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Novel solid polymer electrolyte based on PMMA:CH3COOLi effect of salt concentration on optical and conductivity studies
摘要： Novel solid polymer electrolyte (SPE) films based on poly(methyl methacrylate) (PMMA) and lithium acetate (CH3COOLi) with different weight ratios of PMMA:CH3COOLi wt% (60:40, 70:30, 80:20 wt%) were prepared by solution casting technique. XRD analysis confirmed the amorphous nature of Li–PMMA SPE films. FTIR analysis revealed the structural changes in polymer by complexation with Li salt. From the optical absorbance studies, the value of lowest energy band gap was found to be 3.06 eV for the composition, PMMA:CH3COOLi (60:40 wt%). From AC impedance studies, the highest value of ionic conductivity 8.21 × 10?5 S/cm at 303 K for the SPE film PMMA:CH3COOLi (60:40 wt%) is observed compared to the reported literature. From the results of Li–PMMA SPE film with high ionic conductivity, it is a promising material for the application of solid-state battery.
关键词： Band gap,Ionic conductivity,Dielectric measurements,Li–PMMA SPE
更新于2025-09-23 15:23:52
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Spatial Retrieval of Broadband Dielectric Spectra
摘要： A broadband soil dielectric spectra retrieval approach (1 MHz–2 GHz) has been implemented for a layered half space. The inversion kernel consists of a two-port transmission line forward model in the frequency domain and a constitutive material equation based on a power law soil mixture rule (Complex Refractive Index Model—CRIM). The spatially-distributed retrieval of broadband dielectric spectra was achieved with a global optimization approach based on a Shuffled Complex Evolution (SCE) algorithm using the full set of the scattering parameters. For each layer, the broadband dielectric spectra were retrieved with the corresponding parameters thickness, porosity, water saturation and electrical conductivity of the aqueous pore solution. For the validation of the approach, a coaxial transmission line cell measured with a network analyzer was used. The possibilities and limitations of the inverse parameter estimation were numerically analyzed in four scenarios. Expected and retrieved layer thicknesses, soil properties and broadband dielectric spectra in each scenario were in reasonable agreement. Hence, the model is suitable for an estimation of in-homogeneous material parameter distributions. Moreover, the proposed frequency domain approach allows an automatic adaptation of layer number and thickness or regular grids in time and/or space.
关键词： soil measurements,electromagnetic scattering inverse problems,dielectric measurements,modeling,microwave propagation,dielectric materials
更新于2025-09-23 15:21:01
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Recycled polyolefin as dielectric substrate for patch antennas
摘要： High-performance antennas operating at ultra-high frequency (UHF) are typically designed and fabricated using specialized radio frequency (RF) materials with low loss and consistent properties. This paper proposes and investigates the use of recycled polyolefin (high-density polyethylene and polypropylene) which is not specifically manufactured for RF applications and thus with unknown RF properties, as dielectric substrate for high-performance UHF patch antennas. As a demonstrative application, a polarization-reconfigurable patch antenna with dual feeds is designed and fabricated using adhesive copper foil on recycled polyolefin substrate. Depending on the feed’s magnitude and phase, different types of linear and circular polarizations can be achieved. The point of resonance for both ports is centered at 915 MHz with 10 dB return loss and bandwidth of 28 MHz. Port isolation is as low as ?17 dB with peak linear and circular gain of 7.0 dBi, and 7 dBiC, respectively, observed in all polarizations. The resulting antenna not only performs well, but is also lightweight, low moisture absorbent, mechanically sturdy, inexpensive and ecologically friendly arising from its use of recycled materials.
关键词： microstrip antennas,dielectric materials,polarization-reconfigurable,UHF antennas,dielectric measurements,recycled polyolefin
更新于2025-09-12 10:27:22