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Side-Slither Data-Based Vignetting Correction of High-Resolution Spaceborne Camera with Optical Focal Plane Assembly
摘要： Optical focal plane assemblies are increasingly being used in high-resolution optical satellite systems to enhance the width of the image using linear push-broom imaging. With this system, vignetting occurs in the area of overlap, affecting image quality. In this paper, using the characteristics of the side-slither data, we propose side-slither data-based vignetting correction of a high-resolution spaceborne camera with an optical focal plane assembly. First, the raw side-slither data standardization is used to ensure that each row has the same features. Then, with the spatial correlation of a gray-level co-occurrence matrix, the gray-level co-occurrence matrix is proposed to identify the uniform regions, to extract the sample points. Finally, due to the characteristics of compatible linear response and non-linear response, the power-law model was used to fit, and the Levenberg–Marquardt algorithm was used to fit the model. In the experiment, polynomial fitting, laboratory coefficients and on-orbit coefficients were used for comparison with the proposed method. The side-slither data can be treated as a uniform scene due to their characteristics, and the side-slither image that was corrected using the proposed method showed less than 1% change in mean value, a root-mean-square deviation value better than 0.1%, and the average streaking metrics were superior to 0.02. The results showed that the proposed method performs significantly better in the vignetting area.
关键词： push-broom,gray level co-occurrence matrix,high-resolution optical satellite,side-slither data,vignetting correction,Levenberg–Marquardt,power-law model,optical focal plane assembly
更新于2025-09-23 15:22:29
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Smart Supramolecular “Trojan Horse”-Inspired Nanogels for Realizing Light-Triggered Nuclear Drug Influx in Drug-Resistant Cancer Cells
摘要： Efficient nuclear delivery of anticancer drugs evading drug efflux transporters (DETs) on the plasma and nuclear membranes of multidrug-resistant cancer cells is highly challenging. Here, smart nanogels are designed via a one-step self-assembly of three functional components including a biocompatible copolymer, a fluorescent organosilica nanodot, and a photodegradable near-infrared (NIR) dye indocyanine green (ICG). The rationally designed nanogels have high drug encapsulation efficiency (≈99%) for anticancer drug doxorubicin (Dox), self-traceability for bioimaging, proper size for passive tumor targeting, prolonged blood circulation time for enhanced drug accumulation in tumor, and photocontrolled disassemblability. Moreover, the Dox-loaded nanogels can effectively kill multidrug-resistant cells via two steps: 1) They behave like a “Trojan horse” to escape from the DETs on the plasma membrane for efficiently transporting the anticancer “soldier” (Dox) into the cytoplasm and preventing the drugs from being excreted from the cells; 2) Upon NIR light irradiation, the photodegradation of ICG leads to the disassembly of the nanogels to release massive Dox molecules, which can evade the DETs on the nuclear membrane to exert their intranuclear efficacy in multidrug-resistant cells. Combined with their excellent biocompatibility, the nanogels may provide an alternative solution for overcoming cancer multidrug resistance.
关键词： nuclear delivery,photocontrollable drug release,cancer theranostics,silicon-based nanomaterials,supramolecular assembly
更新于2025-09-23 15:22:29
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Tertiary Amines Differentiated from Primary and Secondary Amines by Active Ester-Functionalized Hexabenzoperylene in Field Effect Transistors
摘要： Herein, we report two novel derivatives of hexabenzoperylene (HBP) that are functionalized with ester groups. Methyl acetate functionalized HBP (1) in single crystals self-assembles into a supramolecular nanosheet, which has a two-dimensional π-stack of HBP sandwiched between two layers of ester groups. With the same self-assembly motif, active ester-functionalized HBP (2) in field effect transistors has enabled differentiation of tertiary amines from primary and secondary amines, in agreement with the fact that active ester reacts with primary and secondary amines but not with tertiary amines to form amides.
关键词： sensors,organic field effect transistors,organic semiconductors,self-assembly,arenes
更新于2025-09-23 15:22:29
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Two-Dimensional Conducting Polymers: Synthesis and Charge Transport
摘要： Current technological advances and prolific endeavors have entrenched two-dimensional conducting polymers as the rapidly emerging interface across a diversity of functional materials for flexible electronics, sensors, ion-exchange membranes, biotechnology, catalysis, energy storage, and conversion. Rational design and fabrication of polymeric nanostructures enriched with well-ordered geometry are appealing and endorse significant impact on their inbuilt electrical, optical, and mechanical properties. In particular, recent interest in controlled hierarchical assembly of monomers/oligomers proved the free-standing sheet-like structures with exotic features of high conductivity and flexibility. Yet, the ongoing research to make nanometer-thick polymers suffers from limitations to access large-area, mechanical stability, and high-range internal ordering. In this perspective, we focus on the radical approaches that highlight confinement-entitled features of two-dimensional polymeric materials correlating to their interface or template-assisted synthesis, structure–property relationship, charge transport properties, and future scopes for relevant practical enactments.
关键词： 2D assembly,self-organization,conjugated polymers,charge transport,interfacial synthesis
更新于2025-09-23 15:22:29
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A fast method for preparing a large diameter, three-dimensional photonic crystal infrared stealth material
摘要： With the development of infrared detection technology, the threat of infrared detection technology to military targets in the battle?eld is becoming more and more serious. Novel infrared stealth materials are in urgent demand. Photonic crystals are promising infrared stealth materials because they can prohibit the propagation of electromagnetic waves in a certain frequency range. This paper outlines a simple and fast method to fabricate three-dimensional photonic crystals for stealth material. Monodisperse polystyrene colloid microspheres with a particle size of 2 μm were prepared and used in a gas–liquid interface self-assembly to form a three-dimensional photonic crystal infrared stealth material. The infrared absorption peak wavelengths of the material were 3.30 μm and 3.42 μm. The band gap is in good agreement with the photon forbidden band (3.24–3.44 μm) obtained from simulation and calculation using Rsoft software. The material meets the requirements of an infrared stealth material and realizes the modulation of the infrared radiation characteristics of the detectable band of 3–5 μm. The process provides a simple, economical, fast, and e?cient new method for the preparation of large diameter, three-dimensional photonic crystal infrared stealth materials.
