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- 2018
- Flexible display
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- electrowetting
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- Optoelectronic Information Science and Engineering
- South China Normal University
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Synthesis, Crystal Structure and Fluorescent Properties of 1D New Double Chain Silver(I) Complex
摘要: A novel silver(I) complex [Ag(btzx)2(NO3)]n [complex 1, where btzx = m-xylylenebis(tetrazole)] is synthesized and characterized by elemental analysis, IR, powder and single crystal X-ray diffraction. The crystal structural analysis shows that silver center is four-coordinated in a distorted tetrahedral geometry by four nitrogen atoms from four different btzx and there are very weak interactions exist between Ag(I) and NO3– anions. This complex displays a 1D ladder-like double chain framework, which is further fabricated into a 2D supramolecular framework via π–π interactions. The fluorescence properties of complex 1 were investigated.
关键词: Silver complex,Coordination polymers,Flexible ligand,m-Xylylenebis(tetrazole)
更新于2025-11-14 14:48:53
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TiO2-Coated Core-Shell Ag Nanowire Networks for Robust and Washable Flexible Transparent Electrodes
摘要: Silver nanowires (AgNWs) are the most promising materials to fabricate flexible transparent electrodes (FTEs) used in next-generation electronics. However, there are several bottlenecks for AgNWs-based FTEs to achieve large-scale applications, which are the thermal instability and rough surface topography of AgNWs and the poor interfacial adhesion between AgNWs and used substrate. To simultaneously address these aforementioned issues, a robust and washable FTE is prepared based on AgNW@TiO2 core-shell network embedding in polyimide (PI) substrate through a facile and scalable solution-based process. After treating with TiO2 sol, an ultra-thin, conformal, and continuous TiO2 shell is coated on AgNWs, which can effectively suppress the atomic surface diffusion. In comparison with pristine AgNW network that breaks into nanorods and nanospheres at 250 °C for 10 min, the AgNW@TiO2 core-shell network is stable at 300 °C, and its resistance just increases by a factor of 11 after annealing at 400 °C for 1 h. Furthermore, the TiO2 shell simultaneously increases the electrical and optical properties of AgNW network. After flowing PI precursors, drying, and thermally curing, the AgNW@TiO2 core-shell network is embedded on the surface of PI substrate with surface roughness of 1.9 nm. In addition to high thermal stability, the conductivity of the AgNWs@TiO2-PI composite FTE remains almost unchanged after repeated 3M tape peeling off cycles and mechanical bending cycles. It is also demonstrated that the AgNWs@TiO2-PI composite FTE is washable, and the relative change in resistance (?R/R0) is ~12% after 100 washing cycles in which a variety of stress situations occurring in combination.
关键词: flexible transparent electrodes,peeling off and mechanical stabilities,TiO2 sol,silver nanowire@TiO2 core-shell network,thermal and washing stabilities
更新于2025-11-14 14:32:36
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Improving performance and stability of planar perovskite solar cells through grain boundary passivation with block copolymer
摘要: Organic-inorganic metal halide perovskite solar cells (PSCs) exhibit excellent photovoltaic performance but suffer from instabilities against moisture and heat due to the inherent hydroscopic nature and volatility of their organic components. Herein, we report that employing block copolymer F127 as the passivation reagent in conjunction with solvent annealing process can efficiently improve the performance and stability of corresponding organic-inorganic PSCs. It is anticipated that the hydrophilic poly(ethylene oxide) tails of F127 polymers connect with contiguous perovskite crystals and passivate defects at perovskite grain boundaries, whereas the dangling hydrophobic poly(phenyl oxide) centers suppress perovskite decomposition caused by moisture and heat. After the optimization of the F127 additive, the planar PSCs with champion power conversion efficiencies of 21.01% and 18.71% were achieved on rigid and flexible substrates, respectively. The F127 passivation strategy provides an effective approach for fabricating high-efficiency and stable PSCs.
关键词: flexible solar cells,block copolymer,perovskite solar cells,interface passivation,stability
更新于2025-10-22 19:40:53
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Thermal atomic layer deposition of AlOxNy thin films for surface passivation of nano-textured flexible silicon
摘要: Aluminum oxynitride (AlOxNy) films with different nitrogen concentration are prepared by thermal atomic layer deposition (ALD) for flexible nano-textured silicon (NT-Si) surface passivation. The AlOxNy films are shown to exhibit a homogeneous nitrogen-doping profile and the presence of an adequate amount of hydrogen, which is investigated by Time-of-Flight Elastic Recoil Detection Analysis (ToF-ERDA). The effective minority carrier lifetimes are measured after the NT-Si surface passivation; the minimum surface recombination velocity (SRV) of 5 cm-s-1 is achieved with the AlOxNy film in comparison to the Al2O3 and AlN films (SRV of 7–9 cm-s-1). The better SRV with AlOxNy film is due to the collective effect of field-effect passivation by the presence of fixed negative charges, and chemical passivation by the presence of hydrogen within the film. The capacitance-voltage, and conductance measurements also are carried out using metal-oxide-semiconductor structure to determine the fixed negative charge density (Nf,ox), and defect density of states (Dit) in the AlOxNy films. The better surface passivation is attributed to unusually large Nf,ox of ~6.07 × 1012 cm-2, and minimal Dit of ~1.01 × 1011 cm-2-eV-1 owing to the saturation of Si dangling bonds by the hydrogen within the AlOxNy film matrix after the annealing step.
