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Elucidating Roles of Polymer Donor Aggregation in All-Polymer and Non-Fullerene Small-Moleculea??Polymer Solar Cells
摘要： The aggregation behavior of polymers plays a crucial role in determining the optical, electrical, and morphological properties of donor-acceptor blends in both all-polymer solar cells (all-PSCs) and non-fullerene small molecule acceptor-polymer solar cells (NFSMA-PSCs). However, direct comparison of the impacts on two different systems has not been reported, although it is important to design universal polymer donors (PDs). Herein, three PDs with different side chains (P-EH, P-SEH and P-Si) are designed to study the PD aggregation effects on the blend morphology and device performance of both all-PSCs and NFSMA-PSCs. It is observed that the aggregation property of PDs is a critical factor in determining the optimal blend morphologies and ultimately the device performances in both the PSC systems. Furthermore, PD aggregation effects on device performance is significantly more impactful in all-PSCs than in NFSMA-PSCs. The P-Si PD exhibiting the strongest aggregation behavior in a processing solvent produces the most severe phase separation in the blend with a polymer acceptor, resulting in the lowest power conversion efficiency (PCE) of all-PSCs. In contrast, when P-Si is used in an NFSMA-PSC, a well-mixed blend morphology is observed, which results in the highest PCE of over 12%. These different roles dependent on PD aggregation mainly originate from the difference in molecular size of polymer acceptor and small molecule acceptor, which influences the entropic contribution to the formation of blend morphology. Our work provides a comprehensive understanding on the PD aggregation-blend morphology relationship in different all-PSC and NFSMA-PSC systems, which serves as an important guideline for the design of universal PDs for both all-PSCs and NFSMA-PSCs.
关键词： polymer solar cells,all-polymer solar cells,non-fullerene small molecule acceptor-polymer solar cells,polymer donor aggregation,blend morphology,power conversion efficiency
更新于2025-09-19 17:13:59
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Alkyl Chain Tuning of Small Molecule Acceptors for Efficient Organic Solar Cells
摘要： A new non-fullerene acceptor, named N3, was developed by using a 3rd-position branched alkyl chain on the pyrrole motif of the molecule, which yielded better performance than the state-of-the-art acceptor Y6. Ternary devices were fabricated, achieving a power conversion efficiency of 16.74% in the lab and a certified efficiency of 16.42% by Newport.
关键词： power conversion efficiency,ternary strategy,non-fullerene acceptor,alkyl chain tuning,organic solar cells
更新于2025-09-19 17:13:59
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Trifluoromethylation Enables a 3D Interpenetrated Low-Band-Gap Acceptor for Efficient Organic Solar Cells
摘要： Herein, tri?uoromethylation has proven to be an effective strategy for ultra-narrow band-gap NFAs. A PCE of 15.59% is achieved from BTIC-CF3-g-based devices, which is the highest value in reported ultra-narrow band-gap acceptors. A ternary device with 16.50% ef?ciency is also obtained, resulting from its red-shifted absorption. Meanwhile, the single-crystal structure of BTIC-CF3-g has been successfully presented, which gives a deep understanding of the solid-state molecular packings in these highly ef?cient acceptors.
关键词： ultra-narrow band-gap,nonfullerene acceptors,tri?uoromethylation,power conversion efficiency,organic solar cells
更新于2025-09-19 17:13:59
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Secondary Grain Growth in Organica??Inorganic Perovskite Films with Ethylamine Hydrochloride Additives for Highly Efficient Solar Cells
摘要： The grain boundaries of perovskite polycrystalline are regarded as a defect region that not only provides carrier recombination sites but also introduces device degradation pathways. Efforts to enlarging the grain size of perovskite film and reducing its grain boundary are crucial for highly efficient and stable PSCs. Some effective methods that facilitate grain growth are post-deposition thermal annealing and solvent vapor annealing. However, a detailed understanding of grain growth mechanisms in perovskite films is lacking. In this study, perovskite films were prepared by adding ethylamine hydrochloride (EACl) to the precursor solution. This additive strategy promotes a new grain growth mode, secondary grain growth, in perovskite films. Secondary grain growth leads to much larger grains with high crystallographic orientation. These excellent properties lead to reduced grain boundaries and the densities of boundary defects. The improved film quality results in a prolonged charge–carrier lifetime and a significantly enhanced PCE. Compared with the PCE 18.42% of the control device, the PCE of the device with EACl additives reaches 21.07%.
关键词： Organic-inorganic perovskite,crystallographic orientation,grain growth,power conversion efficiency,solar cells
更新于2025-09-19 17:13:59
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Bandgap Tailored Nonfullerene Acceptors for Low-Energy-Loss Near-Infrared Organic Photovoltaics
摘要： A series of A?π?D?π–A type nonfullerene acceptors (NFAs) was designed and synthesized with the goal of optimizing light absorption and energy losses in near-infrared (NIR) organic solar cells (OSCs) principally through the use of side chain engineering. Specific molecules include p-IO1, o-IO1, p-IO2, and o-IO2 with optical bandgaps of 1.34 eV, 1.28 eV, 1.24 eV, and 1.20 eV, respectively. Manipulating the optoelectronic properties and intermolecular organization by substituting bulky phenylhexyl (p-) for linear octyl chains (o-) and replacing bisalkoxy (-O2) with alkyl-alkoxy combination (-O1) allows one to target energy bandgaps and achieve a favorable bulk heterojunction morphology when in the presence of the donor polymer PTB7-Th. Solar cells based on o-IO1 and PTB7-Th exhibit an optimal power conversion efficiency of 13.1%. The excellent photovoltaic performance obtained with the o-IO1 acceptor can be attributed to a short-circuit current of 26.3 mA cm?2 and energy losses on the order of 0.54 eV. These results further highlight how side chain engineering is a straightforward strategy to tune the molecular design of n-type molecular semiconductors, particularly in the context of near-infrared high efficiency organic photovoltaics.
