Optical microscopy unveils rapid, reversible electrochemical oxidation and reduction of graphene

摘要： We unveil the reaction dynamics of monolayer graphene in electrochemical oxidation and reduction processes through interference reflection optical microscopy. At 300-nanometer spatial resolution and 200-millisecond temporal resolution, we reveal rapid electrochemical oxidation of graphene, as well as its efficient electrochemical reduction back to the unoxidized state. We identify 1.4 V (vs. Ag/AgCl) as the onset voltage for oxidation, and show that the process is driven by free radicals generated in the electrolysis of water and so fully suppressible by a radical-trapping molecule. Moreover, we find the oxidation process to be spatially heterogeneous at the nanoscale, defect- and history-dependent, and characterized by a self-limiting effect unique to the two-dimensional system. We further demonstrate that electrochemical reduction rapidly reverses the oxidized graphene back to the unoxidized state in a controlled manner, and find strong dependency of reduction speed on the reduction voltage and pH, from which we conclude a one-to-one relationship between protons and electrons in the reduction process. Besides elucidating the electrochemical reaction mechanisms of graphene, our results point to new pathways to the controlled generation and fine-tuning of graphene derivatives through electrochemistry.