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- 2018
- ac-dc difference
- Thermal transfer standard
- inductive voltage
- uncertainty budget
- pulse-driven ac Josephson voltage standard
- Measurement and Control Technology and Instruments
- National Institute of Metrology
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Effect of exciton diffusion on the triplet-triplet annihilation rate in organic semiconductor host-guest systems
摘要： We study the contribution of triplet exciton diffusion to the efficiency loss resulting from F?rster-type triplet-triplet annihilation (TTA) in organic phosphorescent semiconductor host-guest systems, using kinetic Monte Carlo (KMC) simulations. Our study focusses on diffusion due to F?rster-type guest-guest transfer, but includes also a comparison with simulation results for the case of Dexter-type guest-guest transfer. The simulations are carried out for a wide range of F?rster radii, and for guest concentrations up to 100 mol%, with the purpose to support analyses of time-resolved photoluminescence experiments probing TTA. We find that the relative contribution of diffusion to the TTA-induced efficiency loss may be deduced quite accurately from a quantitative experimental measure for the shape of the time-dependent photoluminescence intensity, the so-called r ratio. For small guest concentrations and F?rster radii that are most relevant to organic light-emitting diodes (OLEDs), the diffusion contribution is in general quite small. Under these weak-diffusion conditions, the absolute diffusion contribution to the TTA-induced efficiency loss can be understood quantitatively using a capture radius formalism. The effective guest-guest diffusion coefficient that follows from the TTA simulations, using the capture radius formalism, agrees well with the diffusion coefficient that follows from direct KMC diffusion simulations. The simulations reveal that the diffusion coefficient is strongly affected by the randomness of the distribution of guest molecule locations.
关键词： OLEDs,photoluminescence,kinetic Monte Carlo simulations,Dexter transfer,organic semiconductors,triplet-triplet annihilation,exciton diffusion,host-guest systems,F?rster transfer
更新于2025-09-23 15:23:52
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Scattering Effect Contributions to the Directional Canopy Emissivity and Brightness Temperature Based on CE-P and CBT-P Models
摘要： The directional anisotropy of canopy emissivity and brightness temperature in the thermal infrared band has widely been studied. However, the contribution of different scattering orders has been an open scientific question for many years. The recently proposed CE-P model enables us to analytically evaluate the different scattering orders. Herein, we derive expressions for the first double collisions (DCE12) and first triple collisions (DCE123). Our result shows that DCE123 can simulate the observed emissivity with an error less than 0.001 and that DCE12 is reasonably accurate when leaf emissivity is greater than 0.96. Numerical analysis shows that the contribution of quadruple or greater collisions can be ignored when the leaf (soil) emissivity is no less than 0.90. Furthermore, we develop the CBT-P model to simulate the directional brightness temperature (DBT) based on the new optimized CE-P model (DCE123) and validate it by 4SAIL (4-Stream Radiative Transfer Theory of Scattering by Arbitrary Inclined Leaves) and DART (Discrete Anisotropic Radiative Transfer) models. Both of isothermal (soil temperature is equal to leaf temperature) and nonisothermal (soil temperature is higher than leaf temperature) cases are considered. The maximum differences between the CBT-P model and 4SAIL (DART) are less than 0.35 K (0.42 K), the average differences between CBT-P and 4SAIL (DART) are less than 0.10 K (0.13 K), and the R2 is over 0.99 (0.95) with component emissivities larger than 0.90 and the difference between soil and leaf temperatures less than 20 K. The directional anisotropy of DBT is dominated by the zero-scattering and the single scattering terms according to the new developed CBT-P model.
关键词： directional canopy emissivity (DCE),CBT-P,Discrete Anisotropic Radiative Transfer (DART),4-Stream Radiative Transfer Theory of Scattering by Arbitrary Inclined Leaves (4SAIL),CE-P,directional brightness temperature (DBT)
更新于2025-09-23 15:23:52
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Regulating Charge-Transfer in Conjugated Microporous Polymer for Photocatalytic Hydrogen Evolution
摘要： Band gap engineering in donor-acceptor conjugated microporous polymers is a potential way to increase the solar energy harvesting towards photochemical water splitting. Herein, we report design and synthesis of a series of donor-acceptor CMPs [tetraphenylethylene (TPE) = donor and 9-fluorenone (F) = acceptor], F0.1CMP, F0.5CMP and F2.0CMP which exhibit tunable band gaps and photocatalytic hydrogen evolution from water. The donor-acceptor CMPs exhibit intramolecular charge transfer (ICT) absorption in the visible region (λmax=480 nm) and their band gap is finely tuned from 2.8 eV to 2.1 eV by increasing the 9-fluorenone content. Interestingly, they also show charge transfer emissions (in 540 -580 nm range), assisted by the energy transfer from the other TPE segments (not involved in CT interaction) as evidenced from fluorescence lifetime decay analysis. By increasing the 9-fluorenone content the emission color of the polymer is also tuned from green to red. Photocatalytic activities of the donor-acceptor CMPs (F0.1CMP, F0.5CMP and F2.0CMP) are greatly enhanced compared to the 9-fluorenone free polymer (F0.0CMP) which is essentially due to improved visible light absorption and low band gap of donor-acceptor CMPs. Among all the polymers F0.5CMP with an optimum band gap (2.3 eV) shows highest H2 evolution under visible light irradiation. Moreover, all the polymers show excellent dispersibility in organic solvents and also they are easily processed onto solid substrates.
