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</sub> ) Interlayer
摘要: Electrical and dielectric properties of Au/n-Si metal–semiconductor structures with high dielectric have been examined by capacitance/conductance–voltage (C/G–V) measurements in the frequency range of 5–500 kHz at room temperature. Voltage-dependent profiles of interface states (Nss) and resistance (Ri) were extracted from the C and G data using the low–high-frequency capacitance and Nicollian–Brews methods, respectively. The real and imaginary components of the complex dielectric constant (ε', ε''), electric modulus (M', M''), and ac conductivity (σac) were calculated from the C and G data. All parameters have a strong relation with frequency and voltage, especially at low frequencies due to Maxwell–Wagner relaxation and Nss. The observed peaks in the Nss–V and Ri–V plots can be ascribed by the special distribution of Nss at M/S interface. These results confirmed that [2% graphene cobalt-doped (Ca3Co4Ga0.001Ox)] interlayer has high-dielectric constant and can be used an interlayer instead of the traditional SiO2 at M/S interface to increase their capacitance or more charges/energy storage and reduce both the values of Nss and series resistance (Rs). The values of σ are almost constant at lower–intermediate frequencies, but they start to increase at high frequencies that are corresponding to the dc and ac conductivity, respectively.
关键词: electrical properties,nanostructures,Dielectric properties,graphene,polymer
更新于2025-09-23 15:22:29
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Synthesis and Electrical Transport Properties of CuInGaTe2
摘要: Copper Indium Gallium di-telluride (CIGT) single crystals were synthesized by a special modified Bridgman technique for crystal growth. Our XRD patterns clearly exhibited single phase. The temperature dependence of the electrical conductivity σ(T), Hall coefficient RH(T) in CuInGaTe2 single crystals have been demonstrated over the temperature range 143-558 K for the first time. The Hall coefficient sign confirms the samples displays the p-type conducting. The temperature dependence of the conductivity, Hall coefficient, Hall mobility, and charge carriers concentration were investigated were presented with a clear and effective pictures. CuInGaTe2 single crystals revealed electrical band gaps (or "transport gaps") ranging from 0.64 eV to 0.85 eV. The results obtained from electrical conductivity and carrier concentration revealed the sample p-type with acceptor energy level equal to ≈ 0.027 eV. From the obtained experimental data, the main fundamental physical constants and others for crystals under consideration have been estimated.
关键词: Single crystals,Electrical conductivity,Cu–III–VI2 Chalcopyrite semiconductors
更新于2025-09-23 15:22:29
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[IFIP Advances in Information and Communication Technology] Computer and Computing Technologies in Agriculture X Volume 509 (10th IFIP WG 5.14 International Conference, CCTA 2016, Dongying, China, October 19–21, 2016, Proceedings) || Modelling and Predicting of Soil Electrical Conductivity and PH from Semi-arid Grassland Using VIS-NIR Spectroscopy Technology
摘要: The electrical conductivity (EC) and pH value are key indicators for soil physical and chemical properties, which can re?ect the level of soil acid and alkali, furthermore, in?uence the vegetation growth. The spectroscopy technique can estimate and evaluate electrical conductivity and pH value rapidly and ef?ciently, which can provide useful information on the real-time soil management in the semi-arid rangeland or grassland. We picked the semi-arid grassland of northern China covering an area about 200 km2 as the target research area, given that it is highly sensitive to grazing and mining affect. Soil samples were collected from 72 sampling sites in this area, which covered grazing exclusion, over grazing and grassland restoration area. The SVC HR-1024 spectroradiometer was used to acquire soil spectrum. This study aims to indicate the spectral characteristic for soil EC and pH, and propose a predicting modeling method with optimal input spectral region and transformation by comparing the support vector machine (SVM) regression method and partial least squares (PLSR) regression modeling method. Our results showed that: (1) once EC value is larger than 0.10 ls/m, the soil spectral re?ectance decreases with increasing of EC value. The absorption depth, width and area at 1900 nm reduce with increasing of EC value as well; (2) There are positive correlation between EC, pH value and soil spectral re?ectance. The highest correlation coef?cient value of 0.7 between pH and re?ectance is recorded at visible region around 500 nm; (3) The SVM modeling method produce the higher prediction accuracy (RPD = 2.18, RMSE = 0.035, R2 = 0.78 for EC, RPD > 3, RMSE = 0.349, R2 = 0.91 for pH) rather than PLSR methods in soil EC and pH prediction. This study indicated that it was possible to use the spectroradiometer technology to predict EC and pH value for the soil from semi-arid grassland, which would provide the basis for soil acid and alkali detecting using hyper-spectral remote sensing technology.