关键词： Photonic crystal,Infrared stealth,Gas/liquid interface self-assembly
更新于2025-09-23 15:22:29
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Marangoni interface self-assembly hybrid carbon nano-network for transparent conductive silicone rubber
摘要： Inspired by compact one-dimensional (1D) and two-dimensional (2D) hybrid network like natural thrombosis and beaver’s dam, we use Marangoni interface self-assembly hybrid 1D carbon nanotube and 2D graphene (CNT+G) as continuously connected nano-network onto the surface of silicone ink coated silicone rubber. Both good optical transmittance and electrical conductivity demonstrated in the transparent conductive silicone rubber (TCSR). Besides, the TCSR also have excellent mechanical adhesion between the (CNT+G) film and silicone ink coated silicone rubber.
关键词： Adhesion,Marangoni interface self-assembly,Graphene,CNT,Transparent conductive silicone rubber
更新于2025-09-23 15:22:29
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Self-assembly of fractal liquid crystal colloids
摘要： Nematic liquid crystals are anisotropic fluids that self-assemble into vector fields, which are governed by geometrical and topological laws. Consequently, particulate or droplet inclusions self-assemble in nematic domains through a balance of topological defects. Here, we use double emulsions of water droplets inside radial nematic liquid crystal droplets to form various structures, ranging from linear chains to three-dimensional fractal structures. The system is modeled as a formation of satellite droplets, distributed around a larger, central core droplet and we extend the problem to explain the formation of fractal structures. We show that a distribution of droplet sizes plays a key role in determining the symmetry properties of the resulting geometric structures. The results are relevant to a variety of inclusions, ranging from colloids suspensions to multi-emulsion systems. Such systems have potential applications for novel switchable photonic structures as well as providing wider insights into the packing of self-assembled structures.
关键词： Self-assembly,Fractal structures,Topological defects,Colloids,Liquid crystals
更新于2025-09-23 15:22:29
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Low-cost light manipulation coatings for polymer solar cell photocurrent increase under various incident angles
摘要： We fabricate self-assembled templates to produce textured polydimethylsiloxane (PDMS) with quasi-random dimension distributions which are employed as light manipulation coatings in polymer solar cells (PSCs). When deposited at the PSC glass/air interface, PDMS films with microdome-like structures enhance the short-circuit current density (Jsc) by 7.9% through combined anti-reflective and scattering effects. The PSC power conversion efficiency can thus be improved from 6.75% to 7.28% and a maximum Jsc increase of 21% is observed for incident light tilted by 30 degrees. We compare structures with different diameter dispersities and confirm that quasi-randomness in textured coatings can increase their light scattering ability.
关键词： Nanofabrication,self-assembly,light manipulation,polymer solar cells
更新于2025-09-23 15:22:29
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[IEEE 2018 IEEE CPMT Symposium Japan (ICSJ) - Kyoto, Japan (2018.11.19-2018.11.21)] 2018 IEEE CPMT Symposium Japan (ICSJ) - 400G Multi-Mode and Single-Mode Optical Transmitter Realized by Hybrid-Integrated Silicon Interposer for Data Center Application
摘要： We experimentally demonstrated both 400G multi-mode (MM) and single-mode (SM) optical engines based on Silicon interposer to hybrid integrate laser dice, optics, and fiber arrays. The interposer realized by Silicon bulk micro-machining makes the engine very compact and easily assembled by the built-in Silicon precision. Clear optical eyes with TDECQ of 1.7dB and of 2.7 dB are obtained for 50Gb/s VCSEL in MM optical engine and 100Gb/s EML in SM one, respectively.
关键词： Optical Engine,Hybrid-Integration,VCSEL,Optical Sub-Assembly (OSA),and EML Laser,Silicon Interposer,Silicon Photonics
更新于2025-09-23 15:22:29
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Mechanically Enhanced Electrical Conductivity of Polydimethylsiloxane-Based Composites by a Hot Embossing Process
摘要： Electrically conductive polymer composites are in high demand for modern technologies, however, the intrinsic brittleness of conducting conjugated polymers and the moderate electrical conductivity of engineering polymer/carbon composites have highly constrained their applications. In this work, super high electrical conductive polymer composites were produced by a novel hot embossing design. The polydimethylsiloxane (PDMS) composites containing short carbon fiber (SCF) exhibited an electrical percolation threshold at 0.45 wt % and reached a saturated electrical conductivity of 49 S/m at 8 wt % of SCF. When reducing the sample thickness from 1.0 to 0.1 mm by the hot embossing process, a compression-induced percolation threshold occurred at 0.3 wt %, while the electrical conductivity was further enhanced to 378 S/m at 8 wt % SCF. Furthermore, the addition of a second nanofiller of 1 wt %, such as carbon nanotube or conducting carbon black, further increased the electrical conductivity of the PDMS/SCF (8 wt %) composites to 909 S/m and 657 S/m, respectively. The synergy of the densified conducting filler network by the mechanical compression and the hierarchical micro-/nano-scale filler approach has realized super high electrically conductive, yet mechanically flexible, polymer composites for modern flexible electronics applications.
关键词： compression-induced percolation threshold,synergy,electrical conducting network,hybrid filler,forced assembly
更新于2025-09-23 15:22:29