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Effect of monatomic and molecular ion irradiation on time resolved photoluminescence decay in GaN
摘要： Optical effects induced in silicon-doped wurtzite (0001) GaN epilayers by keV monatomic and molecular ion irradiation were experimentally investigated. Results were analyzed together with data on structure defect formation. In all the cases under consideration, an increase in the collision cascade density (the cases of molecular and heavy atomic ion bombardment) enhances the stable damage accumulation rate and, accordingly, intensifies quenching of luminescence. The processes of PL suppression were theoretically considered as an increase of surface recombination rate of nonequilibrium photo-excited charge carriers due to production of stable damage at the irradiated subsurface layer. It is shown that carrier diffusion determines PL decay time shortening in the shallow implantation cases studied.
关键词： Radiation damage,Photoluminescence,Collision cascade density,Time-resolved PL,Charge carrier diffusion,Ion implantation,GaN
更新于2025-09-23 15:23:52
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Ligand induced anomalous emission shift of size-controlled CsPbBr <sub/>3</sub> nanocrystals
摘要： CsPbX3 perovskite nanocrystals (NCs) have attracted much attention from researchers because of their excellent photoelectric properties like high quantum yield, large absorption cross section, and simple preparation process. The addition of ligands in the synthesis process has a significant effect on the microstructure and photophysical properties of solution-processed NCs, which needs further extensive studies. In this Letter, the effects of ligand electronegativity on the size and photoluminescence (PL) properties of CsPbBr3 NCs were reported. One is typical oleic acid with weak electronegativity, and another is 2-acrylamide-2-methylpropionic sulfonic acid with strong electronegativity. The third is their typical mixture with a molar ratio of 1:1. With the increase in ligand electronegativity, the size of CsPbBr3 NCs increases significantly. However, in contrast to the traditional quantum size confinement effect, the PL peak exhibits an abnormal blue shift gradually and the ligand passivation effect on NC surface defects also becomes more significant. The physical mechanism of this anomalous PL shift phenomena of CsPbBr3 NCs was investigated using the time-resolved PL spectrum and transient absorption spectrum.
关键词： transient absorption spectrum,quantum size confinement,photoluminescence,CsPbX3 perovskite nanocrystals,ligand electronegativity,time-resolved PL spectrum
更新于2025-09-16 10:30:52