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- 2019
- 2018
- silver nanowires
- nanopaper
- transparent electrode
- flexible
- composite electrode
- silver nanowire
- reduced graphene oxide
- zinc oxide
- Nanomaterials and Technology
- Optoelectronic Information Materials and Devices
- South China University of Technology
- China Jiliang University
- Guangdong Poly-Optoelectronics Co.
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Ultrasonic-Enhanced Fabrication of Metal Nanoparticles by Laser Ablation in Liquid
摘要： Laser ablation in liquid (LAL) is known to be a promising method for synthesizing metal nanoparticles. In this study, gold and silver nanoparticles were fabricated by ultrasonic-assisted LAL. Gold and silver plates were ablated using a neodymium-doped yttrium aluminum garnet (Nd:YAG) laser, with a wavelength of 532 nm and energy of 26.4 J cm?2, in distilled water in the presence and absence of an ultrasonic ?eld. The fabricated solution was analyzed with an ultraviolet?visible (UV?vis) nanoparticle colloidal spectrometer, a transmission electron microscope (TEM) with energy-dispersive X-ray spectroscopy (EDS), and ζ-potential measurement. The craters on the silver plates were analyzed by a scanning electron microscope (SEM), a laser microscope, and MATLAB to observe their morphology and calculate the volume to obtain the concentration of the fabricated nanoparticle solution. Optical emissions were observed to study the characteristics of the laser. The results showed that ultrasonic-assisted LAL has considerable potential for fabricating superior metal nanoparticles.
关键词： Silver nanoparticles,Ultrasonic-assisted,Nd:YAG laser,Laser ablation in liquid,Gold nanoparticles
更新于2025-09-19 17:13:59
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Hexavalent Octahedral Template: A Neutral High-Nucleus Silver Alkynyl Nanocluster Emitting Infrared Light
摘要： The first silver nanocluster with an octahedral template of TeO6 6? was synthesized as a neutral 36-nucleus nanocluster, and its structure was demonstrated using single-crystal X-ray diffraction, Fourier transform infrared spectroscopy, electrospray ionization mass spectrometry, and X-ray photoelectron spectroscopy. The peripheral ligands of the cagelike skeleton of the nanocluster are CF3COO? and tBuCC?. During the synthesis, the TeO6 6? template arranged the nanocluster, and a 36-nucleus nanocluster was formed. The effect of the template nature was displayed on the structural features of the nanocluster in comparison with an 8-nucleus cluster, with the same synthesis conditions. The photoluminescence and UV?vis absorption analyses of the nanocluster were also investigated. The nanocluster displayed near-infrared luminescence emission at 690 nm.
关键词： TeO6 6?,photoluminescence,silver nanocluster,octahedral template,infrared light
更新于2025-09-19 17:13:59
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Resonant energy transfer and light scattering enhancement of plasmonic random lasers embedded with silver nanoplates
摘要： The resonant energy transfer enhancement from a plasmonic random laser (PRL) has been investigated by means of a dye-covered PVA film with embedded silver nanoplates (DC-PVA/AgNPs). Different sizes and morphologies of AgNPs were adopted to shift the localized surface plasmon resonance (LSPR) and intensify recurrent light scattering between the AgNPs. For better overlap between surface plasmon resonance and the photoluminescence of fluorescent molecules with appropriately-sized silver nanoprisms, the slope efficiency of the PRL was greatly enhanced and the lasing threshold was obviously reduced. In addition, the photon lifetime for the DC-PVA/AgNPs film reveals an apparent decline around 1.39 ns owing to better coupling with LSPR. The stronger light scattering of samples with bigger-sized silver nanoprisms has been demonstrated by coherent back scattering measurements, which reveals a smaller transport mean free path around 3.3 mm. With a-stable analysis, it has been successfully demonstrated that the tail exponent a can be regarded as an identifier of the threshold of random lasing.
