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Mathematical modeling of heat distribution on carbon fiber Poly(ether-ether-ketone) (PEEK) composite during laser ablation
摘要： Since large amounts of energy are transferred precisely to the material in a very short time, laser and material parameters strongly affect the laser process quality. Mathematical modeling of heat distribution during cavity formation on carbon fiber reinforced PEEK composite material was performed. The temperature distribution equation has been obtained by the Fourier method. At the first stage, 1 J energy laser beam was sent onto the material and the cavity on the composite material was obtained. The constants in the temperature distribution equation obtained by making measurements over the cavity were found. Then the cavities were created with 2, 3 and 4 J laser beams to prove its reliability of the model. The results obtained from the measurement on the cavities and calculated from the temperature distribution equation were compared. Since the unidirectional carbon fibers were used, the obtained cavities have an elliptical shape. Verification experiments were carried out using two different heat conduction constants for in direction along fibers and perpendicular to carbon fibers. Experimental results and the mathematical model are in good agreement.
关键词： Mathematical modeling,Fourier method,Laser ablation,Fiber reinforced composites,Poly(ether-ether-ketone) (PEEK)
更新于2025-09-23 15:21:01
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Advances in Contact Angle, Wettability and Adhesion || Laser Surface Engineering of Polymeric Materials for Enhanced Mesenchymal Stem Cell Adhesion and Growth
摘要： Owing to them being relatively inexpensive and easy to manipulate, polymers are becoming more widely used within the biomedical industry for several different applications. As an example, because of its high wear resistance, low moisture absorption and high chemical resistance, poly(ether ether ketone) is commonly used as a biomaterial in the healthcare and biomedical industries. However, poly(ether ether ketone) surface properties are not optimum for efficient or enhanced bio-functionality, leading it to have somewhat inferior wettability and adhesion characteristics. On account of this, many researchers are now looking to employ surface engineering techniques to improve and enhance the surface properties of poly(ether ether ketone), enhancing its biomimetic nature and improving the bio-adhesion properties. This chapter discusses the importance of Mesenchymal Stem Cells (MSCs), the biological applications of poly(ether ether ketone) and the application of lasers for surface engineering of poly(ether ether ketone) for modifying mesenchymal stem cell response. Through the application of CO2 laser surface engineering it has been shown that laser surface engineering can have a positive effect on the rate of human mesenchymal cell growth, highlighting the opportunities for the healthcare and biomedical industries to adopt such technique. In addition, discussion of including poly(ether ether ketone) and other polymer materials as bio-composite materials for future research is introduced for enhancing material properties.
关键词： surface modification,surface engineering,poly(ether ether ketone),Mesenchymal stem cells,polymeric biomaterials,bio-engineering,laser treatment
更新于2025-09-11 14:15:04
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A facile synthesis of graphene nanoribbon-quantum dot hybrids and their application for composite electrolyte membrane in direct methanol fuel cells
摘要： In this work, we report the concept of synthesizing graphene nanoribbon-graphene quantum dot (GNR-GQD) hybrids with even grafting of GQD on GNR sheet in a facile single step process under ultrasonication in chlorosulfonic acid. Further, diazotization route is followed for the preparation of 4-benzenediazonium sulfonate precursor to sulfonate both GNR and GQD to form sulfonated graphene nanoribbons-sulfonated graphene quantum dots (sGNR-sGQD) nanohybrids. Synergistic and structure dependent effect of nanohybrids is seen via its dispersion in sulfonated poly(ether ether ketone) (sPEEK) to form nanocomposite membrane. sPEEK/sGNR-sGQD (1.5 wt. %) nanocomposite membrane shows remarkable direct methanol fuel cell (DMFC) performance compared to pristine sPEEK and Nafion 117 with 40 % increment in peak power density along with higher durability up to 100 h due to better physicochemical properties like water uptake, ion exchange capacity, proton conductivity, and reduced methanol crossover to suggest its potential which includes diverse membrane applications.
关键词： Graphene nanoribbon-graphene quantum dot hybrids,Nanohybrids,Nanocomposite membrane,Sulfonated poly(ether ether ketone),Direct methanol fuel cell
更新于2025-09-10 09:29:36