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White-light emissive upconversion nanoparticles for visual and colorimetric determination of the pesticide thiram
摘要： The authors describe the use of white-light emitting upconversion nanoparticles (WL-UCNPs) for visual detection of the pesticide thiram. The method is demonstrated to undergo a better discernable color change upon target binding. The WL-UCNPs are modified with the lead(II)-dithizone complex which acts as the energy acceptor and recognition unit. This leads to quenching of the blue (475 nm) and green (545 nm) emissions of the WL-UCNPs, while the red emission (650 nm) remains unaffected. Upon addition of thiram, the quenched emissions are recovered, with a linear signal increase in the range from 2 nM to 20 nM of thiram and a limit of detection of 0.26 nM. The nanoprobe was further integrated into a test paper for visual detection. The concentration-dependent color change that varies from red to cyan and bluish violet and then to white can be visually distinguished.
关键词： Lead-dithizone complex,Color-differentiation,Upconversional nanoprobe,Test paper,Energy transfer
更新于2025-09-23 15:22:29
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A luminescent terbium metal-organic framework for highly sensitive and selective detection of uric acid in aqueous media
摘要： As the final product of purine metabolism, uric acid (UA) existing in urine and serum plays an important role in the body's metabolism, immunity and other functions. However, it is still difficult to sense UA in practice. Herein, a new terbium metal–organic framework (Me2NH2)2[Tb2(L)2]·(H2O)6 (ZJU-158-Tb, ZJU=Zhejiang University, L= 1-(3,5-dicarboxylatobenzyl)-3,5-pyrazole dicarboxylic acid )for luminescent sensing of UA was designed and synthesized. It exhibits highly sensitive and selective detection to UA in aqueous solutions with a quite low detection limit of 7 nM by a luminescence turn-down phenomenon. Furthermore, the practical test papers made by ZJU-158-Tb possess fast monitoring ability for abnormal UA levels in artificial urine and serum through distinct color change, which could be even distinguished by the naked eye.
关键词： uric acid,Metal-organic frameworks,test paper.,fluorescence sensor
更新于2025-09-19 17:15:36