关键词： side chain engineering,nonfullerene acceptors,power conversion efficiency,organic solar cells,near-infrared
更新于2025-09-19 17:13:59
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All-Small-Molecule Organic Solar Cells with an Ordered Liquid Crystalline Donor
摘要： A new small-molecule donor, namely BTR-Cl, which possesses a strong liquid crystalline property and high crystallinity, works well with the non-liquid crystalline acceptor Y6 and gives a record-high power conversion efficiency (PCE) of 13.6% in single-junction all-small-molecule organic solar cells. The BTR-Cl:Y6-based device was certified at the National Institute of Metrology, certifying a PCE of 13.0%.
关键词： All-small-molecule organic solar cells,Phase separation,Liquid crystalline donor,Power conversion efficiency,High crystallinity
更新于2025-09-19 17:13:59
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Light scattering effect of polyvinyl-alcohol/titanium dioxide nanofibers in the dye-sensitized solar cell
摘要： In the present work, polyvinyl-alcohol/titanium dioxide (PVA/TiO2) nanofibers are utilized as a light scattering layer (LSL) on top of the TiO2 nanoparticles photoanode. The TiO2 nanoparticles decorated PVA/TiO2 nanofibers display a power conversion efficiency (PCE) of 4.06%, which is 33% higher than tio2 nanoparticles without LSL, demonstrating the incorporation of PVA/TiO2 nanofibers as LSL reduces the radiation loss and increases the excitation of the electron that leads to high PCE. The incorporation of PVA/TiO2 nanofibers as LSL also increases the electron life time and charge collection efficiency in comparison to the TiO2 nanoparticles without LSL.
关键词： power conversion efficiency,dye-sensitized solar cell,PVA/TiO2 nanofibers,light scattering layer,electron life time
更新于2025-09-19 17:13:59
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Review on Recent Progress of All‐Inorganic Metal Halide Perovskites and Solar Cells
摘要： All-inorganic perovskites are considered to be one of the most appealing research hotspots in the field of perovskite photovoltaics in the past 3 years due to their superior thermal stability compared to their organic–inorganic hybrid counterparts. The power-conversion efficiency has reached 17.06% and the number of important publications is ever increasing. Here, the progress of inorganic perovskites is systematically highlighted, covering materials design, preparation of high-quality perovskite films, and avoidance of phase instabilities. Inorganic perovskites, nanocrystals, quantum dots, and lead-free compounds are discussed and the corresponding device performances are reviewed, which have been realized on both rigid and flexible substrates. Methods for stabilization of the cubic phase of low-bandgap inorganic perovskites are emphasized, which is a prerequisite for highly efficient and stable solar cells. In addition, energy loss mechanisms both in the bulk of the perovskite and at the interfaces of perovskite and charge selective layers are unraveled. Reported approaches to reduce these charge-carrier recombination losses are summarized and complemented by methods proposed from our side. Finally, the potential of inorganic perovskites as stable absorbers is assessed, which opens up new perspectives toward the commercialization of inorganic perovskite solar cells.
关键词： power conversion efficiency,solar cells,inorganic perovskites,stability,energy loss
更新于2025-09-19 17:13:59
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Surface-defect passivation through complexation with organic molecules leads to enhanced power conversion efficiency and long term stability of perovskite photovoltaics
摘要： Organic-inorganic hybrid lead halide perovskites (e.g., CH3NH3PbX3, X=Cl, Br, I) possess a unique combination of excellent electronic and photoelectrochemical properties including suitable and tunable bandgap, low exciton binding energy in the range of 9–80 meV, high extinction coefficient, and long electron and hole diffusion lengths, which make them excellent photovoltaic materials. The perovskite layer is at the core of perovskite solar cells (PSCs), whose quality would directly determine the device performance. The deficiency of long-term stability of the hybrid perovskite material has been one of the greatest barriers to the commercialization of PSCs. One of the most important strategies to achieve stable solar cells is to improve the intrinsic stability of the materials. Most recently, Wang et al. reported an in-depth systematic study on molecular defect passivation approaches through the interaction between organic functional groups and demonstrated both enhanced PCE and long term stability.
关键词： long term stability,power conversion efficiency,perovskite photovoltaics,surface-defect passivation
更新于2025-09-19 17:13:59
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Metala??organic framework nanosheets for enhanced performance of organic photovoltaic cells
摘要： Metal-organic nanosheets (MONs) are an emerging class of two-dimensional materials whose diverse and readily tunable structures make them ideal for use in optoelectronic applications. Here, liquid exfoliation is used to synthesize ultrathin zinc-porphyrin based MONs with electronic and optical properties ideally suited for incorporation into a polythiophene-fullerene (P3HT-PCBM) organic solar cell. Remarkably, the addition of MONs to the photoactive layer of a photovoltaic device results in a power conversion efficiency of 5.2%, almost twice that for reference devices without nanosheets with a simultaneous improvement of Jsc, Voc and FF. Our analysis indicates that the complimentary electronic, optical and structural properties of the MONs allows them to act as a surface to template the crystallization of P3HT leading to a doubling of the absorbance, a tenfold increase in hole mobility and reduced grain size. These results demonstrate the potential of MONs as a tunable class of two-dimensional materials for enhancing the performance of a broad range of organic solar cells and other electronic devices.
关键词： Metal-organic nanosheets,organic photovoltaic cells,power conversion efficiency,liquid exfoliation,zinc-porphyrin
更新于2025-09-19 17:13:59