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[IEEE 2019 Conference on Lasers and Electro-Optics Europe & European Quantum Electronics Conference (CLEO/Europe-EQEC) - Munich, Germany (2019.6.23-2019.6.27)] 2019 Conference on Lasers and Electro-Optics Europe & European Quantum Electronics Conference (CLEO/Europe-EQEC) - Up-Conversion Threshold under Concentrated Sunlight
摘要： We investigate the two-photon threshold of rare-earth up-conversion under concentrated sunlight, in a solar furnace that generates an irradiance of up to 2606 suns on the samples. One of the most efficient up-converters currently available, NaYF4: Er3+ was used. We established a threshold by experimentally observing the transition for up-conversion photoluminescence from a quadratic relation to linear relation as solar concentration was increased. We further investigated the role of energy transfer on the threshold, observing the same threshold for a higher Er3+ content of 50%, but a threshold that exceeds 2300 suns at 15% Er3+. In this way, a tangible limit for the benefit and effect of solar concentration on up-conversion can be obtained for photovoltaic and solar thermal applications.
关键词： photovoltaic,concentrated sunlight,up-conversion,photoluminescence,solar concentration,solar thermal applications
更新于2025-09-16 10:30:52
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Performance enhancement of bulk heterojunction organic solar cells using photon upconverter
摘要： In this article, we show that significant performance enhancement can be obtained by incorporating a photo upconverter layer in bulk heterojunction organic solar cells (BHJ OSCs). We systematically optimize the photon upconversion process for P3HT:PCBM, PSBTBT:PCBM, PBDTTT-C:PCBM and PTB7-Th:PCBM based BHJ OSCs using a simple numerical model followed by optoelectronic simulations. After verifying the integrated model of upconversion with experimental reports, we analyze each type of BHJ OSC incorporating photon upconversion layer having optimized spectral characteristics and estimate efficiency enhancement of ~30.8% (4.55% → 5.95%), ~24.3% (5.02% → 6.24%), ~28.9% (6.35% → 8.19%) and ~16.9% (10.55% → 12.34%) for P3HT:PCBM, PSBTBT:PCBM, PBDTTT-C:PCBM and PTB7-Th:PCBM based OSCs, respectively. We then show that effect of photon upconversion and localized surface plasmon resonance on the best performing OSC material considered in this work i.e. PTB7-Th:PCBM, is non-linear and predict a performance boost of mere ~2.3% (12.32% → 12.62%) from additional effort (due to plasmon resonance). Finally, we discuss possibility of extending the efficiency of PTB7-Th:PCBM based BHJ OSC beyond 16% using concentrated sunlight and a practically realizable upconverter layer.
关键词： Organic solar cell,Photon upconversion,Bulk heterojunction,Concentrated sunlight
更新于2025-09-16 10:30:52