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Physical, structural and optical properties of Sm3+ doped lithium zinc alumino borate glasses
摘要： Sm3+ doped lithium zinc alumino borate glasses with composition 15ZnF2–12Li2CO3–10BaO–8Al2O3–(55-x) B2O3–xSm2O3 where x = 0.1, 0.3, 0.5, 0.7 and 1.1 mol% were prepared by conventional melt quenching technique Their optical, physical, structural, mechanical and luminescence properties are investigated. UV–Vis-NIR absorption spectra showed all possible transitions of samarium ion in this glass matrix. Band gap values for all the glass samples were above 3 eV con?rming the insulating nature for the glass. Densities, assessed using the Archimedes rule, were observed to be increasing with increasing samarium concentration. Increase in molar volume with addition of samarium content indicated that the extension of glass network is on account of the increase of number of Non-Bridging Oxygens created by network modi?er samarium ions. Scanning Electron Microscopy (SEM) image showed a smooth surface for the synthezied glass. X-Ray Di?raction (XRD) technique was employed to verify the amorphous nature of the glasses. A Makishima and Mackenzie theoretical model gave acceptable approximation of elasticity constants viz. Young's modulus, shear modulus, bulk modulus and Poisson's ratio. The high Vickers hardness values evaluated with mechanical loads of 50, 100, 300, 500, 1000 g force, proved the stability of the glasses. Emission spectra showed a prominent transition 4G5/2 → 6H7/2 at 598 nm excited with 6H5/2 → 4P3/2 transition at 401 nm. Luminescence quenching e?ect was observed beyond 0.3 mol% Sm2O3 addition. The chromaticity coordinates (x, y) clustered in the orange-red region, making these Sm3+ doped lithium zinc alumino borate glasses suitable candidate for applications in LEDs and solid-state lasers.
关键词： XRD,Photoluminescence,Samarium,Vickers hardness,Radiation shielding,Makishima and Mackenzie,Rare earth
更新于2025-11-21 11:18:25
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Dual functionality of K0.3WO3/Ag2O nanocomposites for smart window: Energy saving and visible photocatalytic self-cleaning performance
摘要： Series of novel K0.3WO3/Ag2O nanocomposites were successfully prepared by simple two steps method. An exciting fact that near-infrared light shielding and visible photocatalytic self-cleaning effects are integrated into the K0.3WO3/Ag2O film (weight ratio of K0.3WO3 to Ag2O = 30) could offer significant potential applications in smart windows. Furthermore, the optical properties and photocatalytic activity of the composites could be tuned by adjusting the weight ratio of K0.3WO3 to Ag2O. The obtained K0.3WO3/Ag2O films presented enhanced photocatalytic self-cleaning performance compared with pure K0.3WO3 under visible light irradiation. The improved self-cleaning performance of the K0.3WO3/Ag2O composites was ascribed to a combined contribution of the matched energy band structures and boosted separation efficiency of photo-generated carriers. An approximately 2.3°C-3.4 °C decrease in inner temperature was obtained for the heat box covered with K0.3WO3/Ag2O coated glass. Therefore, the proposed K0.3WO3/Ag2O (weight ratio of K0.3WO3 to Ag2O = 30) smart coating is a promising material for self-cleaning energy-saving windows.
关键词： Self-cleaning,Visible photocatalytic,Ag2O,KxWO3,Tungsten bronze,NIR shielding
更新于2025-11-19 16:56:35
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Transparent wood bearing a shielding effect to infrared heat and ultraviolet via incorporation of modified antimony-doped tin oxide nanoparticles
摘要： Optically transparent wood (TW) is an emerging candidate for applications in energy efficient buildings. In this study, anti-ultraviolet and infrared heat shielding TW was prepared based on the delignification of the wood's substrate. This was followed by infiltration of pre-polymerized methyl methacrylate (PMMA) with modified antimony-doped tin oxide (ATO) nanoparticles. The ATO addition enhanced the interfacial bonding among the compounds, which improved the fracture strength, leading to a high fracture strength of 96.4 MPa and modulus of 4.27 GPa with addition of 0.3% ATO. Furthermore, the obtained ATO/TW exhibited high transparency, excellent near infrared (NIR) heat shielding performance, and ultraviolet (UV) shielding properties according to the ultraviolet–visible spectrophotometer measurement, the infrared heat shielding simulation test, and the UV-shielding test. The TW treated with 0.3% ATO still maintained a very low thermal conductivity of around 0.2 W m?1 K?1. After addition of 0.7% ATO, the obtained TW had a quite low UV transmittance of ＜20%. The Aspergillus niger maintained high viability after UV irradiation treatment when shielded with TW treated with 0.7% ATO. The findings indicate that the multifunctional and durable ATO/TW has a potential to be used as energy-saving building material.
