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Effect of pre-existing nuclei on crystallization during laser welding of Zr-based metallic glass
摘要： In this study, experiments are carried out in laser welding of a Zr-based (Zr52.5Ti5Al10Ni14Cu17.9) bulk metallic glass (BMG), pre-existing nuclei nucleus density has significant influence on its crystallization behavior. Based on the classical nucleation/growth theory, it is concluded that a small amount of pre-existing nuclei in a BMG can shift the time-temperature-transformation (TTT) curve from a well-known ‘C-shape’ to a ‘ε-shape.’ This result provides fundamental understanding on why the shape of the TTT curve for a heating process is different from that for a cooling process for the same BMG. Two quality factors were defined as a measure of the effect of pre-existing nucleus density. By integrating the classical nucleation/growth theory with the heat transfer model, the evolution of crystalline phase during laser welding for a BMG with pre-existing nuclei was studied, and the modeling predictions compared favorably with the experimental results.
关键词： Crystallization,Nucleation and growth,Laser processing,Metallic glasses,Amorphous alloys
更新于2025-11-28 14:24:20
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Process control and quality assurance in remote laser beam welding by optical coherence tomography
摘要： Remote laser beam welding significantly outperforms conventional joining techniques in terms of flexibility and productivity. This process benefits in particular from a highly focused laser radiation and thus from a well-defined heat input. The small spot sizes of high brilliance laser beam sources, however, require a highly dynamic and precise positioning of the beam. Also, the laser intensities typically applied in this context result in high process dynamics and in demand for a method to ensure a sufficient weld quality. A novel sensor concept for remote laser processing based on optical coherence tomography (OCT) was used for both quality assurance and edge tracking. The OCT sensor was integrated into a 3D scanner head equipped with an additional internal scanner to deflect the measuring beam independently of the processing beam. With this system, the surface topography of the process zone as well as the surrounding area can be recorded. Fundamental investigations on aluminum, copper, and galvanized steel were carried out. Initially, the influence of the material, the angle of incidence, the welding position within the scanning field, and the temperature on the OCT measuring signal were evaluated. Based on this, measuring strategies for edge tracking were developed and validated. It was shown that orthogonal measuring lines in the advance of the process zone can reliably track the edge of a fillet weld. By recording the topography in the trailing area of the process zone, it was possible to assess the weld seam quality. Comparing the results to microscopic measurements, it was shown that the system is capable of clearly identifying characteristic features of the weld seam. Also, it was possible to observe an influence of the welding process on the surface properties in the heat-affected zone, based on the quality of the measuring signal.
关键词： inline quality assurance,optical coherence tomography,remote laser beam welding,process control
更新于2025-11-28 14:24:20
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Influence of processing parameters on the microstructure and tensile property of 85 W-15Ni produced by laser direct deposition
摘要： The plate-like shape 85W-15Ni parts were produced by laser direct deposition technology with different processing parameters (laser power and scanning speed). The influence of processing parameters and their corresponding laser energy density on the microstructural characterization, phase composition and tensile property of 85W-15Ni samples was investigated. The results show that the relative density of samples increased with the laser energy density and the densification trend started to slow as the laser energy density reached 380-400 J/mm3, though the highest density value was obtained with laser energy of 425 J/mm3. With the increase of laser energy density, more disorder and fine W dendrites existed at the bonding region between deposition layers and more W-W grain boundaries formed at the central region of the layer. The 85W-15Ni samples produced with different processing parameters consisted of W and γ-Ni phase. To improve the tensile property, it is necessary to increase the laser energy density to obtain denser structure and reduce the residual pores or gaps. However, the excessive laser energy density resulted in the formation of more W-W grain boundaries that were detrimental to the tensile property. The best tensile properties were obtained at the laser energy density of 395 J/mm3.
关键词： 85W-15Ni,Laser direct deposition,Tensile property,Laser energy density,microstructural characterization
更新于2025-11-28 14:24:20
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Identification of nucleation mechanism in laser welds of aluminum alloy
摘要： The nucleation mechanism in laser welds of aluminum alloys is still unclear. Here, we identified it for the first time by adopting an overlap welding procedure. The commonly used 5083 aluminum alloy was taken as an example. The variation of grain structure and grain size in different overlap welding cases was characterized by electron-backscattered diffraction. Results revealed that the nucleation mechanism was heterogeneous nucleation, rather than grain detachment and dendrite fragmentation. Furthermore, the chemical composition and phase structure of the heterogeneous nuclei were tested by energy-dispersive spectrometer and transmission electron microscopy, which indicated that they were D022 Al3Ti phase. The present study is significant in that it can provide a theoretical basis for grain refining in laser welds of aluminum alloys.
