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Anharmonic Effects in Single-Walled Carbon Nanotubes Analyzed through Low-Temperature Raman Imaging
摘要： The high thermal conductivity of single-walled carbon nanotubes (SWCNT) has gained much attention for their applications in potential thermal devices. Here, we investigate anharmonic effects, originated from phonon interactions, of SWCNT bundles by temperature dependent Raman imaging using our home-built mini cryostat system. The cryostat system is small enough to be mounted on a piezo scanner that suppresses thermal drift, enabling Raman imaging at different temperatures. We obtained Raman spectral images of several SWCNT bundles with a spatial resolution of a few hundred nanometers at different temperatures. We found that different bundles show different temperature dependences of Raman peak intensity, shift, and width. The temperature dependence was further elucidated by considering the sample topography observed by atomic force microscopy, where bundle effects seem to play an important role to influence the anharmonicity. The temperature-dependent Raman analysis based on spatially resolved imaging will be a powerful tool to investigate anharmonic effects of advanced carbon nanomaterials as well as to realize in-situ visualization of thermal properties for future thermal devices.
关键词： single-walled carbon nanotubes,anharmonic effects,low-temperature,Raman imaging,thermal properties
更新于2025-09-19 17:13:59
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Infrared reflectance, transmittance, and emittance spectra of MgO from first principles
摘要： By using density functional theory calculations we determined the influence of anharmonic effects on the infrared reflectance, transmittance, and emittance of MgO. The goal is to determine the limit of validity of a perturbative (multiphonon) approach. MgO is chosen as a test material because of the availability of different kinds of radiative properties measured experimentally. Nonanalytic terms of the three-phonon scattering coefficients are explicitly calculated and do not provide measurable effects. The agreement is overall very good to such an extent that, already at room temperature, one can clearly identify regions in which four-phonon scattering processes are dominant with respect to the three-phonon ones. The influence of isotopic disorder at cryogenic temperatures is also settled.
关键词： emittance,transmittance,density functional theory,MgO,infrared reflectance,anharmonic effects,phonon-phonon interactions
更新于2025-09-10 09:29:36