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oe1(光电查) - 科学论文

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出版时间
  • 2018
研究主题
  • ac-dc difference
  • Thermal transfer standard
  • inductive voltage
  • uncertainty budget
  • pulse-driven ac Josephson voltage standard
应用领域
  • Measurement and Control Technology and Instruments
机构单位
  • National Institute of Metrology
1183 条数据
?? 中文（中国） ▾

  • Tunable photoluminescence properties and energy transfer of Ca5(BO3)3F: Tb3+/Eu3+ phosphors for solid state lighting

    摘要： A series of Ca5(BO3)3F: Tb3+/Eu3+ phosphors have been prepared via solid-state reaction. Phase purity and crystal structure of as-prepared samples are confirmed by X-ray diffraction measurements. The emission intensity of Ca5(BO3)3F: Tb3+ with Li+, Na+, K+ as charge compensators are remarkably enhanced, and the sample in presence of Na+ exhibits the strongest emission intensity. The emission spectra and fluorescence decays confirm the presence of efficient energy transfers from Tb3+ to Eu3+ in Ca5(BO3)3F: Tb3+/Eu3+ phosphors. The energy transfer mechanism between Tb3+ and Eu3+ has been proven to be resonant type via the electric dipole-dipole interaction. The thermal quenching temperature T50 obtained from the temperature-dependent emission spectra is 478 K, demonstrating a high thermal stability of the as-obtained Ca5(BO3)3F: Tb3+/Eu3+ phosphors. Moreover, by increasing the molar ratio of Eu3+ to Tb3+, the emission colors of Ca5(BO3)3F: Tb3+/Eu3+ phosphors can be tuned from green to orange, and then to red. These results demonstrate that the as-obtained Ca5(BO3)3F: Tb3+/Eu3+ phosphors may have potential applications in solid-state lighting fields.

    关键词： Energy transfer,Ca5(BO3)3F,Phosphors,Tunable luminescence,Solid-state reaction

    更新于2025-09-23 15:23:52

  • Study of the effects of phytoplankton morphology and vertical profile on lidar attenuated backscatter and depolarization ratio

    摘要： Propagation of a lidar beam in a coupled atmosphere-ocean model consisting of multiple atmospheric and upper oceanic layers and a rough ocean surface is studied by using a vectorized Monte Carlo radiative transfer solver optimized specifically for lidar-based remote sensing applications. The effects of assumed phytoplankton morphology variations and its vertical distribution on the lidar attenuated backscatter and depolarization ratio are studied. In this study, a phytoplankton particle is assumed to be a sphere, a sphere with a core, or a randomly distorted hexahedron with or without a core. The single-scattering properties of the nonspherical/inhomogeneous particles are computed using appropriate state-of-the-art light-scattering computational capabilities. Vertical variation of the phytoplankton distribution is derived explicitly using a PAR (photosynthetically active radiation) limited carbon biomass balance equation that is subsequently coupled with the Monte Carlo solver.

    关键词： Radiative transfer,Lidar,Ocean optics,Monte Carlo,Phytoplankton,Net primary production,Remote sensing

    更新于2025-09-23 15:23:52

  • An unstructured Monte Carlo ray-tracing method for solving radiative heat transfer in 3D gray semitransparent medium

    摘要： Monte Carlo ray-tracing method (MCRTM) is widely used for solving the Radiative Transfer equation (RTE) due to its high accuracy and flexibility. In this paper, a MCRTM is developed for solving the radiative heat transfer in gray semitransparent media with complex geometries which are discretized by 3D unstructured grids. A novel algorithm associated to unstructured four-node tetrahedron element is proposed for generating random emitting positions of rays, and the ray tracing process is performed based on Beer's law. Meanwhile, radiation distribution factors are used for calculating radiative source terms which are loaded to the grid. The present method is first validated by comparing the predictive results with those from previous studies on a cubic enclosure, a 3D L-shaped enclosure, and a 3D elliptical enclosure, respectively. Furthermore, a radiation-conduction heat transfer problem is examined in a cylindrical enclosure. All the comparisons show that the present method is in good agreement with these previous cases. This method can be well adapted to various complex geometries. In addition, since the source term is calculated by the radiation distribution factor, which can be reused for different conditions as long as the volumetric radiative properties remain unchanged, this will bring great advantage when coupled with other heat transfer models such as conduction, convection, combustion, etc.