更新于2025-11-28 14:24:20
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Effect of Heat Input on Porosity Defects in a Fiber Laser Welded Socket-Joint Made of Powder Metallurgy Molybdenum Alloy
摘要： Porosity defects are still a challenging issue in the fusion welding of molybdenum and its alloys due to the pre-existing interior defects associated with the powder metallurgy process. Fiber laser welding of end plug and cladding tube made of nanostructured high-strength molybdenum (NS-Mo) alloy was performed in this work with an emphasis on the role of welding heat input. The distribution and morphology of porosity defects in the welded joints were examined by computed tomography (CT) and scanning electron microscopy (SEM). Preliminary results showed that laser welding of NS-Mo under low heat input significantly reduced the porosity defects in the fusion zone. The results of computed tomography (CT) showed that when the welding heat input decreased from 3600 J/cm (i.e., 1200 W, 0.2 m/min) to 250 J/cm (i.e., 2500 W, 6 m/min), the porosity ratio of the NS-Mo joints declined from 10.7% to 2.1%. Notable porosity defects under high heat input were related to the instability of the keyhole, expansion and the merging of bubbles in the molten pool, among which the instability of the keyhole played the dominant role. The porous defects at low heat input were generated as bubbles released from the powder metallurgy base metal (BM) did not have enough time to overflow and escape.
关键词： fiber laser welding,molybdenum alloy,porosity defects,heat input
更新于2025-11-28 14:24:20
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High Temperature Oxidation and Wear Resistance of In Situ Synthesized (Ti3Al?+?TiB)/Ti Composites by Laser Cladding
摘要： (Ti3Al + TiB)/Ti composites were prepared on Ti6Al4V by laser cladding. The microstructures of the coatings were analyzed; the high temperature wear and oxidation properties of the coatings were investigated and compared with Ti6Al4V. Ti3Al and TiB particles were in situ formed through the reaction between Ti and AlB2. The reinforcements exhibited some crystallographic orientation relationships with a-Ti matrix, and a semi-coherent interface (Ti3Al) or a coherent interface (TiB) was obtained. The weight gain of the coating under each combination of temperature and time condition was 20 to 30 pct of the value of Ti6Al4V under the same experimental parameters. A denser and well-bonded TiO2 + Al2O3 layer was formed, effectively hindering the oxygen diffusion compared with the TiO2 layer on Ti6Al4V. EBSD result showed that the Al2O3 mainly assembled into clusters and located close to the interface while the outer area of the oxidation layer was mainly TiO2. The friction coefficients and wear losses of the coatings were lower than those of the substrates at 300 °C to 750 °C. The oxidation was a crucial factor affecting the wear performance at high temperatures. The protective effect of the TiO2 + Al2O3 layer and the formation of transfer films on the worn surface contributed to the improved wear resistance of the coating.
关键词： TiB,Laser Cladding,Wear Resistance,Ti Composites,In Situ Synthesized,High Temperature Oxidation,Ti3Al
更新于2025-11-28 14:24:20
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Hyperspectral and thermal temperature estimation during laser cladding
摘要： Although there is no doubt about the tremendous industrial potential of metal additive manufacturing techniques such as laser metal deposition, the technology still has some intrinsic quality challenges to overcome before reaching its industrial maturity. Noncontact in situ monitoring of the temperature evolution of the workpiece could provide the necessary information to implement an automated closed-loop process control system and optimize the manufacturing process, providing a robust solution to these issues. However, measuring absolute temperatures is not self-evident: wavelength-dependent emissivity values vary between solid, liquid, and mushy metallic regions, requiring spectral information and dedicated postprocessing to relate the amount of emitted infrared radiation to the material temperature. This paper compares the temperature estimation results obtained from a visible and near-infrared hyperspectral line camera and a conventional short-wave infrared (SWIR) thermal camera during the laser melting and cladding of a 316L steel sample. Both methods show agreeing results for the temperature distribution inside the melt pool, with the SWIR camera extending the temperature measurements beyond the melt pool boundaries into the solid region.
