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Structure and property of lead-free (K,Na)NbO3–(Bi1/2Na1/2)ZrO3–CaTiO3 piezoelectric ceramics
摘要: Simultaneous improvement of piezoelectricity and temperature stability is vital for developing high-performance KNN-based lead-free materials. Here, effects of CaTiO3 on phase structure, piezoelectricity and temperature stability of (1 – x)[0.95(K0.5Na0.5)NbO3–0.05(Bi0.5Na0.5)ZrO3]–xCaTiO3–0.2%MnO2 ceramics were studied. It was found that the orthorhombic-tetragonal phase transition temperature can be gradually decreased by increasing CaTiO3 content. Particularly, the improved strain temperature stability (strain varied < 15% when measurement temperature reaches 110 °C) and enhanced electrical properties (d33 ~ 296 pC/N and strain ~ 0.14%) can be observed in the ceramics with x = 0.02. Therefore, shifting the TO?T below room temperature is an effective way to promote temperature stability and electrical properties of KNN-based piezoelectric materials.
关键词: Lead-free piezoelectric ceramics,Temperature stability,CaTiO3,Piezoelectricity,KNN-based
更新于2025-09-10 09:29:36
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Ultralow loss and temperature stability of Li3Mg2NbO6-xLiF ceramics with low sintering temperature
摘要: Novel temperature stable Li3Mg2NbO6-xLiF (x=0.5-8 wt. %) ceramics with ultralow loss were fabricated by the solid-state reaction process. The influence of LiF addition on the sintering, grain growth and morphology, and improved microwave dielectric characteristics was investigated. A single orthorhombic Li3Mg2NbO6 structure could be confirmed by Raman spectra and XRD patterns. Dense and homogeneous microstructure could be obtained with ~10 μm average grain size. Results demonstrated that the εr values were relevant to bulk density and the high Q×f values were influenced by the large grain sizes. The τf values depend on porosity corrected dielectric constant. Notably, the remarkably desirable microwave dielectric characteristics: εr=15.4, Q×f=100,000 GHz, τf=?3.1 ppm/°C were achieved for the Li3Mg2NbO6 ceramics with x=6 wt% sintered at 925 °C, which could be applied for ultra-low loss LTCC applications.
关键词: ultra-low loss,temperature stability,single orthorhombic structure
更新于2025-09-04 15:30:14