关键词: Semi-arid grassland,Spectral modeling and predicting,Soil electrical conductivity and pH,Spectral characteristic
更新于2025-09-23 15:22:29
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Promotion of Overall Water Splitting Activity Over a Wide pH Range by Interfacial Electrical Effects of Metallic NiCo-nitrides Nanoparticle/NiCo <sub/>2</sub> O <sub/>4</sub> Nanoflake/graphite Fibers
摘要: Many efforts have been made to develop bifunctional electrocatalysts to facilitate overall water splitting. Here, a fibrous bifunctional 3D electrocatalyst is reported for both the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER) with high performance. The remarkable electrochemical performance is attributed of the catalysts to a number of factors: the metallic character of the three components (i.e., Ni3N, CoN, and NiCo2O4); the electronic structure, nanoflake-nanosphere network with abundant electroactive sites, and the electric field effect at the interfaces between different components. The oxide–nitride/graphite fibers have the lowest overpotential requirements of 71 and 183 mV at 10 mA cm?2 for HER and OER in alkaline medium, respectively. These values are comparable to those of commercial Pt/C (20 wt%) and RuO2. The electrodes also show a response to HER and OER in both neutral and acid media. Furthermore, the 3D structure can be highlighted by all-round electrodes for overall water splitting. The calculations on the changes in electrons transfer and the Femi level from oxides to oxides/nitrides reveal that the observed superb electrocatalytic performance can be attributed to the presence of Ni3N and CoN derived from the in situ nitridation of NiCo2O4.
关键词: electrocatalysts,overall water splitting,interfacial electrical effects
更新于2025-09-23 15:22:29
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Surface passivation of GaAs (0?0?1) by Hg2Cl2 nanoplates combined with hexadecanethiol
摘要: Surface states in III–V semiconductor materials have detrimental effects on their optical and electronic properties, and the passivation of GaAs surface has become of longstanding interest. Here, we demonstrated a two-step process to greatly reduce surface states of GaAs (0 0 1) by a combination of Hg2Cl2 and alkanethiol. Firstly, uniformly distributed Hg2Cl2 nanoplates with a size around 200 nm were deposited on GaAs surface by the incubation of the etched wafer into the mercury (II) chloride solution, without the need of a reducing agent. Secondly, hexadecanethiol (HDT) molecules were assembled on the Hg2Cl2-GaAs hybrid surface, which decreases the density of surface states through electron transfer processes. Noticeably, after such two steps, a significant enhancement of photoluminescence (PL) signal was noted. It may be due to the fact that components of As2O3 and As0 which are identified as major sources of the surface states are reduced considerably, or even disappear. Chemical state changes of mercury species are expected to play a key role in achieving the surface passivation. Obtained hybrid GaAs materials with considerably improved photonic signals open a new avenue for the fabrication of electronic and optoelectronic devices.
关键词: Surface states,GaAs (0 0 1),Hg2Cl2 nanoplate,PL enhancement,Electrical passivation
更新于2025-09-23 15:22:29
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High frequency electromagnetic energy phenomena in chiral dielectric structures with distributed and localized conductive insertions
摘要: Chiral dielectric structures with conductive insertions have the tendency to peculiarly concentrate the electromagnetic energy, subject to their specific architecture. The study analyses the associated heating effect at high transmission levels at GHz frequency, for the applications related to electromagnetic shielding. The favorable shielding structure can suffer, in well defined situations, a mechanical stress and/or an acceleration of aging mechanisms.
关键词: Numerical analysis,Electrical properties,Honeycomb,Thermal analysis
更新于2025-09-23 15:22:29
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The influence of Ag doping and annealing on phase, structural and carrier transport characteristics of CIS thin films
摘要: The un-doped and Ag-CIS thin films were deposited on quartz glass substrates by single source thermal evaporation method. Then, some CIS films were annealed in vacuum or N2 atmosphere from 350 °C to 550 °C. The results of XRD patterns showed the phase compositions of CIS thin films were changed with the increase of annealing temperature. Meanwhile, the results of Raman measurement confirmed a dramatic transition from CA phase to CH phase. Furthermore, the Ag atoms could promote the recrystallization process and the transition from CA phase to CH phase, which might result in the improvement of optical-electrical properties of CIS film. The transient photocurrent of the CIS-3 sample annealed at 450 °C was higher than those of other samples, which might be related to the good crystal quality. The results of I-V curves confirmed the N-type conduction of CIS-3 films, which was consistent with the results of EDS measurement. The C-V results of CIS-2 films also were the same as the results of EDS measurement. Furthermore, for the CIS-2 samples, with increase of annealing temperature, the change of conduction type may be related to the S element volatilization under vacuum situation and the decomposition of the substitutional defects AgIn.