关键词： localized surface plasmon resonance,resonant energy transfer,silver nanoplates,light scattering enhancement,plasmonic random laser
更新于2025-09-19 17:13:59
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Broadband plasmonic coupling and enhanced power conversion efficiency in luminescent solar concentrator
摘要： Advancements in solar energy harvesting technologies call for innovative approaches to meet the ever-growing energy demand. This study exploits the plasmonic interaction of metal nanoparticles (MNPs) with fluorophores to improve the optical performance of Luminescent Solar Concentrators (LSCs). Plasmonic Luminescent Solar Concentrator (PLSC) with dimensions of 45 × 45 × 3 mm3 containing Lumogen Red305 dye and gold core silver shell nanocuboids (Au@Ag NCs) were fabricated and characterized. Plasmonic coupling in the PLSC device was influenced through spacing and spectral overlap between the nanocuboids (NCs) and Red305 dye. The spacing between Au@Ag NCs and Red305 dye was controlled by the doping concentration of Au@Ag NCs for acquiring a homogeneous sample. The optical performance of PLSC waveguides was investigated through edge emission measurements of the waveguides while varying the doping concentration of Au@Ag NCs. A maximum enhancement of 30% in the fluorescence was achieved for PLSC device containing an optimal doping concentration (1.1 ppm) of Au@Ag NCs. A transition from maximum fluorescence enhancement to quenching was demonstrated, emphasizing the importance of MNP doping concentration and spectral overlap when coupling Au@Ag NC and Red305 dye molecules. At high doping concentrations of Au@Ag NCs, non-radiative energy transfer from Red305 dye molecules to the Au@Ag NCs made quenching a dominant effect. Monocrystalline silicon solar cells were attached to one edge of the PLSC waveguides. For the sample with 1.1 ppm Au@Ag NCs doping concentration, the power conversion efficiency was found to be 1.2 times higher than the power conversion efficiency of 0 ppm sample.
关键词： Gold core silver shell nanocuboids,Edge emission,Photon mode density,Luminescent solar concentrator,Surface plasmon resonance,Plasmonic coupling
更新于2025-09-19 17:13:59
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Hierarchical Laser-Patterned Silver/Graphene Oxide Hybrid SERS Sensor for Explosive Detection
摘要： We demonstrate an ultrafast laser-ablated hierarchically patterned silver nanoparticle/graphene oxide (AgNP/GO) hybrid surface-enhanced Raman scattering (SERS) substrate for highly sensitive and reproducible detection of an explosive marker 2,4-dinitrotoluene (2,4-DNT). A hierarchical laser-patterned silver sheet (Ag?S) is achieved by ultrafast laser ablation in air with pulse energies of 25, 50, and 100 μJ. Multiple laser pulses at a wavelength of 800 nm and a pulse repetition rate of 50 fs at 1 kHz are directly focused on Ag?S to produce and deposit AgNPs onto Ag?S. The surface morphology of ablated Ag?S was evaluated using atomic force microscopy, optical pro?lometry, and ?eld emission scanning electron microscopy (FESEM). A rapid increase in the ablation rate with increasing laser energy was observed. Selected area Raman mapping is performed to understand the intensity and size distribution of AgNPs on Ag?S. Further, GO was spin-coated onto the AgNPs produced by ultrafast ablation on Ag?S. The hierarchical laser-patterned AgNP/GO hybrid structure was characterized using FESEM, high-resolution transmission electron microscopy, X-ray di?raction, Fourier transform infrared spectroscopy, and Raman spectroscopy. Further, hierarchical laser-patterned AgNP/GO hybrid structures have been utilized as SERS-active substrates for the selective detection of 2,4-DNT, an explosive marker. The developed SERS-active sensor shows good stability and high sensitivity up to picomolar (pM) concentration range with a Raman intensity enhancement of ～1010 for 2,4-DNT. The realized enhancement of SERS intensity is due to the cumulative e?ect of GO coated on Ag?S as a proactive layer and AgNPs produced by ultrafast ablation.
