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Influence of the polarization of the laser beam in femtosecond laser-induced breakdown spectroscopy
摘要： Laser-induced breakdown spectroscopy (LIBS) is an important technique which is widely used to analyze element composition. In order to improve the sensitivity of LIBS, researchers have been dedicated to enhance the spectral intensity of LIBS by proposing a number of methods. In addition, we find that laser polarization has great influence on the emission intensity of femtosecond LIBS. By comparing the emission intensity of femtosecond LIBS in the circular and linear polarizations, the spectral intensity in the case of circular polarization is stronger than that in the case of linear polarization. Moreover, this phenomenon is more obvious as laser energy increases. The polarization plays an important role in LIBS signal intensity. Based on the observation, the enhanced mechanism of the laser polarization on the spectral intensity is discussed in this paper, which will be helpful to spectral analysis and component analysis.
关键词： femtosecond laser,LIBS,spectral enhancement,laser polarization
更新于2025-09-23 15:19:57
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Enhancement of photocatalytic activity by femtosecond-laser induced periodic surface structures of Si
摘要： Laser induced periodic surface structures (LIPSS) represent a kind of top down approach to produce highly reproducible nano/microstructures without going for any sophisticated process of lithography. This method is much simpler and cost effective. In this work, LIPSS on Si surfaces were generated using femtosecond laser pulses of 800 nm wavelength. Photocatalytic substrates were prepared by depositing TiO2 thin films on top of the structured and unstructured Si wafer. The coatings were produced by sputtering from a Ti target in two different types of oxygen atmospheres. In first case, the oxygen pressure within the sputtering chamber was chosen to be high (3 × 10–2 mbar) whereas it was one order of magnitude lower in second case (2.1 × 10–3 mbar). In photocatalytic dye decomposition study of Methylene blue dye it was found that in the presence of LIPSS the activity can be enhanced by 2.1 and 3.3 times with high pressure and low pressure grown TiO2 thin films, respectively. The increase in photocatalytic activity is attributed to the enlargement of effective surface area. In comparative study, the dye decomposition rates of TiO2 thin films grown on LIPSS are found to be much higher than the value for standard reference thin film material Pilkington ActivTM.
关键词： photocatalytic dye decomposition,silicon,femtosecond laser pulses,TiO2 thin film,laser induced periodic surface structures,nanoripples
更新于2025-09-23 15:19:57
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Precise laser trimming of alloy strip resistor: A comparative study with femtosecond laser and nanosecond laser
摘要： Laser trimming has become one of the powerful tools for precise manufacturing of alloy resistors that are widely used in electrical vehicles, electrical controlling, and in appliances. In this work, the influence of femtosecond laser trimming is compared with nanosecond laser trimming. The authors found that lasers focused on different heights relative to the sample surface induced significant changes in surface morphologies. The resistance change was systematically investigated as a function of cutting lengths and cutting depths of different laser powers for both lasers. The experiments display that femtosecond laser trimming has a higher precision of the resistance adjustment than nanosecond laser trimming. The periodic ripple structure by the femtosecond laser was investigated at the focus position above, onto, or beneath the surface. The period of a low frequency ripple structure (LFRS) on the ablated groove bottom is about 600–700 nm when the laser focuses just right on the surface but changes to 490–560 nm when focusing above or beneath the surface. The period of a high frequency ripple structure is about 100–380 nm at the vertical direction of LFRS. The period of low frequency ripple on the outside of the groove is smaller than that on the groove bottom for all three focusing cases. The period of the LFRS is not sensitive to the laser power. The range of the resistor value change in the s-polarized light direction of the femtosecond laser is more than that in the p-polarized light direction.
关键词： Fe-Cr-Al alloy resistor,micromachining,femtosecond laser trimming,nanosecond laser trimming
更新于2025-09-23 15:19:57
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Transient optics of gold during laser irradiation: From first principles to experiment
摘要： Intense femtosecond laser pulses can induce dramatic changes on different properties of materials. Laser induced changes of the optical properties are particularly relevant, since they can lead to a modi?cation of the amount of energy that the material absorbs from the laser pulse. In noble metals, changes of re?ectivity upon femtosecond laser illumination are expected to be strong due to the excitation of d electrons. In this work we perform measurements of the re?ectivity of laser excited gold in the infrared and in the ultraviolet range, respectively. We ?nd a remarkable dependence of the re?ectivity on laser ?uence, which is in turn different in both ranges of photon energy. In order to understand the behavior of the re?ectivity in laser excited solids and to explain our measured re?ectivity curves we develop a theoretical scheme in the framework of the two-temperature model with the electronic temperature as the key parameter. Our approach is based on all-electron calculations of the interband contribution to the re?ectivity and a careful determination of the intraband, Drude-like terms and a realistic model for the space and time resolved energy transfer from a Gaussian laser pulse into the electronic system. We obtain very good agreement between experiment and theory and identify the main mechanisms for re?ectivity changes as a function of laser ?uence.
关键词： intraband,Drude-like terms,interband contribution,electronic temperature,Gaussian laser pulse,re?ectivity,two-temperature model,femtosecond laser pulses,optical properties,gold
更新于2025-09-23 15:19:57
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Sequential Evolution of Colored Copper Surface Irradiated by Defocused Femtosecond Laser
摘要： An effective method for the fabrication of sequential colors on copper by adjusting femtosecond laser defocusing distance is proposed. The sequential evolution tendency of induced colors by adjusting laser defocusing distance is carried out. Corresponding mechanisms are revealed by different kinds of surface structures. Angle-resolved spectrum and simultaneously derived hydrophobicity are also investigated.