关键词: Surface passivation,Time-of-flight elastic recoil detection analysis (ToF-ERDA),Aluminum oxynitride,Thermal atomic layer deposition,Black flexible silicon
更新于2025-10-22 19:40:53
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[IEEE 2018 18th International Symposium on Antenna Technology and Applied Electromagnetics (ANTEM) - Waterloo, ON (2018.8.19-2018.8.22)] 2018 18th International Symposium on Antenna Technology and Applied Electromagnetics (ANTEM) - 3-D Printed Flexible Heterogeneous Substrates with Customizable Gain and Bandwidth
摘要: This paper presents a 3-D printed flexible heterogeneous substrate for wearable antennas with customizable bandwidth and gain. These performance parameters are modified by varying the ratio of percentage area of Acrylonitrile Butadiene Styrene (ABS) to NinjaFlex. Five flexible 3-D printed microstrip patch antenna (MPA) prototypes are designed, realized and measured each with different percentage area ratios, where the MPA’s RF performance is characterized with curvature. The five substrate designs are based on a combination of rigid ABS tiles of triangular shape surrounded with flexible NinjaFlex. All five designs show minimal antenna sensitivity to curvature, with a minimum resonant frequency shift of less than 1.2%. Results closely agree with simulations. Increasing the ABS area increases the MPA’s gain, but reduces the bandwidth and increases substrate rigidity. This results in a highly customizable and cost-effective substrate that allows the antenna designer flexibility in the choice of design parameters.
关键词: conformal antenna,3-D printing,wearable antenna,flexible,patch antenna,ABS,flexible electronics,NinjaFlex
更新于2025-09-23 15:23:52
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Free-standing highly conducting PEDOT films for flexible thermoelectric generator
摘要: Recently, organic thermoelectric (TE) materials especially conducting polymers have attracted increasing attention. In this work, we successfully synthesized ultrafine poly (3,4-ethylenedioxythiophene) (PEDOT) nanowires (NWs) (~10 nm) by a simple self-assembled micellar soft-template method and then obtain highly flexible free-standing PEDOT NW films by vacuum-assisted filtration. The films are with very high electrical conductivity (~1340 S cm?1). After being treated with 6 M H?SO? and then with 1 M NaOH at room temperature, the film shows an enhanced power factor of 46.51 μW m?1 K?2 (Seebeck coefficient of 25.5 μV K?1, electrical conductivity of 715.3 S cm?1), which increases by 54% compared with that of the pristine film. To the best of our knowledge, it outperforms the TE performance of all reported one-dimensional conducting polymer-based films. In addition, the TE performance of the film almost remains unchanged even after being bent for 200 times, indicating excellent flexibility. A flexible TE prototype composed of six strips (7 mm × 30 mm) of the as-prepared PEDOT NW films connected in series shows an output power of 157.2 nW at a temperature difference of 51.6 K. The free-standing PEDOT NW films show promise to a new generation of wearable TE devices.
关键词: Flexible,Thermoelectric,Free-standing,PEDOT,Highly conductive
更新于2025-09-23 15:23:52
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Flexible all-organic photorefractive devices
摘要: The objective of the present study is to demonstrate and evaluate the photorefractive (PR) performance of an all-organic PR device with a self-assembled monolayer (SAM)-modified organic conductive electrode of PEDOT:PSS coated on polyethylene terephthalate (PET). The PR composite consisted of a triphenylamine-based photoconductive polymer: poly(4-(diphenylamino)benzylacrylate) (PDAA), triphenylamine photoconductive plasticizer: (4-(diphenylamino)phenyl)methanol (TPAOH), nonlinear optical dye based on aminocyanostyrene: (4-asacycloheptylbenzylidenemalononitrile) (7-DCST), and soluble fullerene: [6, 6]-phenyl C61 butyric acid-methyl ester (PCBM). For comparison with the all-organic PR device, the PR performances using PET/ITO, glass/ITO, and glass/PEDOT:PSS substrates were also evaluated. The PR performance at an applied electric field of 40 V μm-1: diffraction efficiency and the response time of the PR device using PET/PEDOT:PSS-SAM substrate were 21.9%, and 390 ms, respectively. As a result of repeating bending test on this all-organic PR device, we found that the flexible PR device with PET/PEDOT:PSS-SAM substrate had a potential to withstand bending 10,000 times and revealed that the change in the haze value strongly influenced the degradation of PR performance.