关键词： Visible-light absorption,Conjugated polymers,Photocatalysis,Charge transfer,Energy transfer
更新于2025-09-23 15:23:52
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Versatile and Switchable Responsive Properties of a Lanthanide-Viologen Metal-Organic Framework
摘要： Metal–organic frameworks (MOFs) provide intriguing platforms for the design of responsive materials. It is challenging to mobilize as many components as possible of a MOF to collaboratively accomplish multiple responsive properties. Here, reversible photochromism, piezochromism, hydrochromism, ionochromism, and luminescence modulation of an ionic Eu(III) MOF is reported furnished by cationic electron-deficient viologen units and exchangeable guest anions. Mechanistically, the extraordinarily versatile responsive properties are owed to electron transfer (ET), charge transfer (CT), and energy transfer, involving viologen as electron acceptor, anion as electron donor, luminescing Eu(III) as energy donor, and anion-viologen CT complex or ET-generated radical as energy acceptor (luminescence quencher). Moreover, guest anions and waters provide flexible handles to control the ET-based responsive properties. Water release/reuptake or exchange with organic solvents can switch on/off the response to light, while reversible anion exchange can disenable or awaken the responses to pressure, light, and water release/reuptake. The impacts of water and anions on ET are justified by the high polarity and hydrogen-bonding capability of water, the different electron donor strength of anions, and the strong I?-viologen CT interactions. The rich responsive behaviors have great implications for applications such as pressure sensors, iodide detection, and chemical logic gates.
关键词： metal–organic frameworks,electron transfer,charge transfer,luminescence switches,piezochromism
更新于2025-09-23 15:23:52
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Highly Selective Fluorescent Probe Based on 2-(2′-Dansylamidophenyl)-Thiazole for Sequential Sensing of Copper(II) and Iodide Ions
摘要： A novel highly selective fluorescent probe based on 2-(20-dansylamidophenyl)-4-phenylthiazole (1) is developed for sequential sensing of copper(II) and iodide ions in acetonitrile. The fluorescence mechanism is based on cation-induced inhibition of excited-state intramolecular hydrogen transfer, intramolecular charge transfer, and metal–ligand electron/charge transfer. Subsequent iodide-induced extrusion of copper(II) results in partial revival of fluorescence. Probe 1 and its ensemble with copper (II) show high selectivity for copper(II) and iodide ions, respectively, in acetonitrile solution.
关键词： Excited-state intramolecular hydrogen transfer,I?,Cu2+,Intramolecular charge transfer,Dansyl-thiazole conjugate
更新于2025-09-23 15:23:52
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Micro Grating Deposition on Non-Planar Surfaces by Polymer-Assisted Transfer Printing
摘要： By spin-coating a few hundred of nanometer thick poly(methyl methacrylate) (PMMA) film on a micron or a sub-micron scale structure, the structure can be transferred on an arbitrary substrate. More precisely, by using a thin PMMA support layer and releasing the structure from the transient substrate into water, the PMMA with the structure can be collected on a desired substrate. Here, this technique is demonstrated to be suitable for transferring metallic binary grating and few-layer Bragg gratings from flat substrates onto 3D-printed convex lenses. Moreover, the thin PMMA film is sufficiently strong to support centimeter size free-standing areas. This enables fabrication of 1.5 μm thick, free-standing structure of a Bragg-grating with PMMA. Thus, the presented technique provides a powerful tool for transfer printing of micron scale structures.