关键词： silver nanoparticle/graphene oxide (AgNP/GO) hybrid,ultrafast laser ablation,explosive detection,surface-enhanced Raman scattering (SERS),2,4-dinitrotoluene (2,4-DNT)
更新于2025-09-19 17:13:59
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High performance flexible organic photomultiplication photodetector based on ultra-thin silver film transparent electrode
摘要： Flexible and lightweight photomultiplication-type organic photodetectors (PM-OPDs) have attracted wide attention for their broad application prospects, especially in the field of wearable electronic products. However, the common used indium tin oxide (ITO) conductive anode is not conducive to realize high-performance flexible PM-OPD due to its rigidity and fragility. Here, on the flexible polyethylene terephthalate (PET) substrate, we successfully fabricate highly sensitive poly 3-hexylthiophene:phenyl-C70-butyric acid methyl ester (P3HT:PC70BM, 100:1) based PM-OPDs using ultra-thin silver films as the transparent anode. Specifically, a 1 nm thick MoO3 layer is utilized as the wetting layer for facilitating the silver film percolation, and a 2 nm thick MoO3 layer, as the hole transport layer, is coated on top of the ultra-thin silver film before coating the P3HT:PC70BM film. The as-prepared flexible PM-OPDs based on the ultra-thin silver film exhibit the optimal external quantum efficiency (EQE) and responsivity (R) of 1.3×105 % and 388.4 A/W, respectively, under -15 V bias, which are 1.98 times and 2.15 times greater than those of the ITO anode based device. More importantly, the device has good flexibility with the EQE maintaining 70.6% of its initial value after 10 times of bending, and 51.4% of its initial value after 1000 times of bending. This work paves the way for developing flexible PM-OPDs as well as other flexible optoelectronic devices.
关键词： multiplication,transparent electrode,photodetectors,silver film,flexible
更新于2025-09-19 17:13:59
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Femtosecond laser sintering of silver nanoparticles for conductive thin-film fabrication
摘要： Femtosecond laser sintering of metal nanoparticles for fabricating thin metal films/patterns has drawn substantial attention owing to its potential in fabrication of thin-film electrodes in various applications. In such applications, the electrical conductivity and the adhesion strength of the sintered film need to be optimized by forming desired microstructures. However, the physical mechanisms of sintering by ultrashort laser pulses without the effect of inter-pulse heat accumulation, especially microstructure formation, have not yet been clarified. Also, the relation between the microstructure of various sintered films and their properties are largely unknown. In this work, the microstructures and the properties (electrical conductivity and adhesion strength) of sintered film are analyzed by varying the process conditions for Ti:sapphire femtosecond laser sintering of silver nanoparticles. Sintering occurred mainly by surface necking at low laser fluences while by melting of the particles at high laser fluences. When laser fluence was further increased, the balling phenomenon occurred by capillary instability of the molten pool. These sintering phenomena were largely similar to those observed in typical thermal sintering. Both the electrical conductivity and the adhesion strength increased with the laser fluence to reach maximum when melting of the particles began before triggering the balling phenomenon. The maximum electrical resistivity ~ 8.7 μΩ cm obtained in this work was similar to that obtained by other thermal-sintering processes.