关键词： hydrophobicity,femtosecond laser,sequential colors,defocus-dependent
更新于2025-09-23 15:19:57
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Efficient generation of nitrogen vacancy centers by laser writing close to the diamond surface with a layer of silicon nanoballs
摘要： We proposed a method to effectively fabricate negatively charged nitrogen vacancy (NV?) centers close to the diamond surface by applying femtosecond laser writing technique. With a thick layer of silicon (Si) nanoballs coated, diamond surface was irradiated by high-fluence femtosecond laser pulses. A large number of NV? centers were created around the laser ablation crater area without thermal annealing. The distribution of the NV? centers was expanded to about 50 μm away from the crater center. To demonstrate the function of Si nanoballs, we performed the exactly same laser illumination process on the bare region of the sample surface. In this case, only a few NV? centers were generated around ablation crater. At distance of 32 μm away from crater centers, the NV? density for the case with nanoballs was up to 15.5 times higher compared to the case without nanoballs. Furthermore, we also investigated the influence of laser fluence and pulse number on the NV? density for the case with Si-nanoball layer. Finally, the formation mechanism of NV? centers and the role of Si nanoballs were explained via Coulomb explosion model. The method is demonstrated to be a promising approach to efficiently and rapidly fabricate NV? centers close to the surface of the diamond, which are significant in quantum sensing. Furthermore, the results provide deep insights into complex light-matter interactions.
关键词： single emitters,nitrogen vacancy centers in diamond,silicon nanoballs,femtosecond laser technique
更新于2025-09-23 15:19:57
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Femtosecond-laser-irradiation-induced structural organization and crystallinity of Bi2WO6
摘要： controlling the structural organization and crystallinity of functional oxides is key to enhancing their performance in technological applications. in this work, we report a strong enhancement of the structural organization and crystallinity of Bi2Wo6 samples synthetized by a microwave-assisted hydrothermal method after exposing them to femtosecond laser irradiation. X-ray diffraction, UV-vis and Raman spectroscopies, photoluminescence emissions, energy dispersive spectroscopy, field emission scanning electron microscopy, and transmission electron microscopy were employed to characterize the as-synthetized samples. To complement and rationalize the experimental results, first-principles calculations were employed to study the effects of femtosecond laser irradiation. Structural and electronic effects induced by femtosecond laser irradiation enhance the long-range crystallinity while decreasing the free carrier density, as it takes place in the amorphous and liquid states. these effects can be considered a clear cut case of surface-enhanced Raman scattering.
关键词： structural organization,Bi2WO6,femtosecond laser irradiation,crystallinity,microwave-assisted hydrothermal method
更新于2025-09-23 15:19:57
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Effect of irradiation time in the synthesis of Au-Ag nanoalloys by femtosecond laser
摘要： The synthesis of metallic nanoparticles can be performed by femtosecond laser-induced photoreduction of the metallic ion solution. Due to hydrogen radical and the solvated electron generated through the interaction of ultrafast laser and water medium, the dissolved metallic ion in the medium can be converted to their respective metallic atom and then precipitated into nanoparticles. When there is more than one metallic ion available in the solution, alloy nanoparticles can be generated. One parameter that affects this laser-based synthesis was the duration of laser irradiation time that has an advantage for size modification of nanoparticles. In this work, we have synthesized Au-Ag nanoalloys from the mixture of Au and Ag ion in water medium added with 0.01wt% polyvinylpyrrolidone (PVP) as a capping agent and irradiated for 5 and 10 minutes. The result showed that there was linear shifting in surface plasmon resonance (SPR) of the nanoalloys in respect with their volume fraction of the ions. The results also revealed that the nanoparticle size was indeed reduced as the laser irradiation was prolonged, i.e., Au50Ag50 has a particle size of 7.98 nm and 5.18 nm for 5 and 10 minutes irradiation time, respectively.
关键词： irradiation time,Au-Ag nanoalloys,surface plasmon resonance,femtosecond laser,nanoparticle size
更新于2025-09-23 15:19:57
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The efficacy of plasmonic model to calculate HSFL nanostructure period in Sapphire
摘要： In this work, we try to determine all the period of nanostructure subwavelength that can be observed during irradiation by multipulse femtosecond laser in dielectric materials. For this, we use a generalized plasmonic model developed previously to follow the evolution of the periods of the nanostructures on the Sapphire material and their optical properties according to electron-holes plasma excitation and varying the optical spectrum between 300 and 1400 nm. We ?nd a nanostructure area where all the period observed experimentally must be included inside it. This plasmonic model shows its e?ciency and its precision on a nanoscale.
关键词： Sapphire,plasmonic model,HSFL nanostructure,femtosecond laser,electron-holes plasma
更新于2025-09-23 15:19:57
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Ultrafast dynamics observation during femtosecond laser-material interaction
摘要： Femtosecond laser technology has attracted significant attention from the viewpoints of fundamental and application; especially femtosecond laser processing materials present the unique mechanism of laser-material interaction. Under the extreme nonequilibrium conditions imposed by femtosecond laser irradiation, many fundamental questions concerning the physical origin of the material removal process remain unanswered. In this review, cutting-edge ultrafast dynamic observation techniques for investigating the fundamental questions, including time-resolved pump-probe shadowgraphy, ultrafast continuous optical imaging, and four-dimensional ultrafast scanning electron microscopy, are comprehensively surveyed. Each technique is described in depth, beginning with its basic principle, followed by a description of its representative applications in laser-material interaction and its strengths and limitations. The consideration of temporal and spatial resolutions and panoramic measurement at different scales are two major challenges. Hence, the prospects for technical advancement in this field are discussed finally.
关键词： ultrafast dynamics,ultrafast continuous optical imaging,femtosecond laser manufacturing,4D ultrafast scanning electron microscopy,pump-probe shadowgraphy
更新于2025-09-23 15:19:57