- 标题
- 摘要
- 关键词
- 实验方案
- 产品
-
Binder- and conductive additive-free laser-induced graphene/LiNi1/3Mn1/3Co1/3O2 for advanced hybrid supercapacitors
摘要： Hybrid supercapacitors have recently emerged as next-generation energy storage devices that bridge the gap between supercapacitors and lithium-ion batteries. However, developing high energy cathodes that maintain long-term cycle stability and a high rate capability for real applications remains a significantly challenging issue. Herein, we report a facile synthesis method for a laser-scribed graphene/LiNi1/3Mn1/3Co1/3O2 (LSG/NMC) composite for high energy cathode materials for use in hybrid supercapacitors. LSG/NMC composites exhibit not only a high capacitance of up to 141.5 F/g but also an excellent capacitance retention of 98.1% after 1000 cycles at a high current density of 5.0 A/g. The introduction of an NMC spacer between the LSG layers provides an enlarged interspace that can act as an efficient channel for additional storage sites and rapid access. In addition, we further confirmed that hybrid supercapacitors using LSG/NMC cathodes and H2Ti2O25 anodes with an AlPO4/carbon hybrid coating layer (H-HTO) deliver a remarkable energy density of ~123.5 Wh/kg, power density of ~14074.8 W/kg, and a long-term cycle stability of 94.6% after 20,000 cycles. This work demonstrates that our proposed material can be considered a strong cathode candidate for next-generation hybrid supercapacitors.
关键词： laser-scribed graphene,high energy density,hybrid supercapacitors,LiNi1/3Mn1/3Co1/3O2,long-term cycle stability
更新于2025-09-19 17:13:59
-
Exploring Synergistic effect of Ni <sub/>x</sub> Sn <sub/>2x</sub> S <sub/>4x</sub> Thiospinel with MWCNTs with Enhanced Performance in Dye Sensitized Solar cells, Hydrogen Evolution Reaction and as Supercapacitor
摘要： Trifunctional nickel tin sulfide (NixSn2xS4x) thiospinel like structure composited with multiwall carbon nanotubes (MWCNTs) (M–NixSn2xS4x) was synthesized by a facial method. The unit cell arrangement of prepared composite has been studied by Density Functional Theory (DFT) and the theoretical interpretation satisfactorily inferred the presence of synergistic effect between thiospinel and MWCNTs. High metallic conductivity and superior electrocatalytic activities of M–NixSn2xS4x composite plays a prominent diverse roles as counter electrode for dye sensitized solar cells (DSSCs) with 4.67 % efficiency when compared to Pt (5.23 %) at fluorine doped indium tin oxide (FTO), efficient catalyst like Pt for hydrogen evolution reaction (HER) with good cyclic stability and low over potential of ?41 mV at the cathode current density of 10 mA cm2 and Tafel slope of 43 mV/dec at graphite sheet electrode and as impressive capacitance material at graphite sheet electrode alternate to an expensive current collectors like Ni foam with a specific capacitance value of 1,200 Fg?1 at current density of 1 Ag?1 and long life span of 92.6 % retained up to 15,000 cycles.
关键词： HER,Thiospinel,hybrid supercapacitors,cyclic stability,low overvoltage,DSSCs
更新于2025-09-19 17:13:59