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Dielectric and Piezoelectric Properties of Textured Lead-Free Na0.5Bi0.5TiO3-Based Ceramics
摘要: This work provides a comparative study of the dielectric and piezoelectric properties of randomly oriented and textured 0.88Na0.5Bi0.5TiO3-0.08K0.5Bi0.5TiO3-0.04BaTiO3 (88NBT) ceramics. Textured ceramics were fabricated by template grain growth (TGG) method using NaNbO3 (NN) for templates. For textured ceramics with 4 wt% NN templates, a Lotgering factor of 96% and piezoelectric coe?cient d33 of 185 pC/N were obtained. Compared to the randomly oriented ceramics, textured ceramics show lower strain hysteresis (H = 7.6%), higher unipolar strain of 0.041% with corresponding large signal piezoelectric coe?cient d33* of 200 pm/V at applied ?eld of 2 kV/mm. This enhancement can be explained by the grain orientation along <001> direction by texturing, where an engineered domain con?guration is formed after polarization, leading to decreased hysteresis and increased piezoelectric property.
关键词: electrical conductivity,textured ceramics,template grain growth,piezoelectric materials
更新于2025-11-14 17:28:48
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Orientation factor and piezoelectric property in textured (K,Na)NbO <sub/>3</sub> system ceramics with minimal templates
摘要: To lower the sintering temperature and decrease the weight ratio of templates required for fabricating textured (K,Na)NbO3 (KNN) system ceramics, the method of preparing platelike NaNbO3 (NN) single-crystal particles for the templates was improved. The NN crystal particles synthesized by the single-step molten salt method using a mixed salt were treated by ultrasonic vibration and subsequently screened. Using these improved templates, we developed the fabrication method for the textured KNN system ceramics by which the weight ratio of the templates required for the orientation control can be reduced to 1/10 of the conventional weight ratio. The effects of decreasing the weight ratio of templates on sintering temperature, orientation factor, and piezoelectric properties were investigated. In addition, the effects of adding Bi2O3 to KNN calcined powder were also studied to suppress abnormal grain growth, which appears in the textured samples fabricated using smaller amounts of the templates.
关键词: reactive template grain growth,molten salt synthesis,Bi2O3 addition,lead-free piezoelectric materials,ultrasonic treatment,textured ceramics
更新于2025-09-23 15:21:01