关键词： A. Nano composites,A. Wood,B. Ultraviolet shielding,B. Infrared heat shielding
更新于2025-09-23 15:23:52
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CsxWO3 nanosheet-coated cotton fabric with multiple functions: UV/NIR shielding and full-spectrum-responsive self-cleaning
摘要： Utilizing fewer functional materials to achieve multifunctional fabrics via facile approaches have been confronting worldwide scientists with an enormous challenge. In this study, a novel multifunctional cotton fabric, combining UV/NIR shielding and full-spectrum-responsive self-cleaning, has been fabricated via self-assembly of CsxWO3 nanosheets based on electrostatic interaction assisted by Poly (diallyldimethylammonium chloride) (PDDA) in aqueous solution. The microstructure of CsxWO3 nanosheets and their self-assembly coating on cotton fabric were characterized and investigated. The functional properties of the CsxWO3-coated cotton fabric, including UV/NIR shielding and photocatalytic self-cleaning were evaluated. The results indicate that the CsxWO3-coated cotton fabric exhibits superb UV/NIR and heat shielding performance with 15.8 °C and 5.9 °C lower than no coverage and coverage by none-treated cotton fabric, respectively. Moreover, the well-coated cotton fabric demonstrates photocatalytic self-cleaning property responsive to the light ranging from UV, Vis to NIR, especially exhibits highly efficient self-cleaning under the respective irritation of full-spectrum, UV and Vis light (color faded completely within 10 h). In summary, the CsxWO3-coated fabrics can achieve multi-functions of UV shielding, heat insulation and self-cleaning by means of a single functional nanomaterial and promise of huge applications in functional textiles.
关键词： full-spectrum self-cleaning,self-assembly coating,UV/NIR shielding,CsxWO3 nanosheets,functional cotton fabric
更新于2025-09-23 15:23:52
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Tailoring lattices of Bi2WO6 crystals via Ce doping to improve the shielding properties against low-energy gamma rays
摘要： In this study, lattices of Bi2WO6 crystals were tuned by cerium doping in a hydrothermal process in order to enhance the shielding properties against low-energy gamma rays. The products obtained were characterized by Raman, X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, and transmission electron microscopy techniques. The results demonstrated that cerium ions were successfully introduced into the lattices of the Bi2WO6 crystals and they partially replaced the bismuth ion sites. The shielding results showed that 10 mol% cerium doping allowed the Ce-doped Bi2WO6 crystals to shield against 59.5 keV gamma rays at a 49.41% better level compared with the original crystals. The enhanced shielding against low-energy gamma rays was ascribed to the expanded K-edge absorbing area of bismuth after cerium doping. In this study, we developed a facile synthetic method for obtaining Ce-doped Bi2WO6 materials. Importantly, these crystals could be used as functional fillers in rubber composites to prepare wearable products (such as clothing) with desirable shielding properties and no requirement for lead.
关键词： Bismuth tungstate,Gamma ray shielding,Cerium doping
更新于2025-09-23 15:23:52
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24.4: High Performance Top-gate Self-aligned Coplanar a-IGZO TFTs with Light Shielding Metal Design
摘要： The TG-SA a-IGZO TFTs with different light shielding metal (SM) layers design were demonstrated and compared in this paper. Their electrical characteristics have been measured in order to systematically analyze the effect that the SMs ever made on. The relationship between device instability and different SMs design have been systematically analyzed. Then the prototype 14” OLED display with an excellent performance using TG-SA a-IGZO TFTs backplane have been made successfully, which indicates an excellent mass-production prospect.