关键词： temperature estimation,laser cladding,hyperspectral imaging,additive manufacturing,thermal monitoring
更新于2025-11-28 14:24:20
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Mechanism study on the effects of power modulation on energy coupling efficiency in infrared laser welding of highly-reflective materials
摘要： High-reflectivity of materials, such as magnesium, copper and aluminum, results in low thermal efficiency of their infrared laser welding processes. AZ31 magnesium alloy was selected to study the effects of power modulation on energy coupling efficiency in laser welding of highly-reflective materials. A model for the relationship between energy coupling efficiency and modulation parameters was obtained. The energy coupling efficiency in optimized modulated-power laser welding was about 1.58 times that in constant-power welding. The mechanism was explored by analyzing keyhole evolution and the resulted pressure distribution along keyhole wall during welding. The keyhole evolutions in laser continuous welding of common material (Q345 steel, reflectivity of 65%) and highly-reflective material (AZ31, reflectivity of 85%) were observed through high-speed imaging by utilizing a half sandwich method. The results indicated that the secret of improving energy coupling efficiency of laser welding process of highly-reflective materials through power modulation was the formation of a deep keyhole and its long life. When instantaneous power decreased from the peak, there was still enough recoil pressure at the bottom of keyhole to resist surface tension and hydrostatic pressure of liquid metal, which was the fundamental reason for the long time existence of keyhole with a large depth.
关键词： laser welding,magnesium alloy,recoil pressure,keyhole,highly-reflective materials,power modulation
更新于2025-11-28 14:24:20
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Effects of tilt angle between laser nozzle and substrate on bead morphology in multi-axis laser cladding
摘要： Laser cladding has been increasingly used for repairing and remanufacturing critical and high-value components due to its unique benefits such as high solidification rates and a small heat-affected zone. In laser cladding, tilt angle between a laser nozzle and a substrate has a significant impact on deposited bead morphology. To ensure the quality of laser cladding, the effects of tilt angle on bead morphology are investigated in this study. An analytical model is introduced to predict bead shapes for three tilting postures. In the first case, a substrate remains horizontal while the nozzle is tilted. All three parameters, including width, height, and peak point offset, will be influenced by the laser beam power distribution. In the second case, a substrate is tilted while the laser nozzle is kept axial to the substrate’s normal, the peak point offset will ascend along with the increasing of the tilt angle (gravity effect). In the third case, the laser nozzle remains vertical while the substrate is tilted, which leads to variations of cladding width, cladding height, and especially peak point shifting value. These parameters will be dependent on the integrated effect of gravity and the laser beam power distribution. A set of experiments is conducted to demonstrate the effectiveness of the proposed model. This study illustrates that the variation of cladding width and height with the tilt angle can be accurately calculated by the predictive model, and that the peak point shifting value is roughly smaller than 5% of cladding width when the tilt angle is less than 30°. These findings show that trajectory planning of multi-axis laser cladding can be optimized using an acceptable range of tilt angle between the laser nozzle and substrate.
关键词： Bead morphology,Laser beam power distribution,Laser cladding,Tilting posture,Gravity effect
更新于2025-11-28 14:24:20
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Effects of Power Modulation, Multipass Remelting and Zr Addition Upon Porosity Defects in Laser Seal Welding of End Plug to Thin-Walled Molybdenum Alloy
摘要： Aiming to solve the serious porosity defects in laser welded girth joints of thin-walled tube and end plug made of nano-sized Ce2O3 doped Mo alloy (NC-Mo), the influences of laser power modulation, multipass remelting and zirconium (Zr) addition on the number, size and distribution of porosity defects were experimentally studied. By utilizing X-ray computed tomography (XCT), scanning electron microscope (SEM), energy dispersive spectroscopy (EDS) analysis, transmission electron microscope (TEM) and Raman spectrum (RS), the porosity feature of welded joints achieved under various conditions was analyzed. The results showed that welding cycles had a significant influence on the porosity ratio of fusion zone (FZ) while the amplitude and frequency of laser power waveform slightly influenced the porosity. When the welding cycles increased from 2 to 8, the porosity ratio of FZ decreased from about 1.00% to about 0.48% and the maximum and average pore diameters reduced by about 53% and 27%, respectively. Adding minor Zr in molten pool can further reduce the RP of FZ to about 0.35%. Through analysis, it can be seen that the pores in FZ can be divided into irregularly-shaped keyhole-induced pores and spherical metallurgy-induced pores. The latter was generated possibly because some impurity elements (including O and H) pre-existing in base metal (BM). Increasing welding cycles can promote the gas in molten pool to float and outflow, thus significantly decreasing the porosity. Moreover, Zr added in molten pool can be preferentially reacted with O to generate ZrO2, which can inhibit the precipitation of volatile MoO2 to thus suppress the generation of metallurgy-induced pores.
关键词： Molybdenum alloy,Multipass remelting,Power-Modulated laser welding,Zirconium addition,Porosity
更新于2025-11-28 14:24:20