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Precursor engineering for performance enhancement of hole-transport-layer-free carbon-based MAPbBr3 perovskite solar cells
摘要： An optimized two-step sequential deposition method to fabricate hole-transport-layer-free carbon-based methyl ammonium lead bromide (MAPbBr3) perovskite solar cells is reported. Small amounts of MABr are introduced into the PbBr2 precursor solution during the first step to prepare MAPbBr3 perovskite films (labeled as MAPB-xMABr), which promotes the conversion of PbBr2 into perovskite phase and results in denser perovskite films with increased crystallinity, lower trap density, and longer carrier lifetime. After optimization, a maximum power conversion efficiency (PCE) of 7.64% (VOC ? 1.36 V) is obtained for MAPB-0.2MABr based solar cells. Significantly, the non-encapsulated devices exhibit excellent long-term stability in ambient air (25e30 (cid:2)C and 20e30% relative humidity), showing no degradation after a year’s exposure. While, it also shows superior thermal stability with PCE retaining 95% of the initial efficiency after 120 h under thermal stress of 80 (cid:2)C and 40e70% relative humidity.
关键词： Perovskite solar cells,High stability,Precursor engineering,Hole transport layer free,Crystal growth
更新于2025-09-23 15:21:01
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Low Temperature Processed Highly Efficient Hole-Transport-Layer Free Carbon-based Planar Perovskite Solar Cells with SnO2 Quantum Dot Electron-Transport-Layer
摘要： The use of expensive hole transport layer (HTL) and back contact along with the stability issue of perovskite solar cells have been a detrimental factor when it comes to commercialization of the technology. In addition, high-temperature and long annealing time processed electron transport layers (ETLs, e.g., TiO2) prevents the flexible solar cell application in most polymer substrate. Herein, we opted for HTL-free carbon electrodes owing to their low-cost production and superior stability in air, compared to their noble metal counterparts. In this work, we fabricate planar perovskite solar cells using low-temperature solution processed SnO2 quantum dots (QDs) as ETL, which offers significant advantages over high temperature processed ETLs due to its excellent electron extraction and hole blocking ability. In addition, by integrating a low cost and stable carbon electrode, an impressive energy conversion efficiency of 13.64% with a device architecture glass/In doped SnO2/QD-SnO2/Perovskite/Carbon under 1 sun illumination at ambient conditions have been achieved. This work paves the way to achieve fully low-temperature processed printable perovskite solar cells (PSCs) at an affordable cost by integrating the QD SnO2 ETL and Carbon electrode.
关键词： low-temperature process,planar perovskite solar cells,hole transport layer free,carbon electrode,SnO2 Quantum Dot
更新于2025-09-19 17:13:59