关键词： reliability,light shielding metal,top-gate self-aligned coplanar structure,a-IGZO TFTs
更新于2025-09-23 15:23:52
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Exploiting electrostatic shielding-effect of metal nanoparticles to recognize uncharged small molecule affinity with label-free graphene electronic biosensor
摘要： Label-free electronic biosensors as the non-electrochemical analytical tools without requirement of sophisticated instrumentation have become attractive, although their application in competitive affinity sensing of uncharged small molecules is hindered by a difficulty in the development of competing analogues. To break through this bottleneck, we report a novel analogue made by epitope-modified metal nanoparticles to enable the electronic signaling of small-molecule analyte recognition via competitive affinity. While the electronic signaling capability of metal nanoparticle analogues is demonstrated by a graphene field-effect transistor bioassay of small-molecule glucose as a proof-of-principle, interestingly, we discover a new electronic signaling mechanism in the metal nanoparticle affinity, different to the intuitive charge accumulation expectation. On the basis of Kelvin-probe force microscopic potential characterization and theoretical discussion, we fundamentally elucidated the signaling mechanism as a seldom used electrostatic shielding-effect, that is, in the analogue-receptor affinity, metal nanoparticles with the charge density lower than receptor biomolecules can reduce the collective electrical potential via charge dispersion. Further consider the convenient epitope-modifiability of metal nanoparticles, the easy-to-develop analogues for diverse target analyte might potentially be predictable in the future. And the application of label-free electronic biosensors for the competitive affinity bioassay of range-extended small molecules may thus be promoted based on the electrostatic shielding-effect.
关键词： electrostatic shielding-effect,competitive affinity,graphene field-effect transistor biosensor,uncharged small molecule,metal nanoparticle analogue
更新于2025-09-23 15:23:52
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[IEEE 2018 International Symposium on Electromagnetic Compatibility (EMC EUROPE) - Amsterdam (2018.8.27-2018.8.30)] 2018 International Symposium on Electromagnetic Compatibility (EMC EUROPE) - Terahertz Shielding Prediction of Id-Periodic N Anolayered Coatings by an Effective Homogeneous Model
摘要： An innovative effective-medium model of 1D-periodic multilayer coatings is developed by applying the transmission line method. Each period consisting of several layers with subwavelength thickness in the nanometer range is modelled as a homogeneous medium characterized by an effective complex conductivity and unit relative permeability. The resulting effective single layer (ESL), having the same total thickness of the multilayer laminate, is represented by a transfer matrix given by the product of the transmission matrices of the periods composing the structure. The effective homogeneous model is used to compute the shielding effectiveness of 1D-periodic photonic-band-gap transparent coatings made by alternating layers of silver and zinc oxide films in the frequency range up to 10 THz. The good accuracy of the results obtained using the ESL is demonstrated by comparison with the results computed by means of the rigorous multilayer formulation.
关键词： THz shielding effectiveness,1D-periodic multilayer coating,effective homogeneous model
更新于2025-09-23 15:23:52
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An investigation on shielding properties of BaO, MoO3 and P2O5 based glasses using MCNPX code
摘要： In the present work, some radiation shielding quantities (mass attenuation coefficients, effective atomic number, effective electron density, half value layer and mean free path) for various BaO–MoO3–P2O5 ternary glass systems have been determined within the 0.015–15 MeV energy range, using WinXCom program. Additionally, the mass attenuation coefficients of all the investigated glasses have been calculated using MCNPX simulation code (version 2.6.0) and compared to those of WinXCom results. Among the studied glasses, BaMoP8 glass sample with MoO3 content of 70% mol is found to have superior gamma-ray shielding characteristics. Moreover, the glasses studied in this paper possess better radiation shielding properties by providing shorter half value layer (HVL) than RS-253 G18 commercial glass and some concrete samples namely ordinary, hematite-serpentine and ilmanite-limonite.
关键词： Attenuation coefficients,MCNPX,MoO3-based glass,WinXCom,Radiation shielding
更新于2025-09-23 15:22:29
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AIP Conference Proceedings [Author(s) SolarPACES 2017: International Conference on Concentrating Solar Power and Chemical Energy Systems - Santiago, Chile (26–29 September 2017)] - Use of ilmenite and boron waste as a radiation shielding panel
摘要： Ilmenite is an important and interesting metallic oxide mineral. It is a titanium-iron oxide mineral with formula FeTiO3. It is the primary ore of iron and titanium metal. The largest boron mineral reserves in the world are located in Turkey. Each year 900,000 tons of boron waste results from boron production. Boron waste is caused big environmental problem in Turkey. In this study, evaluation of ilmenite and boron waste was performed to investigate the potential use in shielding materials. In this study, incorporation of ilmenite-boron waste has been investigated for its effect on the physical, morphological, mechanical and shielding properties. Several mixtures were prepared with different proportions of ilmenite and boron waste ranging from 0% to 50%. Then they dried and sintered at 1000, 1050 and 1100 (cid:113)C for 2 hours. Sintered samples were characterized.
关键词： environmental problem,ilmenite,boron waste,sintering,radiation shielding
更新于2025-09-23 15:21:21