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High performance phototransistors with organic/quantum dot composite materials channels
摘要： Nanomaterials, especially quantum dots, have become one of the most great potential channel transport layer materials in the field of photo detection mainly due to their particular light absorption characteristics. However, there are still many disadvantages such as low carrier transport capability possibly attributable to the discontinuity nature of materials. Therefore, particular phototransistors with pentacene/CdSe@ZnS QDs composite materials channels have been prepared by simply blending and spin-coating 6,13-Bis(triisopropylsilylethynyl)-pentacene (TIPS-pentacene) and QDs solution in weight ratio of 3:1. The particular device architecture with organic/quantum dot composite materials channels effectively combined the high carrier mobility advantage of organic semiconductors with the strong absorption characteristic of quantum dots in specific optical band regions and further overcame the low conductivity shortcomings of pure quantum dot materials. The device with particular pentacene/CdSe@ZnS QDs composite channel exhibited excellent electrical and optical properties with current switch ratio Ion/off of 104, carriers mobility of ~0.161 cm2/V, photosensitivity P of 105, responsivity R of 0.33 mA/W and detectivity D of 1.48 ? 1011 Jones at drain voltage of (cid:0) 35 V and light intensity of 1.6 mW/cm2, respectively, indicating that this composite, as one of the most promising channel transport layer material candidates for photodetector, provides one chance to improve the characteristic of photodetector transistors just by using hybrid channel technology.
关键词： Solution method,Quantum dots,Photodetectors,Composite materials,Organic thin film transistors
更新于2025-09-11 14:15:04
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Polymer–Mineral Composites Mimic Human Kidney Stones in Laser Lithotripsy Experiments
摘要： Despite the widespread use of laser lithotripsy to fragment kidney stones in vivo, there is a lack of robust artificial stone models to replicate the behavior of human stones during lithotripsy procedures. This need for accurate stone models is particularly important as novel laser technologies are introduced in the field of lithotripsy. In this work, we present a method to prepare composite materials that replicate the properties of human kidney stones during laser lithotripsy. Their behavior is understood through the lens of near-IR spectroscopy and helps to elucidate the mechanism of laser lithotripsy in kidney stone materials.
关键词： composite materials,artificial kidney stones,near-IR absorption,biomineralization,laser ablation
更新于2025-09-11 14:15:04
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Core/shell-structured TiO2/PbS photoanodes for high-performance CsPbBr3 perovskite solar cells
摘要： PbS colloidal quantum dots (CQDs) were used as sensitizers to modify the mesoporous TiO2 (m-TiO2) layer/CsPbBr3 perovskite interface in solar cells by controlling the various spin-coating cycles on the surface of m-TiO2. The visible light absorption of m-TiO2 was enhanced because of the PbS CQDs. The prominent power conversion efficiency (PCE) of 5.04% for the core/shell-structured TiO2/PbS photoanode was higher than that of the pristine device (2.45%). This investigation provides a basis for the effect of CQD sensitization of the functional interfaces on the performance of perovskite solar cells (PSCs) under ambient conditions.
关键词： Thin films,Deposition,Composite materials,Interface
更新于2025-09-11 14:15:04
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BIFEVOX Composites: Manufacture and Characterization
摘要： Design of composites is a way to improve the quality of solid electrolytes. By mechanically mixing and annealing substituted bismuth vanadate with nanosized aluminum, bismuth, and zirconium binary oxides, we obtained heterogeneous materials Bi4V1.7Fe0.3O11 – δ/xAl2O3, Bi4V1.7Fe0.3O11 – δ/xBi2O3, and Bi4V1.7Fe0.3O11 – δ/xYSZ. The investigation tools were X-ray powder diffraction and electron microscopy with energy-dispersive microanalysis. The composition of materials was studied, the non-interaction of components was elucidated in the aluminum oxide and zirconium oxide composite series, and a nonuniform distribution of nanopowder particles across the surfaces and cleaves of sinters was discovered. The bismuth atoms from bismuth oxide were shown to be capable of incorporating into the Bi4Fe0.3V1.7O11 – δ structure. The charge transport characteristics of the materials were studied by impedance spectroscopy. No changes were observed in logσ–103/T trends in composites with various binary oxides and various oxide contents. An increase in binary oxide concentration was shown to give rise to an insignificant decay in electrical conductivity.
