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[IEEE 2018 43rd International Conference on Infrared, Millimeter, and Terahertz Waves (IRMMW-THz 2018) - Nagoya (2018.9.9-2018.9.14)] 2018 43rd International Conference on Infrared, Millimeter, and Terahertz Waves (IRMMW-THz) - Terahertz Quasiparticle Acceleration: From Electron-Hole Collisions To Lightwave Valleytronics
摘要： Intense lightwaves can accelerate quasiparticles inside solids. This strong-field light-matter interaction results in the emission of high-harmonic or high-order sideband radiation. While the former process relies on a complex coupling between simultaneously driven interband polarization and intraband currents, high-order sidebands originate from a ballistic acceleration of the quasiparticles within the bands. This mechanism allows for the implementation of a quasiparticle collider in order to study those entities in close analogy to conventional collision experiments. Accelerating electrons and holes in a monolayer of transition metal dichalcogenides extends this scheme to internal quantum degrees of freedom. Our experiments show a lightwave-induced switching of the valley pseudospin, paving the way to ultimately fast valleytronics.
关键词： valley pseudospin,terahertz,high-harmonic generation,lightwave valleytronics,electron-hole collisions,quasiparticle acceleration,high-order sideband radiation,transition metal dichalcogenides
更新于2025-09-04 15:30:14
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Enhanced photocatalytic simultaneous removals of Cr(VI) and bisphenol A over Co(II)-modified TiO2
摘要： To enhance the electron-hole separation and boost the practical performance of commercial titania (Degussa P25) under natural solar light, in this work, P25 was modified with Co(II) species (CoP25) through post-treatment with decomposition of Co-EDTA precursors in a wet chemical anchoring process. With appropriate Co(II) loading amount as molecular cocatalyst, the resulted CoP25-4 showed significantly improved photocatalytic performance for Cr(VI) reduction and bisphenol A (BPA) oxidation under UV-light irradiation. The co-existence of Cr(VI) and BPA promoted mutually the degradation of both pollutants. Under simulated solar light (AM 1.5G) illumination, the Cr(VI) reduction rate over CoP25-4 was 8.5 times enhanced compared with that over P25, while the simultaneous degradation rate of BPA over CoP25-4 was 8 times higher than that over P25. Further investigations indicated that the covalent atomic Co(II) anchoring on P25 significantly promoted the photogenerated electron-hole separation and facilitated Cr(VI) reduction via the formation of Co(I) intermediate and simultaneously boosted BPA oxidation. Our results demonstrated a facile strategy to modify P25 with remarkably improved performance for the practical application in environmental pollution management under natural light excitation.
关键词： bisphenol A,electron-hole separation,Cr(VI) reduction,photocatalytic,Co(II)-modified TiO2
更新于2025-09-04 15:30:14