关键词： Femtosecond,Nanoparticle,Sintering,Thin film,Laser,Silver
更新于2025-09-19 17:13:59
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Plasmonic Silver Nanoprism-Induced Emissive Mode Control between Fluorescence and Phosphorescence of a Phosphorescent Palladium Porphyrin Derivative
摘要： We have succeeded in significantly enhancing fluorescence from intrinsically phosphorescent palladium octaethylporphyrin (Pd-porphyrin) that has an intersystem crossing efficiency of ~1 by using silver nanoprisms (AgPRs). This was achieved by controlling the wavelength of localized surface plasmon (LSP) resonance of AgPRs and the distance between the Pd-porphyrin molecules and the AgPR surfaces. In addition to enhancing phosphorescence by spectrally overlapping the phosphorescence band with the LSP resonance band, tuning the LSP wavelength to approximately 520 nm led to the appearance of a new emission band around the wavelength corresponding to the fluorescent radiation. The appearance of fluorescence suggests that the nonradiative energy transfer from the singlet excited state of Pd-porphyrin to the LSP of AgPRs overcame the ultrafast intramolecular intersystem crossing to the triplet excited state, manifesting the spectral properties of the singlet excited state of Pd-porphyrin. The fluorescence nature of this radiation was strongly supported by lifetime measurements of the hybrids of Pd-porphyrin and AgPRs. Furthermore, the dependence of the emissive intensities on the distance between the Pd-porphyrin molecules and the AgPR surfaces showed interesting opposite trends. The fluorescence intensity was increased as the distance between the molecules and the AgPRs was decreased from 10.5 nm to 1 nm, while the phosphorescence intensity was decreased, which indicates that the LSP-induced fluorescence radiation process from Pd-porphyrin near the AgPRs outweighed the quenching by the AgPRs, even though the phosphorescence significantly suffered quenching.
关键词： silver nanoprisms,localized surface plasmon resonance,palladium porphyrin,phosphorescence,metal-enhanced fluorescence,fluorescence,intersystem crossing
更新于2025-09-19 17:13:59
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Enhanced light-emitting diode induced fluorescence detection system with capillary electrophoresis
摘要： An enhanced fluorescence detection system of capillary electrophoresis (CE) was equipped with a concave silver mirror, by which the detection sensitivity of light-emitting diode induced fluorescence (LEDIF) can be increased greatly. The silver concave mirror and the cathode window in photomultiplier tube (PMT) were accurately set face to face at the same axis. When the two labeled tumor markers exactly moved to the center of detection window, the emission from analytes are excitated by LED source. Currently, the analytes may be regarded as a luminescent source point. When the source point exactly moves to the focus of the concave mirror, the emission of the labeled sample was collected effectively, enhanced by convergence and reflected by the concave mirror. Then it was sensitively detected by the PMT. The optical mechanism of enhancing detection sensitivity was explored. A simple comparative test on sensitivity was carried out, which aimed to compare sensitivity of the new detection system with concave mirror to that without concave mirror but the other conditions were kept the same. Two tumor markers labeled with FITC were selected for the test, using the simple LEDIF detect system. The results (LOD, 150 nM for L-Leu and L-Val) showed that the detection sensitivity matched with concave mirror reached more 16 times than the detection method without concave mirror.
关键词： Curvature radius,Light-emitting diode induced fluorescence,Tumor markers,Concave silver mirror,Polarized light,Highly sensitive optical detector
更新于2025-09-19 17:13:59
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Flexible perovskite solar cells based on AgNW/ATO composite transparent electrodes
摘要： Silver nanowire (AgNW) transparent electrodes are promising for ?exible perovskite solar cells (PSCs) due to their low cost, high conductivity, high transmittance and roll-to-roll fabrication processes. We resolved problems with incorporating AgNW networks into PSCs such as smooth surface morphology, space ?lling and chemical stability by employing solution-deposition of conductive ATO nanoparticles onto pre-existing AgNW networks at low temperatures. AgNW/ATO composite transparent electrodes show a transmission of 76–82 % in the visible region with an excellent sheet resistance of 18 O sq?1, similar to the commercial PET/ITO transparent electrodes. To build up ?exible PSCs, we adopted an architecture in which the thin ?lm of CH3NH3PbI3 was sandwiched between the ZnO (as the electron-selective layer) and carbon electrode (as the hole-selective layer) on the AgNW/ATO composite transparent electrodes. Under AM 1.5 G and 100 mW cm?2 simulated sunlight illumination, the ?exible PSCs based on AgNW/ATO composite transparent electrodes achieved PCEs of 5.07 %. The ?exible devices maintained their performance after 100 bending cycles at 6 mm radius of curvature.
关键词： Transparent electrode,Silver nanowire,ATO nanoparticles,Flexible,Perovskite solar cell
更新于2025-09-19 17:13:59