关键词： composite materials,bismuth vanadates,impedance spectroscopy,bismuth oxide,oxygen-ion conductors
更新于2025-09-10 09:29:36
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Polyelectrolyte Dielectrics for Flexible Low-Voltage Organic Thin-Film Transistors in Highly Sensitive Pressure Sensing
摘要： Organic thin-film transistors (OTFTs) can provide an effective platform to develop flexible pressure sensors in wearable electronics due to their good signal amplification function. However, it is particularly difficult to realize OTFT-based pressure sensors with both low-voltage operation and high sensitivity. Here, controllable polyelectrolyte composites based on poly(ethylene glycol) (PEG) and polyacrylic acid (PAA) are developed as a type of high-capacitance dielectrics for flexible OTFTs and ultrasensitive pressure sensors with sub-1 V operation. Flexible OTFTs using the PAA:PEG dielectrics show good universality and greatly enhanced electrical performance under a much smaller operating voltage of ?0.7 V than those with a pristine PAA dielectric. The low-voltage OTFTs also exhibit excellent flexibility and bending stability under various bending radii and long cycles. Flexible OTFT-based pressure sensors with low-voltage operation and superhigh sensitivity are demonstrated by using a suspended semiconductor/dielectric/gate structure in combination with the PAA:PEG dielectric. The sensors deliver a record high sensitivity of 452.7 kPa?1 under a low-voltage of ?0.7 V, and excellent operating stability over 5000 cycles. The OTFT sensors can be built into a wearable sensor array for spatial pressure mapping, which shows a bright potential in flexible electronics such as wearable devices and smart skins.
关键词： composite materials,organic field-effect transistors,flexible electronics,pressure sensors,dielectrics
更新于2025-09-10 09:29:36
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Improvement of the third order nonlinear optical properties of nematic liquid crystal under the influence of different compositional percentage of doped SWCNT and the external electric field
摘要： In this research, the nematic liquid crystal (NLC) was doped with varying concentration (0-1 % wt.) of single walled carbon nanotubes (SWCNTs) at room temperature to study the nonlinear optical (NLO) properties of E5CN7@CNT cell.The third order NLO properties such as the nonlinear susceptibility, the nonlinear refraction (NLR) and the nonlinear absorption (NLA) were determined by using Z-scan techniques. The nonlinear studies have been done using a continuous wave (CW) He: Ne laser at 632.8 nm.Doping SWCNTs to eutectic uniaxial NLC (E5CN7) enhanced the third order nonlinear susceptibility, ??(3) and consequently the nonlinearity properties of composite systems improved.It is found that at lower concentration of CNTs (c< 0.75 % wt.), the third order nonlinear susceptibility are increased, but for concentration 0. 5<c<1 % wt., the third order nonlinear susceptibility are decreased. The negative sign of the observed NLR index, indicates that the E5CN7@CNT exhibits self-defocusing type optical nonlinearity. The two photon absorption (TPA) behavior, corresponding to negative sign NLA of samples. The reorientation of samples molecules amplifies upon the application of electric field, then nonlinearity increases.
关键词： Composite materials,Nematic liquid crystal,Carbon nanotubes,Third order nonlinear susceptibility,Nonlinear optics,Electric field,Z-scan method
更新于2025-09-10 09:29:36
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AIP Conference Proceedings [Author(s) 6TH INTERNATIONAL CONFERENCE ON PRODUCTION, ENERGY AND RELIABILITY 2018: World Engineering Science & Technology Congress (ESTCON) - Kuala Lumpur, Malaysia (13–14 August 2018)] - Hydrothermal synthesis of carbon dots and their luminescence
摘要： The synthesis of carbon dots by hydrothermal method with external heating from precursors such as glucose, citric acid, birch bark soot, cowberry, blueberry, redcurrant, and blackbird cherry are investigated. The photoluminescence studies of these carbon dots at di?erent excitation wavelengths was held. It is shown that there is an e?ect of the shift of luminescence spectra intensity peaks with the increasing of excitation wavelengths. The presence of this e?ect open new perspectives for development of composite materials from carbon dots, starch, and epoxy, which can convert the light of the blue LED into the green.
