion method,Selective recognition,Molecularly imprinting
更新于2025-09-23 15:23:52
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Facile synthesis of thin black TiO2 ? x nanosheets with enhanced lithium-storage capacity and visible light photocatalytic hydrogen production
摘要： In combination of a facile and scalable solvothermal method and solid-phase reduction reactions, a novel two-dimensional black TiO2 ? x nanosheet (TiO2 ? x NS) with high specific surface area of 108 m2 g?1 and nearly total solar spectral absorption capability have been successfully prepared. With careful characterizations, the novel TiO2 ? x NS showed enhanced electrochemical performance and visible-light photocatalytic activity than those of their white TiO2 nanosheet (TiO2 NS) precursors. The black TiO2 ? x NS electrode delivered a reversible specific capacity of 160 mA h g?1 even after cycling at 0.5 C (1 C = 190 mA h g?1) for 300 times, which was significantly higher than the corresponding white TiO2 NS electrode (104 mA h g?1). Meanwhile, the TiO2 ? x NS also exhibited enhanced ability of visible-light photocatalytic hydrogen production than that of the white TiO2 NS. It is expected that making white TiO2 NS into black ones is an effective way to design the photocatalysts with visible light response and the anodes with long lifetime and high rate performance in lithium ion batteries. The novel black TiO2 ? x NS could find potential applications in the field of environmental management and energy storage and conversion.
关键词： Solvothermal method,Photocatalysis,Black TiO2 ? x nanosheets,Anodes
更新于2025-09-23 15:23:52
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Environmentally friendly methodology for fouling removal in pipeline based on leaky guided wave generated by quasi-axisymmetric excitation mode
摘要： In this paper, an environmental and innovative clean technique for pipeline fouling is proposed, which is based on leaky ultrasonic guided waves (LUGWs) generated by quasi-axisymmetric excitation mode. The cavitation, which induced by the LUGWs in liquid medium, is employed for removing fouling inside a pipe. Cavitation corrosion and high-speed jet generated by the collapse of cavitation bubbles destroy fouling layer, and no by-products are formed during the removal process, which means that fouling removal in this way is friendly to the environment. The working frequency is determined by finite element method models and experiment. The effect of removal and its uniformity are measured by mass analysis, scanning electron microscope and energy-dispersive spectroscopy from macro to micro. The descaling experiment results show that the proposed method is able to remove the fouling inside a pipe uniformly.
关键词： Finite element method,Fouling removal,Quasi-axisymmetric,Leaky ultrasonic guided waves
更新于2025-09-23 15:23:52
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Optical measurements based on practical methods for detecting time-wise morphing structures
摘要： Nowadays non-contact measurement methods have become widely used systems in several fields especially robotics, aerospace, architecture, and cultural heritage. Practical devices, taken from mass markets, are increasingly being used in scientific and engineering research fields thanks to their ability to combine good accuracy with to the low-cost and ready-to-use experimental setup. In the present paper, digital image analysis (based on digital camera devices) and three-dimensional scanning technique (based on Kinect I and Kinect II sensors) are compared to evaluate their performance in detecting a time-wise shape modification. Digital camera and Kinect sensors are used to the non-contact detection of a morphing blade able to modify its geometry according to airflow temperature variation. The comparison showed the capability of the digital image technique to provide quantitative information when a proper alignment is adopted, while the three-dimensional scanning process allows the continuous blade detection useful to quantify the shape modification. Two-dimensional and three-dimensional blade shape reconstruction processes are also discussed.
关键词： Reverse Engineering,Non-contact measurement,Point cloud,Kinect sensor,Optical method,Digital image analysis
更新于2025-09-23 15:23:52