    关键词： Monte Carlo ray-tracing method,Radiative heat transfer,Semitransparent medium,Radiation distribution factor,Unstructured grids

    更新于2025-09-23 15:23:52

  • NIR-Fluorescent Multidye Silica Nanoparticles with Large Stokes Shifts for Versatile Biosensing Applications

    摘要： We have synthesized and characterized of a series of single and multidye copolymerized nanoparticles with large to very large Stokes shifts (100 to 255 nm) for versatile applications as standalone or multiplexed probes in biological matrices. Nanoparticles were prepared via the St?ber method and covalently copolymerized with various combinations of three dyes, including one novel aminocyanine dye. Covalently encapsulated dyes exhibited no significant leakage from the nanoparticle matrix after more than 200 days of storage in ethanol. Across multiple batches of nanoparticles with varying dye content, the average yields and average radii were found to be highly reproducible. Furthermore, the batch to batch variability in the relative amounts of dye incorporated was small (relative standard deviations <2.3%). Quantum yields of dye copolymerized nanoparticles were increased 50% to 1000% relative to those of their respective dye-silane conjugates, and fluorescence intensities were enhanced by approximately three orders of magnitude. Prepared nanoparticles were surface modified with polyethylene glycol and biotin and bound to streptavidin microspheres as a proof of concept. Under single wavelength excitation, microsphere-bound nanoparticles displayed readily distinguishable fluorescence signals at three different emission wavelengths, indicating their potential applications to multicolor sensing. Furthermore, nanoparticles modified with polyethylene glycol and biotin demonstrated hematoprotective qualities and reduced nonspecific binding of serum proteins, indicating their potential suitability to in vivo imaging applications.

    关键词： Fluorescent silica nanoparticles,Biocompatible nanoparticles,Large stokes shift,Near-infrared fluorescence,Multicolor assay,Resonance energy transfer

    更新于2025-09-23 15:23:52

  • Graphdiyne: A promising nonlinear optical material modulated by tetrahedral alkali-metal nitrides

    摘要： A new series of the functionalized graphdiyne (GDY) material was designed by adsorbing the tetrahedral Li3NM molecules on the largely delocalized π-conjugated GDY surface, namely Li3NM@GDY (M = Li, Na, K), and its structure, chemical stability, electronic property, and the first hyperpolarizability were investigated by using the density functional theory computations. Our results reveal that the Li3NM molecules can interact with three triangular holes on the GDY surface, in which the van der Waals interactions play a crucial role in enhancing the structural stability. Meanwhile, the total NPA charges on the Li3NM molecules are gradually increased from Li to K, and the Li3NM molecules can transfer an electron to GDY, forming intramolecular electron donor and acceptor pairs. All of studied complexes exhibit the giant static first hyperpolarizabilities (βtot), up to ~2.88 × 105 a.u. for Li3NK@GDY, which can be explained by two-level expression from the TDDFT calculations. This study will inevitably stimulate further synthesis of the novel graphdiyne-based nonlinear optical materials.

    关键词： Graphdiyne,Electronic structure,TDDFT,Charge transfer,Nonlinear optical property

    更新于2025-09-23 15:23:52

  • Observation of Site-Resolved Vibrational Energy Transfer Using a Genetically Encoded Ultrafast Heater

    摘要： Allosteric information transfer in proteins has been linked to distinct vibrational energy transfer (VET) pathways in a number of theoretical studies. Experimental evidence for such pathways, however, is sparse because site-selective injection of vibrational energy into a protein, i.e. localized heating, is required for their investigation. Here, we solve this problem by the site-specific incorporation of the non-canonical amino acid β-(1-azulenyl)-L-alanine (AzAla) via genetic code expansion. Being an exception to Kasha′s rule, AzAla undergoes ultrafast internal conversion and heating after S1 excitation while upon S2 excitation it serves as a fluorescent label. We endowed PDZ3, a protein interaction domain of postsynaptic density protein 95, with this ultrafast heater at two distinct positions. Using ultrafast IR spectroscopy, we could indeed observe VET from the incorporation sites in the protein to a bound peptide ligand on a picosecond timescale. This approach based on genetically encoded AzAla paves the way for detailed studies of VET and its role for function in a wide range of proteins.