关键词： transfer printing,non-planar surfaces,free-standing structures,microstructure transfer
更新于2025-09-23 15:23:52
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[IEEE 2018 IEEE PELS Workshop on Emerging Technologies: Wireless Power Transfer (WoW) - Montréal, QC, Canada (2018.6.3-2018.6.7)] 2018 IEEE PELS Workshop on Emerging Technologies: Wireless Power Transfer (Wow) - An Elliptical Magnetic Field-Orientated Control for Interoperability and Misalignment Tolerance in Inductive Power Transfer
摘要： To improve the interoperability and misalignment tolerance of the inductive power transfer (IPT) system, the concepts of circular rotating magnetic field control and elliptical rotating field orientated control(FOC) are proposed in this paper. The method of analogy analysis between LIM (liner inductive motor) and IPT is adopted to improve the magnetic field distribution characteristics. Detailed output voltage derivation of circular pads and DD pads under misalignment are given. An approximate calculation model is built to study the influence of end effect and gap variation on magnetic field distribution. Experimental results verify the laws of circular magnetic field and elliptical magnetic field.
关键词： misalignment,magnetic field-orientated control,analogy analysis,wireless power transfer,interoperability,inductive power transfer(IPT)
更新于2025-09-23 15:23:52
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Handling Electromagnetic Radiation beyond Terahertz using Chromophores to Transition from Visible Light to Petahertz Technology
摘要： An increase of the operating frequencies of electromagnetic waves leads from the well-established terahertz technology to the visual and reaches petahertz radiation. It is shown that electromagnetic radiation close to petahertz is attractive for technology where knowledge about radio waves can be applied. The dimensions of such radiation are still classically macroscopic; however, molecular components such as resonators were used where quantum mechanics rules have to be considered. Constructions of coupled resonators for energy transfer are as well demonstrated as molecular components for optical metamaterials.
关键词： Dyes,FRET,Energy transfer,Reflectance,Petahertz,Visible light,Resonators,Metamaterials,Terahertz,Electromagnetic radiation
更新于2025-09-23 15:23:52
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An Interplay between Photons, Canopy Structure, and Recollision Probability: A Review of the Spectral Invariants Theory of 3D Canopy Radiative Transfer Processes
摘要： Earth observations collected by remote sensors provide unique information to our ever-growing knowledge of the terrestrial biosphere. Yet, retrieving information from remote sensing data requires sophisticated processing and demands a better understanding of the underlying physics. This paper reviews research efforts that lead to the developments of the stochastic radiative transfer equation (RTE) and the spectral invariants theory. The former simplifies the characteristics of canopy structures with a pair-correlation function so that the 3D information can be succinctly packed into a 1D equation. The latter indicates that the interactions between photons and canopy elements converge to certain invariant patterns quantifiable by a few wavelength independent parameters, which satisfy the law of energy conservation. By revealing the connections between plant structural characteristics and photon recollision probability, these developments significantly advance our understanding of the transportation of radiation within vegetation canopies. They enable a novel physically-based algorithm to simulate the 'hot-spot' phenomenon of canopy bidirectional reflectance while conserving energy, a challenge known to the classic radiative transfer models. Therefore, these theoretical developments have a far-reaching influence in optical remote sensing of the biosphere.
关键词： vegetation remote sensing,stochastic radiative transfer equation,spectral invariants theory
更新于2025-09-23 15:23:52
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2-(1,1-dioxidobenzo[b]thiophen-3(2H)-ylidene)malononitrile (BTD) Based Styryl Chromophores- Solvatochomic and Computational Investigation of Linear and NLO properties
摘要： Linear and nonlinear optical properties of the twelve styryl dyes are investigated using density functional theory (DFT). Range-separated hybrid CAM-B3LYP and global hybrid BHandHLYP estimate high second order hyperpolarizability. Mean polarizability (α0), polarizability anisotropy (Δα), static first-order hyperpolarizability (β0) and second hyperpolarizability (γ) were found to be overestimated in CAM-B3LYP than in BHandHLYP. As bond length alternation (BLA) increases first order hyperpolarizability increases. Multilinear regression analysis (MLR) shows the solvent basicity, polarizability and dipolarizability are responsible for absorption solvatochromism. The ratio of the dipole moments increases as donor strength and conjugation increases which support charge transfer. The figure of merit (FOM) and intrinsic hyperpolarizability found more in chromophores with dialkylamine donors. As the stability indicated by electrophilicity indices decreases the hyperpolarizability increases. Interrelationships between α0, β0 and γ were evaluated and it shows good linear fit. Absorption is red shifted and hyperpolarizability increases with the amplitude of the sine-shaped potential along the conjugation chain. A high molecular electrostatic potential was observed in dyes containing 2-piperidinothiophene donor.
关键词： NLO,Charge transfer,DFT and TD-DFT,Absorption,Solvatochromism
更新于2025-09-23 15:23:52