关键词: All-organic,Photorefractive polymer,ITO-free device,PET substrate,PEDOT:PSS,Flexible
更新于2025-09-23 15:23:52
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Pay-As-You-Go financing: A model for viable and widespread deployment of solar home systems in rural India
摘要: Decentralised Solar Home Systems (SHSs) are established as an effective strategy to connect the ‘last mile’ without electricity access and leapfrog communities to clean energy solutions. According to the World Bank, the Pay-As-You-Go (PAYG) model has emerged as one of the effective commercially viable solutions to provide decentralised energy access to rural and remote communities in developing nations. The paying ability of households is a critical challenge for energy enterprises, and PAYG, with its easy payment schemes makes solar units affordable and allows households to gradually own these systems. The model also offers user training, ongoing maintenance, and service blocking functionality that minimises investment risk. The PAYG model has demonstrated huge success in Sub-Saharan Africa where Kenya pioneered the model as a cost competitive modern alternative for kerosene. One in five people in India lack access to electricity, and grid-connected rural communities often face frequent blackouts. With the advancement in distributed solar technologies and growing penetration of the mobile telecommunications network in India, PAYG could advance into a successful model to electrify communities living off the grid. Our analysis involves a two-dimensional approach where a systematic review of PAYG literature including case studies from Kenya and India was performed, followed by three expert interviews to further augment learnings and opportunities to deploy PAYG SHSs in India. This analysis finds that India's socio-political context seems suited for increased PAYG penetration, including utilising the opportunity provided by the country's Unified Payments Interface. This paper offers insights for practitioners and policymakers to consider the PAYG model to deploy clean electricity to households and rural micro-enterprises.
关键词: Public-private partnership,Decentralised renewable energy,Flexible repayment,Energy access,Rural electrification,Pay-As-You-Go model (PAYG)
更新于2025-09-23 15:23:52
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Resistive room temperature LPG sensor based on a graphene/CdO nanocomposite
摘要: The authors decribe an ultra-sensitive, room temperature, flexible transparent LPG sensor based on the use of a CdO/graphene nanocomposite. The graphene prevents the accumulation of CdO, enhances the surface area, and acts as a gas sensing material. FESEM images show a uniform decoration of CdO nanoparticles on graphene. The CdO/graphene composite was deposited as a film on interdigitated electrodes (IDEs) which then were used for chemiresistive sensing of liquid petroleum gas (LPG) by using a four probe technique. A Resistivity decreases significantly upon exposure to a LPG. The electrical resistance measurement at a constant bias voltage of 0.5 V. The sensor of type CdO/graphene (1 wt.%) exhibits a sensitivity of 600 ppm of LPG at 27 °C. It is a highly selective, stable and sensitive to low concentration of LPG even at room temperature.
关键词: Gas sensor,CdO,Liquefied petroleum gas,Graphene,Flexible
更新于2025-09-23 15:23:52
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Biocompatible and sustainable power supply for self-powered wearable and implantable electronics using III-nitride thin-film-based flexible piezoelectric generator
摘要: Energy harvesters that scavenge biomechanical energy are promising power supply candidates for wearable and implantable electronics. Of the most widely used energy harvesters, piezoelectric generators can generate more electric charge than their triboelectric counterparts with similar device size, thus are more suitable to make compact wearable devices. However, most high-power piezoelectric generators are made from lead zirconate titanate, making them undesirable for wearable applications due to the toxic lead element. In this study, a flexible piezoelectric generator (F-PEG) is fabricated with chemically stable and biocompatible Group-III-nitride (III-N) thin film by a layer-transfer method. The III-N thin-film F-PEG can generate an open-circuit voltage of 50 V, a short-circuit current of 15 μA, and a maximum power of 167 μW at a load resistance of 5 M?. Applications of the III-N thin-film F-PEG are demonstrated by directly powering electronics such as light-emitting diodes and electric watches, and by charging commercial capacitors and batteries to operate an optical pulse sensor. Furthermore, the III-N thin-film F-PEG shows good durability and a stable output after being subjected to severe buckling tests of over 30,000 cycles.
关键词: flexible,piezoelectric generators,thin film,III-nitride,self-powered system,biocompatible
更新于2025-09-23 15:23:52