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??a??Extended Spiro Corea??Based Nonfullerene Electrona??Transporting Material for Higha??Performance Perovskite Solar Cells
摘要： Electron transport materials (ETMs) play a significant role in perovskite solar cells (PSCs). However, conventional solution processable organic ETMs are mainly restricted to fullerene derivatives and it is challenging to obtain nonfullerene ETMs with satisfactory properties. In this work, a new organic semiconductor SPS-4F is synthesized by utilizing the classical spiro[fluorine-9′9-thioxanthene] unit to construct a π-extended core. Although spiro is normally used in hole transport materials, the new spiro derivative SPS-4F is successfully used as an ETM in inverted PSCs with power conversion efficiency over 20%. In addition, SPS-4F can strongly coordinate with MAPbI3 perovskite and lead to efficient surface trap passivation. The resultant PSCs exhibit excellent stability in air because of the hydrophobic property of SPS-4F. This work opens up opportunities to obtain a new family of ETMs based on spiro and paves a way to the fabrication of high-performance PSCs with low cost.
关键词： spiro derivatives,perovskite solar cells,nonfullerenes,passivation,electron transport materials
更新于2025-09-23 15:21:01
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Efficient Structure for InP/ZnS-Based Electroluminescence Device by Embedding the Emitters in the Electron-Dominating Interface
摘要： The charge-carrier distribution has been an important parameter in determining the efficiency of quantum-dot-based light-emitting diodes (QLEDs). In this Letter, we demonstrate a new inverted device structure of ITO/ZnO/polyethylenimine/quantum dots (QDs)/1,3,5-tris(N-phenylbenzimidazole-2-yl)benzene (TPBi)/4,4′-bis(9-carbazolyl)-2,2′-biphenyl (CBP)/MoO3/Al for improving the efficiency of InP-QD-based QLEDs. By introducing a thin layer of electron transport materials, the hole accumulation at the hole transport layer and the QD interface is largely reduced, which suppresses the quenching effect of holes on the QD emission. Compared with the conventional device structure with the emitters at ZnO/CBP pn junction, the peak current efficiency (external quantum efficiency) increases from 3.83 (5.17 cd/A) to 6.32% (8.54 cd/A) by imbedding the QDs at the electron-dominating interface of ZnO/TPBi. The analysis reveals that an internal quantum efficiency of nearly 100% is achieved for the InP-QD-based device (with a photoluminescence quantum yield of 32%). This work provides an alternative device structure for achieving high-efficiency QLED devices.
关键词： electron transport materials,quantum-dot-based light-emitting diodes,internal quantum efficiency,charge-carrier distribution,InP-QD-based QLEDs
更新于2025-09-23 15:19:57
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Molecular engineering of an electron-transport triarylphosphine oxide-triazine conjugate toward high-performance phosphorescent organic light-emitting diodes with remarkable stability
摘要： Organic electron-transport materials are an essential component to boost performances and stability of organic light-emitting diodes. We present a robust organic electron-transport compound 3-(6-(3-(4,6-bis(4-biphenylyl)-1,3,5-triazin-2-yl)phenyl)pyridin-2-yl)phenyldiphenylphosphine oxide by facilely coupling the triphenylphosphine oxide moiety to the 2-phenyl-4,6-bis(4-biphenylyl)-1,3,5-triazine unit via a 2,6-pyridinylene linker. It is well soluble in weakly polar solvents and possesses a high Tg of 123 °C with an exceptional Td≈470 °C at 1% weight loss and deep HOMO/LUMO levels of ca. ?6.45/?3.06 eV. The phosphorescent spectrum measured in solid state at 77 K reveals a notable triplet energy of 2.88 eV. n-Doping with 8-hydroxyquinolatolithium (Liq) produces the electron mobility value of 4.66×10?5–3.21×10?4 cm2 V?1 s?1@(2–5)×105 V cm?1. Moreover, the contrasting solubility of the bromo reaction intermediate and the new compound in alcoholic solvents facilitates separation. The characterizations of bottom- and top-emission green phosphorescent OLEDs involving this single Liq-doped electron-transport layer reveal long stability. In particular, the latter provides outstanding performances with 77.4 cd A–1 (corresponding to an EQE of 18.7%) and 86.8 lm W–1@ca. 1000 cd m?2, based on the green emitter bis(2-phenylpyridine)(2-(4-methyl-3-phenylphenyl)pyridine)iridium(III). Moreover, driven by a constant current for ca. 640 h, the initial luminance of 1000 cd m–2 appears almost no decay.
