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Laser absorption spectroscopy of rare and doubly-substituted carbon dioxide isotopologues
摘要： Unambiguous detection of the clumped carbon dioxide isotopologue 13C16O18O with isotope ratio mass spectrometry is difficult due to isobaric interference on m/z = 47. We present an analytical technique based on direct absorption laser spectroscopy for precise, direct and simultaneous detection of all isotopologues involved in the isotope exchange reaction 12C16O2 + 13C16O18O ? 12C16O18O +13C16O2 and of 12C16O17O. The achieved precision of 2×10-5 for the 13C16O18O/13C16O2 and 12C16O18O/12C16O2 isotopologue ratios allows to determine the equilibrium constant K of the isotope exchange reaction with an external reproducibility of better than 2×10-5 (1σ) after 9 reference-sample comparisons. Each comparison requires 7 minutes. The isotopic composition of the pure gas can be simultaneously analyzed with a precision of 0.05‰ (1σ) for δ13C and δ18O, and 0.15‰ (1σ) for δ17O. The instrument deploys two interband cascade lasers (ICL) with center wavelengths of 4.3 μm and 4.4 μm. A custom-built optical cell has been designed for single pass and multi pass optical paths (pathlength ratio 1:100); it allows simultaneous detection of rare and abundant isotopologues. The setup is capable to analyze pure CO2 samples of ～100 μmol.
关键词： clumped isotope analysis,mid-IR lasers,tunable lasers,doubly substituted isotopologues,carbon dioxide,laser spectroscopy,laser absorption
更新于2025-09-12 10:27:22
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[IEEE 2019 Conference on Lasers and Electro-Optics Europe & European Quantum Electronics Conference (CLEO/Europe-EQEC) - Munich, Germany (2019.6.23-2019.6.27)] 2019 Conference on Lasers and Electro-Optics Europe & European Quantum Electronics Conference (CLEO/Europe-EQEC) - Characterization of the Verdet Constant of Dy <sub/>2</sub> O <sub/>3</sub> Ceramics in the Two-Micron Spectral Range
摘要： High-power solid-state mid-IR lasers are being actively developed, as they possess the key properties for a vast number of technological applications [1] (e. g. lidar, gas sensing, or pump sources optical parametric oscillators) and are in a high demand for basic research as well [2]. These potentialities have recently led to intensive investigations of new mid-IR laser gain media [3,4] and other optical elements. One of the key components under investigation is an optical isolator (OI), a magneto-optical device enabling safe operation of a laser by preventing harmful back-reflections into the laser cavity. The development of high-power OIs is particularly challenging due to the severe thermal effects which arise because of the relatively high absorption of the currently available magneto-optical elements. Therefore, a lot of scientific effort is being put into the research of novel magneto-optical materials with the desired properties: high Verdet constant, low absorption and excellent thermal properties. All of these properties enable a reduction of the heat generated in the magneto-optical element. A large number of new magneto-optical materials for high-power OIs have been reported in the recent years. The vast majority of these reports targeted materials suitable for the wavelengths around 1 μm (corresponding to the neodymium and ytterbium doped gain media) in the task to find a better alternative to the most commonly used magneto-optical material for this spectral range – the terbium gallium garnet (TGG) [5]. In this manner, materials based on highly magnetically active rare-earth ions (e. g. Ce3+ [6], Tb3+ [7] or Ho3+ [8]) have been established as a possible next generation of magneto-optical materials for the visible and near-IR OIs. Some of these materials possess local transparency windows in the mid-IR as well, however, reports dealing with their magneto-optical characteristics in this region (or reports of any other suitable materials) were so far very rare. Nevertheless, Verdet constants of CeF3 crystal [9], DyxY0.95-xLa0.05O3 ceramics (with variable doping X = 0.7 – 0.9) [10] and EuF2 crystal [11] have been recently reported at the wavelength of ~1.94 μm, having ~7, ~10 - 14, and ~12 rad/Tm respectfully. We present broadband experimental characterizations of the Verdet constant of three novel material samples of Dy2O3-based ceramics in a broad spectral range 0.6 – 2.4 μm with the relative error of the measurement ~5%. An analytical approximation of the data is a challenging task due to the multiple resonances and absorption bands of Dy3+ ions within the measured range and is currently under investigation. The obtained values for the Verdet constant at 1.94 μm were 17.8, 22.2 and 26.8 rad/Tm predicting a high potential for Dy2O3 ceramics utilization in a high-power mid-IR OIs. The measured transmittances of our samples at 1.94 μm were equal to 54%, 72% and 76%.
关键词： mid-IR lasers,optical isolators,magneto-optical materials,Dy2O3 ceramics,Verdet constant
更新于2025-09-12 10:27:22
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[IEEE 2019 Conference on Lasers and Electro-Optics Europe & European Quantum Electronics Conference (CLEO/Europe-EQEC) - Munich, Germany (2019.6.23-2019.6.27)] 2019 Conference on Lasers and Electro-Optics Europe & European Quantum Electronics Conference (CLEO/Europe-EQEC) - Annealing Influence on Structural and Luminescencent Properties of ZnSe:Fe
摘要： Zinc Selenide crystals doped with Iron are promising material to be used as an active media in tunable mid-IR lasers (4 ? 5 μm) [1]. The ZnSe:Fe lasing characteristics close to the theatrical maximum are obtained by optical excitation [2]. Nowadays other pumping methods are also being explored. Previously we have observed luminescence in the mid-IR spectral region with the maximum at the wavelength of 3.9 μm under electron-impact excitation. The present research is focused on the in?uence of annealing process in Zn atmosphere on defective-impurity compound (DIC) and intensity of mid-IR cathodoluminescence (CL). We studied DIC by two-photon confocal microscopy (TPCM) on Carl Zeiss LSM NLO 710 (commercially available equipment). The TPCM allows detecting edge luminescence (EL) (460-480 nm) and DIC (480 - 725 nm) as well as mapping luminescence distribution [3]. In the CL experiments, the crystals were excited by a pulsed electron gun with the accelerated electron energy of 36 kV [4]. A series of ZnSe single crystals doped with Fe by thermal diffusion from surface was subjected to the DIC and CL studies. The initial ZnSe plates were cut from boules grown from the melt by the Bridgman method with an addition of Tellurium. Iron concentrations varied from 0.01 to 14 wt.% as determined by XDR. The samples were observed by TPCM and CL before and after annealing in Zn atmosphere.
关键词： mid-IR lasers,ZnSe:Fe,two-photon confocal microscopy,cathodoluminescence,annealing
更新于2025-09-12 10:27:22