    关键词： protein modification,energy transfer,non-canonical amino acid,time-resolved spectroscopy,mutagenesis

    更新于2025-09-23 15:23:52

  • A turn-on fluorescent probe for vitamin C based on the use of a silicon/CoOOH nanoparticle system

    摘要： The authors describe a fluorometric method for the turn-on determination of vitamin C (ascorbic acid). The blue fluorescence of silicon nanoparticles (SiNPs; with excitation/emission maxima at 350/450 nm) is found to be quenched by CoOOH nanoparticles (NPs). In the presence of vitamin C, the CoOOH NPs are decomposed by a redox reaction between the diol group of vitamin C and CoOOH NPs. As a result, fluorescence recovers. On the basis of this finding, a fluorometric method was designed for the turn-on detection of vitamin C. Under optimal conditions, the method has a low detection limit (0.47 μM) and a linear response in the 0.5 μM to 20 μM a concentration range. It was successfully applied to the determination of vitamin C in spiked red grape and orange juice, and in vitamin C tablets.

    关键词： Fluorescence Bturn-on^ strategy,Cobalt oxyhydroxide nanoparticles,Fluorometry,Stern-Volmer plot,Surface energy transfer,Redox reaction,Inner filter effect,Quenching,Silicon nanoparticles

    更新于2025-09-23 15:23:52

  • SwissKnife-Inspired Multifunctional Fluorescence Probes for Cellular Organelle Targeting Based on Simple AIEgens

    摘要： Facile, efficient and mass production of aggregation-induced emission (AIE) luminogens (AIEgens) with excited-state intramolecular proton transfer (ESIPT) characteristics was achieved by one-step condensation reaction of 2-(hydrazonomethyl)phenol with benzaldehydes. The function of as-prepared AIEgens could be tuned easily by varying the functional group carrying on the phenyl ring of benzaldehyde just like Swiss knife handle. The suitable distance and angle of intramolecular hydrogen bond in these AIEgens endowed them with ESIPT properties, intense solid-state luminescence and large Stokes shifts (155?169 nm). These AIEgens could not only serve as biological probes showing specific targeting to lipid droplets, endoplasmic reticulum and lysosomes, respectively, but also generate reactive oxygen species upon visible light irradiation to make them promise for photodynamic therapy.

    关键词： Fluorescence probes,Aggregation-induced emission,Excited-state intramolecular proton transfer,Photodynamic therapy,Organelle-targeting

    更新于2025-09-23 15:23:52

  • Simultaneous Singlet–Singlet and Triplet–Singlet F?rster Resonance Energy Transfer from a Single Donor Material

    摘要： For almost 70 years, F?rster resonance energy transfer (FRET) has been investigated, implemented into nowadays experimental nanoscience techniques, and considered in a manifold of optics, photonics and optoelectronics applications. Here, we demonstrate for the first time simultaneous and efficient energy transfer from both donating singlet and triplet states of a single photoluminescent molecular species. Using a biluminescent donor that can emit with high yield from both excited states at room temperature allows to apply the FRET framework to such a bimodal system. It serves as an exclusive model system where the spatial origin of energy transfer is exactly the same for both donating spin states involved. Of paramount significance are the facts that both transfers can easily be observed by eye and that F?rster theory is successfully applied to state lifetimes spanning over eight orders of magnitude.

    关键词： organic light-emitting diodes,energy transfer,biluminescence,dual state FRET

    更新于2025-09-23 15:23:52

  • Highly Efficient Luminescent Liquid Crystal with Aggregation-Induced Energy Transfer

    摘要： A luminescent liquid crystal molecule (TPEMes) with efficient solid-state emission is rationally constructed via the chemically conjugation of blue-emitting tetraphenylethene cores and luminescent mesogenic tolane moieties, which are both featured with aggregation-induced emission properties. As for this fluorophore, aggregation induced energy transfer from the emissive tolane mesogens to the lighting-up tetraphenylethene units endows the molecule pure blue emission in the suspension and bulk state. Combining DSC, POM and 1D XRD experiments, TPEMes is deduced to adapt thermodynamically more stable layered crystalline phase, and can be 'frozen' into a monotropic smectic mesophase due to kinetic reasons. As a result of more densely packing of TPEMes in the crystalline phase indicated by 1D XRD, the luminescence of TPEMes in crystalline phase has blue-shifted with 17 nm relative to the metastable mesophase.

    关键词： tolane,tetraphenylethene,aggregation induced emission,aggregation induced energy transfer,hexagonal columnar phase,luminescent liquid crystals

    更新于2025-09-23 15:23:52