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Efficient NDT small molecule solar cell with high fill factor by pendant group engineering
摘要： Three naphthodithiophene (NDT)-based small molecules, bearing hexyl- (NDT-Hex), null (NDT) and fluorene (NDT-F) substituents at the β-position of the thiophene vertically conjugated to the NDT core, were designed and synthesized. The photovoltaic effect of engineered NDT molecules was investigated with detailed characterization on optical absorption, electronic energy levels, blend morphology, carrier mobility and photovoltaic performance conducted. It shows that the hexyl-substitution enhances the morphological tunability for NDT molecules, which contributes to achieve promising power conversion efficiency (PCE) with high fill factor (FF). The optimized solar cells based on NDT-Hex:PC71BM blends obtains a PCE of 6.7% with an FF of 0.717 and it reaches 8.6% with an FF of 0.638 if a non-fullerene molecular acceptor, NBDTP-Fout, was adopted to blend with NDT-Hex. Both FF are among the top ones of respective kind of solar cells based on NDT small molecule. The work demonstrates a feasible morphology-tuning method toward efficient organic solar cells with high FF.
关键词： morphology-tuning,naphthodithiophene,small molecule solar cells,high fill factor,pendant group engineering
更新于2025-09-23 15:19:57
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Graphdiyne Derivative as Multifunctional Solid Additive in Binary Organic Solar Cells with 17.3% Efficiency and High Reproductivity
摘要： Morphology tuning of the blend film in organic solar cells (OSCs) is a key approach to improve device efficiencies. Among various strategies, solid additive is proposed as a simple and new way to enable morphology tuning. However, there exist few solid additives reported to meet such expectations. Herein, chlorine-functionalized graphdiyne (GCl) is successfully applied as a multifunctional solid additive to fine-tune the morphology and improve device efficiency as well as reproductivity for the first time. Compared with 15.6% efficiency for control devices, a record high efficiency of 17.3% with the certified one of 17.1% is obtained along with the simultaneous increase of short-circuit current (Jsc) and fill factor (FF), displaying the state-of-the-art binary organic solar cells at present. The redshift of the film absorption, enhanced crystallinity, prominent phase separation, improved mobility, and decreased charge recombination synergistically account for the increase of Jsc and FF after introducing GCl into the blend film. Moreover, the addition of GCl dramatically reduces batch-to-batch variations benefiting mass production owing to the nonvolatile property of GCl. All these results confirm the efficacy of GCl to enhance device performance, demonstrating a promising application of GCl as a multifunctional solid additive in the field of OSCs.
关键词： graphdiyne derivative,binary organic solar cells,high fill factor,high efficiency,solid additives
更新于2025-09-19 17:13:59
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Uniform Permutation of Quasi-2D Perovskites by Vacuum Poling for Efficient, High-Fill-Factor Solar Cells
摘要： It is widely accepted that vertically aligning quasi-2D perovskites can improve power conversion efficiency due to directional charge transport from small to large-n-value nanoplates. Here, we report a different strategy of uniformly arranging different-n-value 2D nanoplates (PEA2MAn-1PbnI3n+1) based on our vacuum poling method to enable superior isotropic carrier transport. Consequently, the high efficiency of 18.04% with open-circuit voltage of 1.223 V and champion fill-factor (FF) of 82.4% are demonstrated, presenting a new approach to develop advanced quasi-2D perovskite optoelectronic devices.
关键词： isotropic carrier transport,high-fill-factor,vacuum poling,solar cells,quasi-2D perovskites
更新于2025-09-11 14:15:04
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Fabrication of high fill-factor aspheric microlens array by dose-modulated lithography and low temperature thermal reflow
摘要： A cost-effective fabrication method for high quality and high fill-factor aspheric microlens arrays (MLAs) is developed. In this method, the complex shape of aspheric microlens is pre-modeled via dose modulation in a digital micromirror device (DMD) based maskless projection lithography system. Digital masks for several bottom layers are replaced from circle to hexagon for the purpose of enhancing the fill-factor of MLAs, then a low temperature thermal reflow process is conducted, after which the average surface roughness of microlens is improved to * 0.427 nm while the pre-modeled profile keeps unchanged. Experimental results show that the fabricated aspheric MLAs have almost 100% fill-factor, high shape accuracy and high surface quality. The presented method may provide a promising approach for rapidly fabricating high quality and high fill-factor aspheric microlens in a simple and low-cost way.
关键词： high fill-factor,dose-modulated lithography,aspheric microlens arrays,surface roughness,low temperature thermal reflow
更新于2025-09-04 15:30:14