关键词： composite materials,luminescence spectra,hydrothermal synthesis,carbon dots,photoluminescence
更新于2025-09-10 09:29:36
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The synthesis of Bi2S3/2D-Bi2WO6 composite materials with enhanced photocatalytic activities
摘要： Bi2S3/2D-Bi2WO6 composite materials which combined 2D-Bi2WO6 with Bi2S3 nanoparticles were prepared via ion exchange method. The mass ratio of Bi2S3 nanoparticle could be modulated by changing the quantity of thioacetamide (TAA). For Bi2S3/2D-Bi2WO6 composite materials, Bi2S3 nanoparticles dispersed on the surface of Bi2WO6 nanosheets. The photocatalytic activity was evaluated by photodegradation rhodamine B (RhB) under visible light. RhB was photodegraded nearly completely by BWS-2, while only 67% was photodegraded by Bi2WO6 nanosheet after 5 hours’ visible light irradiation. Based on the optical and electrochemical measurements, Bi2S3/2D-Bi2WO6 composite materials have prolonged carriers’ lifetime, improved carriers’ separation efficiency and decreased carriers’ recombination efficiency. These results endow Bi2S3/2D-Bi2WO6 composite materials with high photocatalytic activities.
关键词： Bi2S3/2D-Bi2WO6,ion exchange method,photocatalytic activities,visible light,composite materials
更新于2025-09-10 09:29:36
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Thermal behaviour of poly(methyl methacrylate)/fullerene composite films
摘要： Poly(methyl methacrylate)/fullerene composite films were fabricated by casting from toluene solutions. The mass fraction of fullerene (C60) was varied from 0.05–3 wt. %. The effect of the fullerene (C60) content on the thermal degradation parameters of the composite films was evaluated by thermogravimetric (TG) analysis. It was found that the incorporation of C60 improved the thermal stability of the polymers. The films eventually decomposed in three stages. Incorporation of fullerene caused a change in the distribution of mass loss over the stages of degradation in comparison with the pristine polymer. Using differential scanning calorimetry (DSC), the phase transitions from the glassy state to the elastic one was studied for the examined polymeric materials. New data relating to the effect of C60 on the glass transition temperature of composites with low weight fractions of filler were obtained. Specifically, for films containing up to 0.1 wt. % of C60, a single glass transition temperature was found, whereas for composites with a higher concentration of filler, two glass transition temperatures were recorded.
关键词： Composite materials,thermogravimetric (TG) analysis,glass transition,DSC,fullerenes,thermal stability
更新于2025-09-09 09:28:46
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TiO2@g-C3N4 heterojunction with directional charge migration behavior for photodegradation of tetracycline antibiotics
摘要： The performance of semiconductor photocatalysts in organic contaminants degradation is strongly influenced by the structure-related charge separation behavior. Hence, titanium dioxide (TiO2) nanowire, which is efficient in directional migration of photocarriers, is prepared and employed as the carrier for the in situ growth of discrete graphite carbon nitride (g-C3N4) to form a compact and high-reactive heterojunction photocatalyst. The structures and properties of the samples are systematically characterized and discussed. The experimental results indicate that the tetracycline photodegradation efficiency obtained by employing TiO2@g-C3N4 as the photocatalyst is improved by 126% and 75%, respectively, compared to that using TiO2 nanowire and bulk g-C3N4. This work highlights that precisely controlling the microstructure and charge separation behavior is critical for preparing high-reactive photocatalysts.
关键词： Composite materials,Semiconductors,Heterojunction,g-C3N4,Photocatalysis
更新于2025-09-09 09:28:46