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Construction of a Noncentrosymmetric Luminescent Coordination Polymer from [BaL <sub/>3</sub> ] Unit (L = Pyridine-2,6-dicarboxylate Acid) and Li(I) Ion
摘要： This work presents the synthesis, crystal structure and properties of a novel noncentrosymmetric (NCS) coordination polymer (CP), namely, (Me2NH2)3[BaLi(2,6-PyDC)3(H2O)] (1) (2,6-PyDC = pyridine-2,6-dicarboxylate acid), which represents the first example of BaLi-CPs with 2,6-PyDC ligand. Single-crystal X-ray structural analysis reveals that the compound features a two-dimensional (2D) layered structure. The simplified structure of each layer belongs to the hcb topology. The second harmonic generation (SHG) response of 1 is about 0.5 times that of KH2PO4 (KDP) marker. What is more, 1 emits bright blue light upon the excitation of 365 nm UV light with the quantum yield (QY, Φ) of 1.63%. The successful construction of this compound convinces the feasibility of constructing NCS CPs via the combination of [BaL3] unit and Li(I) ion.
关键词： noncentrosymmetric,heterometallic complex,luminescence,nonlinear optics
更新于2025-09-23 15:23:52
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A SHG-active manganese coordination polymer with noncentrosymmetric structure based on achiral carboxyphosphinate ligand
摘要： The hydrothermal reaction of MnSO4 with the achiral 2-carboxyethyl(phenyl)phosphinate ligand (H2L) afforded a 2 D coordination polymer manganese phosphinate, [Mn(HL)2]n (1) (H2L ? 2-carboxyethyl(phenyl) phosphinic acid). It contains two types of dimeric ring motifs, which can generate a layer structure through edge-sharing. The interlayer stacking by C-H … p interactions between the C-H groups of the phenyl rings of HL- and the phenyl rings of the adjacent layers results in its crystallization in a noncentrosymmetric crystal structure with (43)2(46(cid:2)66(cid:2)83) topology. Compound 1 shows a second harmonic generation response that is 0.8 times that of urea. The luminescence spectrum indicates an emission maximum at 457 nm, attributed to an intra-ligand emission state.
关键词： noncentrosymmetric structure,manganese,coordination polymer,Hydrothermal synthesis
更新于2025-09-23 15:23:52
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Fundamentals and Applications of Nanophotonics || A dynamical, classical oscillator model for linear and nonlinear optics
摘要： In this chapter we will build and develop a self-consistent, classical oscillator model to describe linear and nonlinear optical interactions like refraction and frequency conversion in both centrosymmetric and noncentrosymmetric materials. In addition to being quite ubiquitous in all of physics, the classical oscillator model of matter is an enormously pedagogical tool that serves as a natural springboard to the description and understanding of quantum systems and leads to a rather detailed portrayal of all the dynamical factors that contribute to most linear and nonlinear optical phenomena. The method is endowed with causality as well as a natural degree of self-consistency that includes linear and nonlinear material dispersions, elements that are usually necessary to understand many of the subtleties of the interaction of light with matter. By way of examples, using this classical approach we will examine harmonic generation in bulk materials and in metal-based nanostructures. In centrosymmetric materials like metals (materials composed of molecules that lack a center of symmetry), second harmonic generation (SHG) arises mostly from nearly free, conduction electrons (nearly free because they are con?ned by the metal walls) and is due to a combination of spatial symmetry breaking (interfaces), the magnetic portion of the Lorentz force, and, to a lesser extent, the interaction of third harmonic (TH) and pump photons. By the same token, the third order nonlinearity (c(3)) gives rise to most of the TH signal, while to a small degree the interaction of pump and SH photons also produces cascaded, TH photons. The classical oscillator model will be pivotal in these systems as well, where a combination of free (Drude) and bound (Lorentz) electrons suf?ces to describe most linear and nonlinear optical phenomena.
关键词： Lorentz model,centrosymmetric materials,noncentrosymmetric materials,classical oscillator model,harmonic generation,linear and nonlinear optics,Drude model
更新于2025-09-16 10:30:52