- 标题
- 摘要
- 关键词
- 实验方案
- 产品
-
The low resistance and high sensitivity in stretchable electrode assembled by liquid-phase exfoliated graphene
摘要： Flexible electrodes have been extensively investigated to fulfill the development of highly advanced human interaction electronics. It’s still a challenge to develop the conductive film for the scalable device with low resistance under large deformation. In this work, we reported a stretchable conductive layer on elastomer substrates assembled by few-layer graphene, which was exfoliated in the low-boiling organic solvent with assistance of hyperbranched copolymer as stabilizer that was adsorbed on the nanosheets via CH-π non-covalent connections. The relative resistance change of graphene film is 117% as the mechanical strain reaches 35%, which retains high conductivity under tensile operation. The resistance of the graphene electrode is dependent on the overlapping of the nanosheets during the deformation, in which the slipping of nanosheets is due to the lubricant effect of the hyperbranched segments acting as dynamic CH-π interactions. This work highlights a general strategy of the stretchable conductive film for the flexible electronics, and sheds a light on the conduction mechanism for the graphene film during large deformation.
关键词： Stretchable,Graphene,Flexible electrode,Hyperbranched polymer
更新于2025-09-23 15:21:01
-
Planar perovskite solar cells using triazatruxene-based hyperbranched conjugated polymers and small molecule as hole-transporting materials
摘要： Conjugated polymers have been widely used as hole-transporting materials (HTMs) in planar perovskite solar cells (p-PSCs) and play a vital role in hole transport. In this work, based on triazatruxene (TAT), two hyperbranched conjugated polymers (named as TATF8HBP and TATSFHBP) and a star-shaped carbazole-functionalized small molecule (named as TATCz3) are employed as HTMs in p-PSCs with a well solubility. The differences of these materials between carrier mobility, hole extraction and transmission are investigated due to their discrepancy in molecular structure, leading to their photovoltaic performances sequence as follows: TATF8HBP (11.11%) > TATSFHBP (9.48%) > TATCz3 (0.87%). In addition, the short-circuit current density (Jsc), open circuit voltage (Voc) and fill factor (FF) of p-PSCs show the same trend as PCE does. The results reveal that TATF8HBP exhibits the best performance as a hole-transporting layer (HTL) since the polymer chain and its fluorene unit contribute to the hole transport.
关键词： perovskite solar cells,hyperbranched polymer,triazatruxene derivative,photovoltaic characteristics,hole-transporting materials
更新于2025-09-16 10:30:52