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Temperature-dependent luminescence of Ce-doped SrO-B2O3 glasses
摘要: In this study, the photoluminescence (PL) and X-ray-induced scintillation of trivalent cerium, Ce3+, in strontium borate glasses was examined. As no precipitated crystallites were observed, the slight coloration of the glasses was attributed to the formation of defects that are inactive in electron spin resonance spectroscopy. Both the Ce3+/(Ce3++Ce4+) ratio, which was estimated based on the Ce LIII-edge in X-ray absorption near edge structure analysis, and the internal quantum efficiency of Ce-doped glasses increased as the amount of Ce(OCOCH3)3×H2O, which acted as a reducing agent, was increased. Although the PL intensity was independent of the temperature in the range of 10–300 K, the X-ray induced scintillation exhibited thermal quenching behavior with an activation energy of 0.14 eV.
关键词: borate glass,scintillation,thermal quenching,Ce L-edge X-ray absorption near edge structure (XANES),photoluminescence,cerium
更新于2025-09-23 15:21:01
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Landscape of s-triazine molecule on Si(100) by a theoretical x-ray photoelectron spectroscopy and x-ray absorption near-edge structure spectra study
摘要: The chemisorbed structure for an aromatic molecule on a silicon surface plays an important part in promoting the development of organic semiconductor material science. The carbon K-shell x-ray photoelectron spectroscopy (XPS) and the x-ray absorption near-edge structure (XANES) spectra of the interfacial structure of an s-triazine molecule adsorbed on Si(100) surface have been performed by the ?rst principles, and the landscape of the s-triazine molecule on Si(100) surface has been described in detail. Both the XPS and XANES spectra have shown their dependence on different structures for the pristine s-triazine molecule and its several possible adsorbed con?gurations. By comparison with the XPS spectra, the XANES spectra display the strongest structural dependency of all of the studied systems and thus could be well applied to identify the chemisorbed s-triazine derivatives. The exploration of spectral components originated from non-equivalent carbons in disparate local environments has also been implemented for both the XPS and XANES spectra of s-triazine adsorbed con?gurations.
关键词: silicon surface,x-ray absorption near-edge structure (XANES),x-ray photoelectron spectroscopy (XPS),s-triazine
更新于2025-09-09 09:28:46