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Role of electron and hole centers in energy transfer in BaBrI crystals
摘要： In this paper we study a role of F-centers, hole centers and excitons in energy transfer in Eu-doped BaBrI crystals. Optical absorption spectra, thermally stimulated (TSL) and photostimulated (PSL) luminescence in wide temperature range 7-300 K are studied in undoped and doped with different concentrations of Eu ions BaBrI crystals. Based on experimental and calculated results two possible energy tranfer processes from host to Eu2+ ions are established.
关键词： energy transfer,thermoluminescence,alkali earth halides,scintillators,bromide,iodide,F-center,photostimulated luminescence
更新于2025-09-23 15:22:29
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Photostimulated and persistent luminescence of samarium ions in BaFCl
摘要： Storage phosphors with e?cient photostimulated luminescence (PSL) and/or persistent luminescence (PersL) are in great demand for a range of applications. In this paper, PSL, PersL and thermoluminescence (TL) of samarium ions doped in a macroscopic and sub-micron crystals of BaFCl are reported, and it is demonstrated that the co-precipitated BaFCl:Sm3+ sub-micron crystals become an e?cient photostimulable X-ray storage phosphor upon annealing in the temperature range of 200–500 °C. The dependence of storage phosphor properties on annealing temperature was investigated and it was found that the X-irradiated co-precipitated BaFCl:Sm3+ crystallites (~400 nm size) showed maximum PSL and PersL from both Sm2+ and Sm3+ ions when annealed at 500 °C for 4 h. From a comparison with data for the macroscopic crystal (~3 mm) and ball-milled nanopowders (~30 nm), it also followed that PSL and PersL in the BaFCl:Sm system is a?ected by the crystal size. TL from Sm2+ of the macroscopic crystal is compared with the TL of sub-micron powders annealed at di?erent temperatures.
关键词： Storage phosphor,Photostimulated luminescence,Samarium,Thermoluminescence,Persistent luminescence
更新于2025-09-10 09:29:36