关键词： halogen impurities,heterocycles,electron-transport materials,lifetime,phosphine oxides
更新于2025-09-19 17:13:59
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[IEEE 2019 TEQIP III Sponsored International Conference on Microwave Integrated Circuits, Photonics and Wireless Networks (IMICPW) - Tiruchirappalli, India (2019.5.22-2019.5.24)] 2019 TEQIP III Sponsored International Conference on Microwave Integrated Circuits, Photonics and Wireless Networks (IMICPW) - A Novel Perovskite Solar Cell with ZnO-Cu <sub/>2</sub> O as Electron Transport Material-Hole Transport Material
摘要： Perovskite solar cells have gained remarkable position among the emerging photovoltaic technologies, owing to their increased power conversion efficiency exceeding 20%. The development of various electron transport materials (ETM), perovskite absorbers, hole transport materials (HTM) have contributed well in the efficiency enhancement and stability improvement. One of the major development is the use of ZnO as ETM that replaces TiO2. ZnO has material properties similar to that of TiO2 but possesses improved electron mobility. Moreover, ZnO fabrication methods are easier and of low cost. Cuprous oxide (Cu2O), an earth abundant inorganic p-type material, is recently investigated as a best hole transport material that can replace Spiro-OMeTAD. In this paper, the performance of a planar CH3NH3PbI3 based solar cell using ZnO as ETM and Cu2O as HTM is evaluated using SCAPS 1D software. The combination of ZnO ETM and Cu2O HTM improves the charge transport and reduces the cost. The overall conversion efficiency obtained for the proposed ZnO ? Cu2O perovskite solar cell using CH3NH3PbI3 by SCAPS simulation is 22.77%. The performance of CH3NH3PbI3 based solar cells with ZnO as ETM and with various hole transport materials such as spiro-OMeTAD, CuI, CuSCN and NiO are evaluated and compared with the proposed structure using SCAPS software. The result indicates that ZnO ? Cu2O as ETM-HTM pair is a reliable configuration for CH3NH3PbI3 based solar cell.
关键词： Perovskite,Electron transport materials,Hole transport materials,SCAPS 1D software
更新于2025-09-16 10:30:52
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[IEEE 2019 10th International Conference on Computing, Communication and Networking Technologies (ICCCNT) - Kanpur, India (2019.7.6-2019.7.8)] 2019 10th International Conference on Computing, Communication and Networking Technologies (ICCCNT) - An organic-inorganic solar cell with graphene as an electron transport layer: an approach to increase the carrier collection efficiency
摘要： Methyl-Ammonium lead halide based solar cell has shown a tremendous approach to fulfill the energy crisis on the earth for its high efficiency and low manufacturing cost. While there are some other materials which influence the execution of Perovskite sunlight based cell, these materials are nothing but the electron as well as hole transport materials. In this article the behavior and performances of electron transport materials are mostly focused which generally increase the proficiency of Perovskite solar cell by simultaneously increasing the open circuit voltage and short circuit current. The role of graphene as an electron transport material is mainly discussed and also compared with some other metal oxide electron transport material as well as organic-based electron transport material. As keeping graphene as an electron transport material the predicted results of Perovskite solar cell are as follows: - maximum power conversion efficiency (PCE) = 23.42%, short-circuit-current-densit=3.25A/m2,open-circuit-voltage=0.86v,fill factor=0.83au. So graphene-based electron transport material can be the entry for the improvement of Perovskite solar cell.
关键词： electron transport materials,fill factor,efficiency,open circuit voltage,graphene,Perovskite solar cell,short-circuit current density
更新于2025-09-16 10:30:52
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Non-conjugated polymers as thickness-insensitive electron transport materials in high-performance inverted organic solar cells
摘要： Two non-conjugated polymers PEIE-DBO and PEIE-DCO, prepared by quaternization of polyethyleneimine ethoxylate by 1,8-dibromooctane and 1,8-dichlorooctane respectively, are developed as electron transport layer (ETL) in high-performance inverted organic solar cells (OSCs), and the effects of halide ions on polymeric photoelectric performance are fully investigated. PEIE-DBO possesses higher electron mobility (3.68×10?4 cm2 V?1 s?1), higher conductivity and more efficient exciton dissociation and electron extraction, attributed to its lower work function (3.94 eV) than that of PEIE-DCO, which results in better photovoltaic performance in OSCs. The inverted OSCs with PTB7-Th: PC71BM as photoactive layer and PEIE-DBO as ETL exhibit higher PCE of 10.52%, 9.45% and 9.09% at the thickness of 9, 35 and 50 nm, respectively. To our knowledge, PEIE-DBO possesses the best thickness-insensitive performance in polymeric ETLs of inverted fullerene-based OSCs. Furthermore, PEIE-DBO was used to fabricate the inverted non-fullerene OSCs (PM6:Y6) and obtained a high PCE of 15.74%, which indicates that PEIE-DBO is effective both in fullerene-based OSCs and fullerene-free OSCs.
关键词： Electron transport materials,Organic solar cells,Thickness-insensitive,Non-conjugated polymer
更新于2025-09-12 10:27:22