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Inconel625/316L functionally graded material using spectral diagnostics during laser additive manufacturing process
摘要： In this paper, the composition of Inconel625/316L functionally graded material during the additive manufacturing process was monitored on-line by laser-induced plasma optical emission spectroscopy. Several spectral lines are used to establish the quantitative relationship between relative intensity, relative intensity ratio, plasma temperature, and functional gradient material composition variation. It is shown that the change between relative strength and compositional content is similar to actual expectations. But, the relationship between the relative intensity with Inconel625 content is nonlinear. Cr-I/Ni-I relative intensity ratios almost linearly decrease with increasing Inconel625 content. The linear correlation coe?cient of the best ?tted curve was 0.943, and the maximum percentage error was 7.5%. The plasma temperature was obtained by the Boltzmann plot using ?ve neutral chrome lines between 330 and 380 nm. Plasma temperature almost linearly increases with increasing Inconel625 content in a range. The linear correlation coe?cient of the plasma temperature ?tted straight line was 0.93, and the maximum percentage error was 2.7%. The feasibility of composition monitoring of gradient materials by spectral information during the additive manufacturing process was veri?ed.
关键词： plasma temperature,spectral diagnosis,laser additive manufacturing,composition monitoring
更新于2025-11-28 14:24:20
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Spectral characteristic of laser-induced plasma in soil
摘要： The spectral characteristic of laser-induced plasma in soil was studied in this work, plasma under the condition of different time delays and irradiances. Moreover, the time evolution characteristics of plasma temperature and electron density were discussed. Within the time delay range of 0–5 μs, the spectral intensity of the characteristic lines of Si Ⅰ: 288.158 nm, Ti Ⅰ: 336.126 nm, Al Ⅰ: 394.400 nm and Fe Ⅰ: 438.354 nm of the four main elements in two kinds of national standard soil decayed exponentially with time. The average lifetime of the spectral lines was nearly 1.56 μs. Under the condition of different time delays, the spectral intensity of Pb Ⅰ: 405.78 nm in soil increased linearly with laser energy. However, the slope between the spectral intensity and laser energy decreased exponentially with the increase of time delay, from 4.91 to 0.99 during 0–5 μs. The plasma temperature was calculated by the Boltzmann plot method and the electron density was obtained by inversion of the full width at half maximum (FWHM) of the spectrum. The plasma temperature decreased from 8900 K to 7800 K and the electron density decreased from 1.5×1017 cm-3 to 7.8×1016 cm-3 in the range of 0–5 μs.
关键词： soil,time delay,electron density,laser energy,LIBS,plasma temperature
更新于2025-09-23 15:19:57
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[IEEE 2019 PhotonIcs & Electromagnetics Research Symposium - Spring (PIERS-Spring) - Rome, Italy (2019.6.17-2019.6.20)] 2019 PhotonIcs & Electromagnetics Research Symposium - Spring (PIERS-Spring) - Near-surface Plasma Formation in Air under Action of Two Laser Pulses at Two Wavelengths on Titanium in the Air
摘要： The spectra and structure of the near-surface plasma formation were experimentally investigated with a two-pulse laser effect at wavelengths of 532 and 1064 nm on a titanium target in the air, depending on the time interval between laser pulses and their order. The dependences of the temperature of the laser plasma on the parameters of paired laser pulses were established for laser radiation power densities of q1.064 ≤ 3.9 · 109 W/cm2, and of q0.532 =≤ 2.7 · 109 W/cm2 at wavelengths of 1064 and 532 nm, respectively. It is shown that optimal conditions for recording the erosion plasma spectra are provided with a leading effect on second harmonic radiation with a time interval between laser pulses of 4–5 μs, which is important for increasing the efficiency of the laser emission spectral analysis and laser-plasma processing of materials.
关键词： two-pulse laser effect,titanium,plasma temperature,laser plasma,spectral analysis
更新于2025-09-19 17:13:59
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Near-Surface Plasma Formed by Dual-Pulse Laser Action at Two Wavelengths on Titanium in Air
摘要： Spectra and structures of near-surface plasma torches were studied experimentally by measuring the speci? c mass loss and plume luminosity caused by dual-pulse laser radiation at wavelengths 1064 and 532 nm on titanium in air as functions of the time between laser pulses and their sequence. Dependences of the laser-plasma temperature and concentration of charged particles on the paired laser pulse parameters were established at laser radiation power densities q1064 ≤ 3.1·109 and q532 ≤ 2.7·109 W/cm2 for λ = 1064 and 532 nm. The optimal conditions for recording erosion plasma spectra had the initial effect from second-harmonic radiation with a time interval between pulses of 4–5 μs; for speci? c mass loss, 3–6 μs. The results were important for enhancing the ef? ciency of laser emission spectral analysis and laser-plasma processing of materials.
关键词： speci? c mass loss,laser plasma,plasma-torch structure,plasma temperature,electron concentration,dual-pulse laser action
更新于2025-09-16 10:30:52
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Picosecond laser ablation and depth profile of Cu(In, Ga)Se2 thin film layer
摘要： Laser ablation based on picosecond laser was used to achieve the micro-analysis of Cu(In, Ga)Se2 (CIGS) thin film with the ablation crater diameter of 50 μm and the ablation crater central depth of 93 ± 13 nm. We achieved the depth profile of CIGS thin film with different laser shot number. The evolutions of spectral lines intensities of Ca from glass substrate and Ga and In from CIGS thin film layer, and intensity ratios of Ca/Ga and Ca/In could exhibit the change of the ablation volume, which could estimate the thin film thickness of single CIGS thin film layer. The average plasma temperature was calculated to be about 5243 ± 100 K, and the average electron density was calculated to be about 4.5×1016 cm?3. It is shown that our experimental setup is suitable to achieve a precise control and monitor the element compositions in each CIGS thin film layer in the research and in the production of CIGS solar cells.