关键词: Doping,CIS,Optical-electrical Properties,Photocurrent,Annealing
更新于2025-09-23 15:22:29
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On the anomaly in the electrical characteristics of thin film transistors with multi-layered sol-gel processed ZnO
摘要: A set of bottom-gate Zinc Oxide (ZnO) thin film transistors (TFTs) with active layers containing 1, 4 and 8 layers of spin-coated ZnO were fabricated and their electrical characteristics such as transistor transfer and capacitance-voltage characteristics were analyzed. The transconductance of the single-layered ZnO transistor shows a single peak. On the other hand, multiple peaks and humps were observed in the transconductance and capacitance-voltage characteristics of multi-layered ZnO transistors. The multi-layers were grown by reiteration of the spin-coating process, producing ZnO-ZnO interlayer-interfaces. The surface of the ZnO layer in contact with the ambient contains active sites, resulting in chemisorption of ambient gases such as oxygen prior to the deposition of subsequent layers. The chemisorbed species become negatively-charged and form charge sheets, depleting the surface/interface region. It was proposed that the formation of depletion layers at ZnO-ZnO interlayer-interfaces is the main cause for the observed anomaly.
关键词: Sol-gel,Zinc oxide,Spin-coating,Thin-film transistors,Electrical Properties,Interface Defects
更新于2025-09-23 15:22:29
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Physical and electrical properties of nitrogen-doped hydrogenated amorphous carbon films
摘要: Nitrogen-doped hydrogenated amorphous carbon films (a-C:H:N) have been prepared by a plasma-activated chemical vapor deposition technique (PACVD) by using a plasma beam source (PBS). The properties of the a-C:H:N films were changed by varying the total pressure, the substrate temperature (100 °C, 300 °C) and nitrogen partial pressure p(N2) by adding nitrogen to the precursor acetylene (C2H2). For the investigations, a-C:H:N films have been deposited onto glass slides and doped silicon wafers. The deposition rate decreased with increasing nitrogen content in the N2/C2H2 gas mixture and with decreasing total pressure. The elemental composition of two sample series (300 °C) has been analyzed with Elastic Recoil Detection Analysis (ERDA). The highest N content and N/C ratio was estimated to be 16 at.% and 0.25 at the highest p(N2), respectively. Microhardness measurements showed that the hardness decreased with increasing p(N2). Electrical resistance of the a-C:H:N films was measured by 4-point probe. Electrically conductive coatings have been obtained by nitrogen-doped a-C:H films at higher substrate temperature (300 °C). The electrical resistance of the a-C:H:N films also decreases with decreasing total pressure, with the lowest value being about 1 Ohm cm. The film density was determined by means of X-ray reflectometry (XRR).
关键词: PACVD,carbon nitride films,electrical conductivity,DLC,carbon films,XRR
更新于2025-09-23 15:22:29
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[IEEE 2018 IEEE Energy Conversion Congress and Exposition (ECCE) - Portland, OR, USA (2018.9.23-2018.9.27)] 2018 IEEE Energy Conversion Congress and Exposition (ECCE) - Net Zero Energy Houses with Dispatchable Solar PV Power Supported by Electric Water Heater and Battery Energy Storage
摘要: Over a year, net zero energy (NZE) houses produce and feed zero net metered electrical energy to the grid. Technical challenges, notably the 'duck curve' arise due to the fact that peak solar generation and load demand are seldom coincident. Common approaches to mitigate this limitation include the curtailment of solar power, and the use of storage. Surplus solar energy may be stored in a battery, which can subsequently be discharged to supply the home electricity needs when demand is in excess. In addition to batteries, less expensive electric water heaters, which are ubiquitous, can be modified as energy storage systems, functioning as 'uni-directional batteries' by virtue of their high thermal mass. This paper proposes the use of a hybrid energy storage system including both batteries and variable power electric water heaters in NZE residences. It is demonstrated that the hybrid energy storage system along with solar PV generation coordinated and virtual power plant (VPP) controls would reduce the required battery size and ratings while still harvesting the maximum solar energy potential. The proposed control strategy enables the NZE homes to produce dispatchable power or behave like controllable loads, and benefits at the utility level are demonstrated by interconnection of NZE homes with an IEEE 13 node test feeder system. The technology has the potential to mitigate all issues related to solar power variability.
关键词: Net Zero Energy (NZE) Residences,Home Energy Management (HEM),Electrical Water Heater (EWH),Virtual Power Plant (VPP),Battery Energy Storage System (BESS)
更新于2025-09-23 15:22:29