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Infrared Light Management Using a Nanocrystalline Silicon Oxide Interlayer in Monolithic Perovskite/Silicon Heterojunction Tandem Solar Cells with Efficiency above 25%
摘要： Perovskite/silicon tandem solar cells are attractive for their potential for boosting cell efficiency beyond the crystalline silicon (Si) single-junction limit. However, the relatively large optical refractive index of Si, in comparison to that of transparent conducting oxides and perovskite absorber layers, results in significant reflection losses at the internal junction between the cells in monolithic (two-terminal) devices. Therefore, light management is crucial to improve photocurrent absorption in the Si bottom cell. Here it is shown that the infrared reflection losses in tandem cells processed on a flat silicon substrate can be significantly reduced by using an optical interlayer consisting of nanocrystalline silicon oxide. It is demonstrated that 110 nm thick interlayers with a refractive index of 2.6 (at 800 nm) result in 1.4 mA cm?2 current gain in the silicon bottom cell. Under AM1.5G irradiation, the champion 1 cm2 perovskite/silicon monolithic tandem cell exhibits a top cell + bottom cell total current density of 38.7 mA cm?2 and a certified stabilized power conversion efficiency of 25.2%.
关键词： monolithic perovskite/silicon tandem solar cells,infrared photocurrent absorption,nanocrystalline silicon oxide interlayers
更新于2025-10-22 19:40:53
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Mechanically Stacked, Two-Terminal Graphene-Based Perovskite/Silicon Tandem Solar Cell with Efficiency over 26%
摘要： A novel configuration for high-performant perovskite/silicon tandem solar cells is demonstrated using a facile mechanical stacking of the sub-cells. The resulting champion perovskite/silicon tandem solar cell exhibits a stabilized efficiency of 25.9% over an active area of 1.43 cm2.
关键词： graphene doping,stabilized efficiency,perovskite/silicon tandem solar cells,mechanical stacking
更新于2025-09-23 15:19:57
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Light Management in Monolithic Perovskite/Silicon Tandem Solar Cells
摘要： Perovskite/silicon tandem solar cells (TSCs), especially 2-terminal, with record efficiency of 28% already been realized, have presented great potentials to be low-cost and efficient substitutes for dominant silicon photovoltaics. It is quite realistic to achieve efficiencies exceeding 30%, which have been indicated by extensive optical simulations. Super light management in monolithic perovskite/silicon TSCs is one of the prerequisites to make it a reality. In this review, various forms of optical losses, such as reflection loss, parasitic absorption and current mismatch, are analyzed systematically to provide better understanding of the performance of perovskite/silicon TSCs. Particularly, a simple refractive index matching rule derived from the Fresnel equation is proposed as a basis of material selection and device design. Meanwhile, an overview of current strategies and challenges in monolithic perovskite/silicon TSCs is highlighted, comprising of bandgap engineering of perovskites and light trapping methods, aiming to provide guidance for further improvement of the tandem devices.
关键词： anti-reflection,light management,parasitic absorption,light trapping,current matching,monolithic perovskite/silicon tandem solar cells
更新于2025-09-19 17:13:59
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Large Area 23%-Efficient Monolithic Perovskite/Homo-Junction-Silicon Tandem Solar Cell With Enhanced UV Stability Using Down-Shifting Material
摘要： UV induced degradation and parasitic ultraviolet (UV) absorption by the 'sun-facing' carrier transport layer in a perovskite cell hinders stability and electrical performance when the perovskite cell is a top cell for a Si-based tandem. In this work, we tackle these issues by applying textured polydimethylsiloxane (PDMS) films that incorporate a down-shifting material (Ba,Sr)2SiO4:Eu2+ micron phosphor on the front of monolithic perovskite/silicon tandem cells. This film serves multiple purposes: antireflective control for the top cell, light trapping in the Si cell as well as absorbing UV and re-emitting green light with high quantum yield. When applied onto a 4 cm2 monolithic perovskite/silicon tandem solar cell, the power conversion efficiency was improved from 20.1% (baseline device without any anti-reflective film) to 22.3% (device with anti-reflective film but without the phosphors) and to 23.1% (device with down-shifting and antireflective film). The steady-state efficiency of 23.0% and a high FF of 81% achieved by the champion device are the highest values to date for a monolithic perovskite/Si tandem that uses homo-junction-silicon bottom cell. Moreover, results of continuous UV irradiation test show that this composite down-shifting antireflection film significantly enhances the UV stability for the tandem device. This work demonstrates an elegant approach for improving the efficiency and stability for larger area perovskite/silicon tandems.
关键词： perovskite/silicon tandem solar cells,down-shifting material,efficiency improvement,polydimethylsiloxane (PDMS),UV stability
更新于2025-09-16 10:30:52
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Two‐terminal Perovskite silicon tandem solar cells with a high‐Bandgap Perovskite absorber enabling voltages over 1.8?V
摘要： Perovskite silicon tandem solar cells are a promising technology to overcome the efficiency limit of silicon solar cells. Although highest tandem efficiencies have been reported for the inverted p‐i‐n structure, high‐efficiency single junction perovskite solar cells are mostly fabricated in the regular n‐i‐p architecture. In this work, regular n‐i‐p perovskite solar cells with a high‐bandgap mixed cation mixed halide absorber suitable for tandem solar cells are investigated by compositional engineering and the open‐circuit voltage is improved to over 1.12 V using a passivating electron contact. The optimized perovskite solar cell is used as a top cell in a monolithic perovskite silicon tandem device with a silicon heterojunction bottom cell allowing for voltages up to 0.725 V. The tandem solar cells with an active area of 0.25 cm2 achieve record open‐circuit voltages of up to 1.85 V and have efficiencies over 20%. Analyzing the perovskite absorber by spatially resolved photoluminescence measurements shows a homogenous and stable emission at ~ 1.7 eV which is an optimal value for tandem applications with silicon. The tandem solar cells are mainly limited due to a low current. A spectrometric characterization reveals that the perovskite solar cell is current limiting which could be improved by a thicker perovskite absorber.
关键词： spectrometric characterization,high‐bandgap perovskite absorber,perovskite silicon tandem solar cells
更新于2025-09-12 10:27:22