关键词： Ablation morphology,Electron density,Cu(In, Ga)Se2 thin film,Picosecond laser induced breakdown spectroscopy,Plasma temperature
更新于2025-09-16 10:30:52
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Characterization of the fast ionization wave induced by a CO <sub/>2</sub> laser pulse in argon
摘要： Fast ionization wave (FIW), a postbreakdown phenomenon of laser-induced plasma, is observed for a laser intensity of 1011–1013 W/m2 using the CO2 laser pulse in the atmospheric pressure condition. FIW is distinguishable as “overdriven detonation” according to Raizer’s Chapmann-Jouguet detonation theory because FIW is known as the type of laser-absorption wave that has a higher propagation velocity than the laser-supported detonation wave (LSDW). Some reports have described the expansion of FIW using a solid-state laser. Nevertheless, the threshold phenomena between FIW and LSDW are not fundamentally understood. This study used the high-speed visualization and optical emission spectroscopy to investigate the transition of the laser-absorption wave in argon gaseous form. To elucidate the physics of the transition threshold, a 5 J CO2 pulse laser, an Echelle spectrometer, and an intensi?ed CCD camera are used for the quantitative investigation of the plasma temperature and density. Results demonstrate that the FIW front had an electron temperature of 0.7 eV and an electron number density of 2.5 × 1023 m?3. At the FIW–LSDW transition, the electron temperature increased by 1 eV, and the density decreased by 2.2 × 1023 m?3. Besides, the transition threshold and the existence of local-thermodynamic equilibrium were evaluated based on the electron temperature, and the density was obtained from the spectroscopic experiments.
关键词： plasma temperature,optical emission spectroscopy,fast ionization wave,plasma density,CO2 laser,laser-induced plasma
更新于2025-09-12 10:27:22
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One-point calibration of Saha-Boltzmann plot to improve accuracy and precision of quantitative analysis using laser-induced breakdown spectroscopy
摘要： Calibration-free laser-induced breakdown spectroscopy (CF-LIBS) has recently gained attention due to its potential to overcome matrix effects on quantitative analysis using LIBS. However, the efficiency of CF-LIBS may be compromised by uncertainties in the experimental and spectroscopic parameters. To minimize these uncertainties and improve quantitative analysis, the one-point calibration (OPC) method was recently introduced to empirically correct the emission line intensities in a Boltzmann plot. In this work, we used the OPC method on a Saha-Boltzmann plot to cover a large energy range and to obtain more precise and accurate plasma temperature and electron density (Ne) values than were obtained with a Boltzmann plot using OPC method. For the analysis, we prepared two sets of sodium chloride (NaCl) samples: one with graphite and another with calcium carbonate (CaCO3). We observed matrix effects when we evaluated the calibration curves of carbon line intensity as a function of carbon concentration. Corrections by the OPC method to the Boltzmann or Saha-Boltzmann plots minimized the matrix effects and also guaranteed that the calculated plasma temperature were the same for the primary elements of each sample, suggesting that they were in local thermodynamic equilibrium. When the OPC method was applied to the Saha-Boltzmann plot, we obtained an uncertainty of less than 0.5% for plasma temperature and Ne; an r2 value of 0.994; and a root mean square relative error (RMSRE) of 8% for C concentration. Meanwhile, the traditional OPC method resulted in an uncertainty of 2.3% for plasma temperature and Ne and a validation with r2 of 0.977 and RMSRE of 13% for C concentration. These results showed that the OPC method efficiently improved the quantitative analyses possible with the Saha-Boltzmann plot using CF-LIBS.
关键词： LIBS,Calibration-free model,One-point calibration,Electron density,Plasma temperature,Saha-Boltzmann plot
更新于2025-09-12 10:27:22
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High-density cascade arc plasma sources for application to plasma windows for virtual vacuum interfaces
摘要： We develop two cascade arc plasma sources for application to plasma windows for virtual vacuum interfaces. For windowless vacuum–atmosphere separation, a compact arc discharge source having a channel diameter of 3 mm is fabricated, and an atmospheric Ar thermal plasma is generated. For an alternative differential pumping system, separating low- and high-pressure vacuum chambers, a larger arc device with an 8-mm diameter is also constructed, producing a high-density He plasma. The performances of the two cascade arcs as plasma windows are investigated. The 3-mm arc discharge generates a steep pressure gradient of Ar 100 kPa–100 Pa through the discharge channel, while the 8-mm discharge apparatus isolates the high-pressure side at 7 kPa from the lower pressure of 54 Pa. Emission spectroscopy of visible and vacuum UV radiation reveals the characteristics of the Ar and He plasmas. Spectral analysis yields a plasma temperature of around 1 eV in both discharges. Stark broadenings of the H-b and Ar I lines give an electron density of 6.5 (cid:2) 1016 cm(cid:3)3 for Ar 60 A with a gas ?ow rate of 1.0 l/min and 4.7 (cid:2) 1013 cm(cid:3)3 under a He 100-A and 0.45-l/min condition.
关键词： electron density,plasma temperature,emission spectroscopy,virtual vacuum interfaces,He plasma,cascade arc plasma sources,plasma windows,Ar thermal plasma
更新于2025-09-04 15:30:14